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New description of long period stacking order structures of martensites in {beta}-phase alloys

Journal Article · · Scripta Metallurgica et Materialia
 [1];  [2];  [3];  [4]
  1. Univ. of Tsukuba, Ibaraki (Japan). Inst. of Materials Science
  2. Teikyo Univ., Utsunomiya (Japan). Dept. of Materials Science and Engineering
  3. Univ. of Tokyo (Japan). Mineralogical Inst.
  4. Univ. of Illinois, Urbana, IL (United States). Dept. of Materials Science and Engineering

The martensitic transformations in {beta}-phase alloys have attracted much attention for many years, since they are associated with the unique shape memory and superelasticity effects, and the lattice instability or unusually soft elastic constant c{prime}[=c11-c12/2]. Besides, the structural changes are all similar to each other; i.e. ordered BCC parent (B2 type or DO{sub 3} type) structures transform to long period stacking order structures, with 2-dimensionally close-packed planes. Furthermore, these alloys in a single crystal state even exhibit martensite-to-martensite transformation among the long period stacking order structures. These structural changes became clear after the crystal structure determination of {beta}{sub 1}{prime} martensite in a Cu-Al alloy near the Cu{sub 3}Al composition by Nishiyama and Kajiwara. The authors discuss the structural change following their scheme. The structure of the martensite in {beta}-phase alloys was extensively re-examined. As a result, the displacements of stacking positions from the ideal a/3 positions and the monoclinicity of 18R(9R) martensites were confirmed in most of the alloys examined, such as Cu-Zn-Ga, Cu-Zn-Al, Au-Cu-Zn, and Cu-Al-Ni alloys. Thus, they can conclude that the structures of the martensites in {beta}-phase alloys are intrinsically monoclinic except for 2H martensites.

OSTI ID:
139984
Journal Information:
Scripta Metallurgica et Materialia, Journal Name: Scripta Metallurgica et Materialia Journal Issue: 10 Vol. 29; ISSN 0956-716X; ISSN SCRMEX
Country of Publication:
United States
Language:
English

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