Olefin‐Supported Rhenium(III) Terminal Oxo Complexes Generated by Nucleophilic Addition to a Cyclopentadienyl Ligand

Lohrey, Trevor D.; Bergman, Robert G.; Arnold, John

doi:10.1002/anie.201707957

Olefin‐Supported Rhenium(III) Terminal Oxo Complexes Generated by Nucleophilic Addition to a Cyclopentadienyl Ligand

Journal Article · Fri Oct 06 00:00:00 EDT 2017 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.201707957· OSTI ID:1398286

^[1]; Bergman, Robert G. ^[2]; ^[1]

Department of Chemistry University of California, Berkeley 420 Latimer Hall Berkeley CA 94720 USA, Chemical Sciences Division Lawrence Berkeley National Laboratory 1 Cyclotron Road Berkeley CA 94720 USA
Department of Chemistry University of California, Berkeley 420 Latimer Hall Berkeley CA 94720 USA

Abstract

The reactivity of the oxo Re ^V β‐diketiminate, OReCl ₂ (BDI), with various cyclopentadienide (Cp) sources has been investigated. As a result, we have developed a route to a new class of terminal oxo complexes of Re ^III supported by olefin moieties of substituted cyclopentadienes. The success of this pathway is due to the electrophilic nature of the Cp ligand in the cation, [ORe(η ⁵ ‐Cp)(BDI)] ⁺ ( 3 ⁺ ), which allows for nucleophilic attack by a variety of reagents under mild conditions. In contrast, ^t BuNC was found to attack at the oxo moiety to produce isocyanate by oxygen atom transfer.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1398286

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Journal Issue: 45 Vol. 56; ISSN 1433-7851

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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Olefin‐Supported Rhenium(III) Terminal Oxo Complexes Generated by Nucleophilic Addition to a Cyclopentadienyl Ligand

Journal Article · Thu Oct 05 20:00:00 EDT 2017 · Angewandte Chemie · OSTI ID:1398285

Olefin‐Supported Rhenium(III) Terminal Oxo Complexes Generated by Nucleophilic Addition to a Cyclopentadienyl Ligand

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