Analysis of the CO2 Chemisorption in Li5FeO4, a New High Temperature CO2 Captor Material. Effect of the CO2 and O2 Partial Pressures

Lara-García, Hugo A.; Sanchez-Camacho, Pedro; Duan, Yuhua; Ortiz-Landeros, José; Pfeiffer, Heriberto

doi:10.1021/acs.jpcc.6b12431

Title: Analysis of the CO₂ Chemisorption in Li₅FeO₄, a New High Temperature CO₂ Captor Material. Effect of the CO₂ and O₂ Partial Pressures

Journal Article · Mon Jan 23 00:00:00 EST 2017 · Journal of Physical Chemistry. C

DOI:https://doi.org/10.1021/acs.jpcc.6b12431· OSTI ID:1399479

Lara-García, Hugo A. ^[1]; Sanchez-Camacho, Pedro ^[1]; Duan, Yuhua ^[2]; Ortiz-Landeros, José ^[3];

^[1]

National Autonomous Univ. of Mexico, Mexico City (Mexico). Inst. of Materials Research
National Energy Technology Lab. (NETL), Pittsburgh, PA (United States)
National Polytechnic Inst. (IPN), Mexico City (Mexico). Higher Education School of Chemical Engineering and Extractive Industries (ESIQIE). Dept. of Engineering in Metallurgy and Materials

Pentalithium ferrite (Li₅FeO₄) was tested in this paper as possible CO₂ captor, both by theoretical calculations and experimental measurements. The pristine Li₅FeO₄ compound with orthorhombic structure was synthesized via solid-state reaction and it was structural and microstructurally characterized. Later, sample was heat-treated at temperatures from room temperature to 900 °C under different CO₂ or CO₂–O₂ atmospheres. Li₅FeO₄ exhibits excellent CO₂ chemisorption abilities with a capture capacity about 12.9 mmol/g, which is outstanding in comparison to other previously reported ceramic captors. This material is able to react with CO₂ from 200 °C to approximately 715 °C showing a high kinetic of reaction even at CO₂ partial pressure values as low as 0.2. Finally and additionally, results suggest that oxygen addition does enhance the CO₂ chemisorption on Li₅FeO₄ at temperatures below 700 °C, although oxygen addition seems to favor the desorption process at higher temperatures.

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Research Organization:: National Autonomous Univ. of Mexico, Mexico City (Mexico); National Energy Technology Lab. (NETL), Pittsburgh, PA (United States)

Sponsoring Organization:: USDOE; National Council of Science and Technology (CONACYT) (Mexico)

Grant/Contract Number:: 251801; IN-101916

OSTI ID:: 1399479

Report Number(s):: NETL-PUB-21003

Journal Information:: Journal of Physical Chemistry. C, Vol. 121, Issue 6; ISSN 1932-7447

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 38 works

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References (40)

Post-Combustion CO₂ Capture Using Solid Sorbents: A Review Samanta, Arunkumar; Zhao, An; Shimizu, George K. H. Industrial & Engineering Chemistry Research, Vol. 51, Issue 4, p. 1438-1463 https://doi.org/10.1021/ie200686q	journal	September 2011
Citrate Sol–Gel Method for the Preparation of Sodium Zirconate for High-Temperature CO ₂ Sorption Jo, Hyun Geun; Yoon, Hyung Jin; Lee, Chan Hyun Industrial & Engineering Chemistry Research, Vol. 55, Issue 13 https://doi.org/10.1021/acs.iecr.5b04915	journal	March 2016
Recent advances in solid sorbents for CO ₂ capture and new development trends Wang, Junya; Huang, Liang; Yang, Ruoyan Energy Environ. Sci., Vol. 7, Issue 11 https://doi.org/10.1039/C4EE01647E	journal	January 2014
Review of recent advances in carbon dioxide separation and capture Kenarsari, Saeed Danaei; Yang, Dali; Jiang, Guodong RSC Advances, Vol. 3, Issue 45 https://doi.org/10.1039/c3ra43965h	journal	January 2013
Adsorbent Materials for Carbon Dioxide Capture from Large Anthropogenic Point Sources Choi, Sunho; Drese, Jeffrey H.; Jones, Christopher W. ChemSusChem, Vol. 2, Issue 9, p. 796-854 https://doi.org/10.1002/cssc.200900036	journal	September 2009
Ca-based synthetic materials with enhanced CO ₂ capture efficiency Valverde, Jose Manuel J. Mater. Chem. A, Vol. 1, Issue 3 https://doi.org/10.1039/C2TA00096B	journal	January 2013
Synthesis and CO ₂ Capture Properties of Nanocrystalline Lithium Zirconate Ochoa-Fernández, Esther; Rønning, Magnus; Grande, Tor Chemistry of Materials, Vol. 18, Issue 25 https://doi.org/10.1021/cm061515d	journal	December 2006
A Novel Method of CO[sub 2] Capture from High Temperature Gases Nakagawa, K. Journal of The Electrochemical Society, Vol. 145, Issue 4 https://doi.org/10.1149/1.1838462	journal	January 1998
Surfactant-Template/Ultrasound-Assisted Method for the Preparation of Porous Nanoparticle Lithium Zirconate Radfarnia, Hamid R.; Iliuta, Maria C. Industrial & Engineering Chemistry Research, Vol. 50, Issue 15 https://doi.org/10.1021/ie102417q	journal	August 2011
Compositional Effects of Nanocrystalline Lithium Zirconate on Its CO ₂ Capture Properties Ochoa-Fernández, Esther; Rønning, Magnus; Yu, Xiaofeng Industrial & Engineering Chemistry Research, Vol. 47, Issue 2 https://doi.org/10.1021/ie0705150	journal	January 2008
Analysis of the CO2 chemisorption reaction mechanism in lithium oxosilicate (Li8SiO6): a new option for high-temperature CO2 capture Durán-Muñoz, Fernando; Romero-Ibarra, Issis C.; Pfeiffer, Heriberto Journal of Materials Chemistry A, Vol. 1, Issue 12 https://doi.org/10.1039/c3ta00421j	journal	January 2013
A High Temperature Lithium Orthosilicate-Based Solid Absorbent for Post Combustion CO ₂ Capture Quinn, Robert; Kitzhoffer, Ronald J.; Hufton, Jeffrey R. Industrial & Engineering Chemistry Research, Vol. 51, Issue 27 https://doi.org/10.1021/ie300157m	journal	June 2012
Effect of the Particle Size of Quartz Powder on the Synthesis and CO ₂ Absorption Properties of Li ₄ SiO ₄ at High Temperature Xu, Hongliang; Cheng, Weigao; Jin, Xiaozeng Industrial & Engineering Chemistry Research, Vol. 52, Issue 5 https://doi.org/10.1021/ie301178p	journal	January 2013
Lithium orthosilicate for CO2 capture with high regeneration capacity: Kinetic study and modeling of carbonation and decarbonation reactions Amorim, Suélen M.; Domenico, Michele D.; Dantas, Tirzhá L. P. Chemical Engineering Journal, Vol. 283 https://doi.org/10.1016/j.cej.2015.07.083	journal	January 2016
Thermochemical Capture of Carbon Dioxide on Lithium Aluminates (LiAlO ₂ and Li ₅ AlO ₄ ): A New Option for the CO ₂ Absorption Ávalos-Rendón, Tatiana; Casa-Madrid, Julio; Pfeiffer, Heriberto The Journal of Physical Chemistry A, Vol. 113, Issue 25 https://doi.org/10.1021/jp902501v	journal	June 2009
Synthesis and CO ₂ Absorption Properties of Single-phase Li ₂ CuO ₂ as a CO ₂ Absorbent Matsukura, Yusuke; Okumura, Takeshi; Kobayashi, Ryota Chemistry Letters, Vol. 39, Issue 9 https://doi.org/10.1246/cl.2010.966	journal	September 2010
Fundamental research on gas–solid reaction between CO2 and Li2CuO2 linking application for solid CO2 absorbent Oh-ishi, Katsuyoshi; Matsukura, Yusuke; Okumura, Takeshi Journal of Solid State Chemistry, Vol. 211 https://doi.org/10.1016/j.jssc.2013.12.018	journal	March 2014
CO Chemical Capture on Lithium Cuprate, Through a Consecutive CO Oxidation and Chemisorption Bifunctional Process Lara-Garcia, Hugo; Alcántar-Vázquez, Brenda; Duan, Yuhua The Journal of Physical Chemistry C, Vol. 120, Issue 7 https://doi.org/10.1021/acs.jpcc.5b11147	journal	February 2016
CO2 Absorption and Desorption Abilities of Li2O–TiO2 Compounds Ueda, Shigeru; Inoue, Ryo; Sasaki, Kohei ISIJ International, Vol. 51, Issue 4 https://doi.org/10.2355/isijinternational.51.530	journal	January 2011
Analysis and perspectives concerning CO2 chemisorption on lithium ceramics using thermal analysis Ortiz-Landeros, José; Ávalos-Rendón, Tatiana L.; Gómez-Yáñez, Carlos Journal of Thermal Analysis and Calorimetry, Vol. 108, Issue 2 https://doi.org/10.1007/s10973-011-2063-y	journal	November 2011
Experimental and modeling kinetic study of the CO 2 absorption by Li 4 SiO 4 López Ortiz, A.; Escobedo Bretado, M. A.; Guzmán Velderrain, V. International Journal of Hydrogen Energy, Vol. 39, Issue 29 https://doi.org/10.1016/j.ijhydene.2014.05.015	journal	October 2014
Mass spectrometric study of the evaporation of Li5FeO4 as a corrosion product in the compatibility experiment of Li2O pellets with Fe-Ni-Cr alloys Takeshita, Hidefumi; Ohmichi, Toshihiko; Nasu, Shoichi Journal of Nuclear Materials, Vol. 78, Issue 2 https://doi.org/10.1016/0022-3115(78)90449-X	journal	December 1978
Electrochemical properties and Mössbauer effect of anti-fluorite type compound, LiFeO Hirano, A.; Matsumura, T.; Ueda, M. Solid State Ionics, Vol. 176, Issue 37-38 https://doi.org/10.1016/j.ssi.2005.08.013	journal	November 2005
Li ₂ O Removal from Li ₅ FeO ₄ : A Cathode Precursor for Lithium-Ion Batteries ^† Johnson, C. S.; Kang, S. -H.; Vaughey, J. T. Chemistry of Materials, Vol. 22, Issue 3 https://doi.org/10.1021/cm902713m	journal	February 2010
High-energy, efficient and transparent electrode for lithium batteries Martín, Francisco; Navarrete, Elena; Morales, Julián Journal of Materials Chemistry, Vol. 20, Issue 14 https://doi.org/10.1039/b920466k	journal	January 2010
Low temperature synthesis of Fe2O3 and LiFeO2 as cathode materials for lithium-ion batteries Li, Keyan; Chen, Hao; Shua, Fenfen Electrochimica Acta, Vol. 136 https://doi.org/10.1016/j.electacta.2014.05.068	journal	August 2014
CO2 absorption and structural phase transition of .ALPHA.-LiFeO2 Yanase, Ikuo; Kameyama, Akihiro; Kobayashi, Hidehiko Journal of the Ceramic Society of Japan, Vol. 118, Issue 1373 https://doi.org/10.2109/jcersj2.118.48	journal	January 2010
CO2 Absorption Properties of Lithium Ferrite for Application as a High-Temperature CO2 Absorbent Kato, Masahiro; Essaki, Kenji; Nakagawa, Kazuaki Journal of the Ceramic Society of Japan, Vol. 113, Issue 1322 https://doi.org/10.2109/jcersj.113.684	journal	January 2005
Structural and CO ₂ capture analyses of the Li _1+x FeO ₂ (0 ≤ x ≤ 0.3) system: effect of different physicochemical conditions Gomez-Garcia, J. Francisco; Pfeiffer, Heriberto RSC Advances, Vol. 6, Issue 113 https://doi.org/10.1039/C6RA23329E	journal	January 2016
Ab initio thermodynamic approach to identify mixed solid sorbents for CO2 capture technology Duan, Yuhua Frontiers in Environmental Science, Vol. 3 https://doi.org/10.3389/fenvs.2015.00069	journal	October 2015
Electronic Structure, Phonon Dynamical Properties, and ${CO}_{2}$ Capture Capability of ${Na}_{2 - x} M_{x} Zr O_{3}$ ( $M = Li$ ,K): Density-Functional Calculations and Experimental Validations Duan, Yuhua; Lekse, Jonathan; Wang, Xianfeng Physical Review Applied, Vol. 3, Issue 4 https://doi.org/10.1103/PhysRevApplied.3.044013	journal	April 2015
Neues �ber Oxoferrate(III). I. Zur Kenntnis von Li5FeO4 [1] Mit einer Notiz �ber Mischkristalle Na5Fe1?xGaxO4 Luge, R.; Hoppe, R. Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 513, Issue 6 https://doi.org/10.1002/zaac.19845130615	journal	June 1984
Ab initiomolecular dynamics for liquid metals Kresse, G.; Hafner, J. Physical Review B, Vol. 47, Issue 1, p. 558-561 https://doi.org/10.1103/PhysRevB.47.558	journal	January 1993
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set Kresse, G.; Furthmüller, J. Computational Materials Science, Vol. 6, Issue 1, p. 15-50 https://doi.org/10.1016/0927-0256(96)00008-0	journal	July 1996
Thermal Stability and High-Temperature Carbon Dioxide Sorption on Hexa-lithium Zirconate (Li₆Zr₂O₇) Pfeiffer, Heriberto; Bosch, Pedro Chemistry of Materials, Vol. 17, Issue 7 https://doi.org/10.1021/cm047897+	journal	March 2005
Preparation of nanocrystalline Na2ZrO3 for high-temperature CO2 acceptors: chemistry and mechanism Zhao, Tiejun; Rønning, Magnus; Chen, De Journal of Energy Chemistry, Vol. 22, Issue 3 https://doi.org/10.1016/S2095-4956(13)60050-9	journal	May 2013
Unexpected highly reversible topotactic CO ₂ sorption/desorption capacity for potassium dititanate Zheng, Qianwen; Huang, Liang; Zhang, Yu Journal of Materials Chemistry A, Vol. 4, Issue 33 https://doi.org/10.1039/C6TA04117E	journal	January 2016
Facile synthesis of macroporous Li4SiO4 with remarkably enhanced CO2 adsorption kinetics Kim, Hyeonbin; Jang, Hee Dong; Choi, Minkee Chemical Engineering Journal, Vol. 280 https://doi.org/10.1016/j.cej.2015.05.127	journal	November 2015
Synthesis of macroporous Li 4 SiO 4 via a citric acid-based sol–gel route coupled with carbon coating and its CO 2 chemisorption properties Wang, Ke; Yin, Zeguang; Zhao, Pengfei Ceramics International, Vol. 42, Issue 2 https://doi.org/10.1016/j.ceramint.2015.10.083	journal	February 2016
High and efficient Li2CuO2-CO2 chemisorption using different partial pressures and enhancement produced by the oxygen addition Lara-García, Hugo A.; Pfeiffer, Heriberto Chemical Engineering Journal, Vol. 313 https://doi.org/10.1016/j.cej.2016.11.029	journal	April 2017

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Li5FeO4
CO2 chemisorption
thermokinetic analysis
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Title: Analysis of the CO2 Chemisorption in Li5FeO4, a New High Temperature CO2 Captor Material. Effect of the CO2 and O2 Partial Pressures

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Title: Analysis of the CO₂ Chemisorption in Li₅FeO₄, a New High Temperature CO₂ Captor Material. Effect of the CO₂ and O₂ Partial Pressures