Air‐Stable (CAAC)CuCl and (CAAC)CuBH 4 Complexes as Catalysts for the Hydrolytic Dehydrogenation of BH 3 NH 3

Hu, Xingbang; Soleilhavoup, Michèle; Melaimi, Mohand; Chu, Jiaxiang; Bertrand, Guy

doi:10.1002/ange.201500224

Air‐Stable (CAAC)CuCl and (CAAC)CuBH ₄ Complexes as Catalysts for the Hydrolytic Dehydrogenation of BH ₃ NH ₃ (in German)

Journal Article · Fri Mar 20 00:00:00 EDT 2015 · Angewandte Chemie

DOI:https://doi.org/10.1002/ange.201500224· OSTI ID:1400449

Hu, Xingbang; Soleilhavoup, Michèle; Melaimi, Mohand; Chu, Jiaxiang; Bertrand, Guy

Abstract

The first stable copper borohydride complex [(CAAC)CuBH ₄ ] [CAAC=cyclic(alkyl)(amino)carbene] bearing a single monodentate ligand was prepared by addition of NaBH ₄ or BH ₃ NH ₃ to the corresponding [(CAAC)CuCl] complex. Both complexes are air‐stable and promote the catalytic hydrolytic dehydrogenation of ammonia borane. The amount of hydrogen released reaches 2.8 H ₂ /BH ₃ NH ₃ with a turnover frequency of 8400 mol mol _cat ⁻¹ h ⁻¹ at 25 °C. In a fifteen‐cycle experiment, the catalyst was reused without any loss of efficiency.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0009376

OSTI ID:: 1400449

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Journal Issue: 20 Vol. 127; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: German

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