Bridging Zirconia Nodes within a Metal–Organic Framework via Catalytic Ni-Hydroxo Clusters to Form Heterobimetallic Nanowires

Platero-Prats, Ana E.; League, Aaron B.; Bernales, Varinia; Ye, Jingyun; Gallington, Leighanne C.; Vjunov, Aleksei; Schweitzer, Neil M.; Li, Zhanyong; Zheng, Jian; Mehdi, B. Layla; Stevens, Andrew J.; Dohnalkova, Alice; Balasubramanian, Mahalingam; Farha, Omar K.; Hupp, Joseph T.; Browning, Nigel D.; Fulton, John L.; Camaioni, Donald M.; Lercher, Johannes A.; Truhlar, Donald G.; Gagliardi, Laura; Cramer, Christopher J.; Chapman, Karena W.

doi:10.1021/jacs.7b04997

Title: Bridging Zirconia Nodes within a Metal–Organic Framework via Catalytic Ni-Hydroxo Clusters to Form Heterobimetallic Nanowires

Journal Article · Tue Jul 11 00:00:00 EDT 2017 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.7b04997· OSTI ID:1398808

^[1]; League, Aaron B. ^[2]; Bernales, Varinia ^[2]; Ye, Jingyun ^[2];

^[1]; Vjunov, Aleksei ^[3]; Schweitzer, Neil M. ^[4];

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^[3]; Mehdi, B. Layla ^[6]; Stevens, Andrew J. ^[3]; Dohnalkova, Alice ^[7]; Balasubramanian, Mahalingam ^[1];

^[8];

^[5]; Browning, Nigel D. ^[9]; Fulton, John L. ^[3]; Camaioni, Donald M. ^[3];

^[10];

^[2] more »

Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS), X-ray Science Division
Univ. of Minnesota, Minneapolis, MN (United States). Dept. of Chemistry, Minnesota Supercomputing Inst. and Chemical Theory Center
Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Inst. for Integrated Catalysis
Northwestern Univ., Evanston, IL (United States). Dept. of Chemical and Biological Engineering
Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry
Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Physical and Computational Science Directorate
Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Environmental Molecular Sciences Lab. (EMSL)
Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry; King Abdulaziz Univ., Jeddah (Saudi Arabia). Dept. of Chemistry
Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Physical and Computational Science Directorate; Univ. of Washington, Seattle, WA (United States). Dept. of Materials Science and Engineering
Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Inst. for Integrated Catalysis; Technische Univ. Munchen, Garching (Germany). Dept. of Chemistry and Catalysis Research Inst.

Metal-organic frameworks (MOFs), with their well-ordered pore networks and tunable surface chemistries, offer a versatile platform for preparing well-defined nanostructures wherein functionality such as catalysis can be incorporated. Notably, atomic layer deposition (ALD) in MOFs has recently emerged as a versatile approach to functionalize MOF surfaces with a wide variety of catalytic metal-oxo species. Understanding the structure of newly deposited species and how they are tethered within the MOF is critical to understanding how these components couple to govern the active material properties. By combining local and long-range structure probes, including X-ray absorption spectroscopy, pair distribution function analysis and difference envelope density analysis, with electron microscopy imag-ing and computational modeling, we resolve the precise atomic structure of metal-oxo species deposited in the MOF NU-1000 through ALD. These analyses demonstrate that deposition of NiO_xH_y clusters occurs selectively within the smallest pores of NU-1000, between the zirconia nodes, serving to connect these nodes along the c-direction to yield hetero-bimetallic metal-oxo nanowires. Finally, this bridging motif perturbs the NU-1000 framework structure, drawing the zirconia nodes closer together, and also underlies the sintering-resistance of these clusters during the hydrogenation of light olefins.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Energy Frontier Research Center for Inorganometallic Catalyst Design (ICDC); Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Biological and Environmental Research (BER)

Grant/Contract Number:: AC02-06CH11357; SC0012702; AC05-76RL01830

OSTI ID:: 1398808

Journal Information:: Journal of the American Chemical Society, Vol. 139, Issue 30; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 65 works

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