PLZT Film Capacitors for Power Electronics and Energy Storage Applications

Ma, Beihai; Hu, Zhongqiang; Koritala, Rachel E.; Lee, Tae H.; Dorris, Stephen E.; Balachandran, Uthamalingam

doi:10.1007/s10854-015-3025-0

PLZT Film Capacitors for Power Electronics and Energy Storage Applications

Conference · Tue Dec 01 04:00:00 EST 2015

DOI:https://doi.org/10.1007/s10854-015-3025-0· OSTI ID:1398273

Ma, Beihai; Hu, Zhongqiang; Koritala, Rachel E.; Lee, Tae H.; Dorris, Stephen E.; Balachandran, Uthamalingam

Ceramic film capacitors with high dielectric constant and high breakdown strength hold special promise for applications demanding high power density. By means of chemical solution deposition, we deposited ≈2-μm-thick films of lanthanum-doped lead zirconate titanate (PLZT) on LaNiO3-buffered Ni (LNO/Ni) foils and platinized silicon (PtSi) substrates. The dielectric properties and energy storage performance of the resulting samples were determined under a high level of applied electric field. X-ray diffraction stress analysis revealed that PLZT on LNO/Ni bears a compressive stress of ≈370 MPa while PLZT on PtSi endures a tensile stress of ≈250 MPa. Compressive stress was found to lead to heightened polarization, improved tunability, increased irreversible domain wall motion, and enhanced breakdown strength for PLZT deposited on the LNO/Ni as compared with the PtSi substrate. We observed a tunability of ≈55 and ≈40 % at room temperature under 100 kV/cm applied field, remanent polarization of ≈23.5 and ≈7.4 µC/cm^2, coercive electric field of ≈25.6 and ≈21.1 kV/cm, and dielectric breakdown strength of ≈2.6 and ≈1.5 MV/cm for PLZT deposited on LNO/Ni foils and PtSi substrates, respectively. A high recoverable energy density of ≈85 J/cm^3 and energy conversion efficiency of ≈65 % were measured on the PLZT film grown on LNO/Ni.

View Conference

Research Organization:: Argonne National Laboratory (ANL)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE) - Office of Vehicle Technology

DOE Contract Number:: AC02-06CH11357

OSTI ID:: 1398273

Country of Publication:: United States

Language:: English

References (20)

Processing Effects for Integrated PZT: Residual Stress, Thickness, and Dielectric Properties Ong, Ryan J.; Payne, David A.; Sottos, Nancy R. Journal of the American Ceramic Society, Vol. 88, Issue 10 https://doi.org/10.1111/j.1551-2916.2005.00641.x	journal	October 2005
Dielectric strength and reliability of ferroelectric PLZT films deposited on nickel substrates Ma, Beihai; Narayanan, Manoj; Balachandran, U. (Balu) Materials Letters, Vol. 63, Issue 15, p. 1353-1356 https://doi.org/10.1016/j.matlet.2009.03.021	journal	June 2009
Collective dynamics underpins Rayleigh behavior in disordered polycrystalline ferroelectrics Bintachitt, P.; Jesse, S.; Damjanovic, D. Proceedings of the National Academy of Sciences, Vol. 107, Issue 16 https://doi.org/10.1073/pnas.0913172107	journal	April 2010
High energy-storage performance in Pb _0.91 La _0.09 (Ti _0.65 Zr _0.35 )O ₃ relaxor ferroelectric thin films Hao, Xihong; Wang, Ying; Yang, Jichun Journal of Applied Physics, Vol. 112, Issue 11 https://doi.org/10.1063/1.4768461	journal	December 2012
Pyrochlore to perovskite phase transformation in sol‐gel derived lead‐zirconate‐titanate thin films Kwok, Chi Kong; Desu, Seshu B. Applied Physics Letters, Vol. 60, Issue 12 https://doi.org/10.1063/1.107312	journal	March 1992
Improved dielectric properties of lead zirconate titanate thin films deposited on metal foils with LaNiO₃ buffer layers Zou, Q.; Ruda, H. E.; Yacobi, B. G. Applied Physics Letters, Vol. 78, Issue 9, p. 1282-1284 https://doi.org/10.1063/1.1350425	journal	February 2001
Effects of Residual Stress on the Electrical Properties of PZT Films Lee, Jae-Wung; Park, Chee-Sung; Kim, Miyoung Journal of the American Ceramic Society, Vol. 90, Issue 4 https://doi.org/10.1111/j.1551-2916.2007.01610.x	journal	April 2007
A comprehensive review on the progress of lead zirconate-based antiferroelectric materials Hao, Xihong; Zhai, Jiwei; Kong, Ling Bing Progress in Materials Science, Vol. 63 https://doi.org/10.1016/j.pmatsci.2014.01.002	journal	June 2014
Domain wall contributions to the properties of piezoelectric thin films Bassiri-Gharb, Nazanin; Fujii, Ichiro; Hong, Eunki Journal of Electroceramics, Vol. 19, Issue 1 https://doi.org/10.1007/s10832-007-9001-1	journal	March 2007
Thin-film piezoelectric MEMS Eom, Chang-Beom; Trolier-McKinstry, Susan MRS Bulletin, Vol. 37, Issue 11 https://doi.org/10.1557/mrs.2012.273	journal	November 2012
Chemical solution deposition of ferroelectric lead lanthanum zirconate titanate films on base-metal foils Ma, Beihai; Kwon, Do-Kyun; Narayanan, Manoj Journal of Electroceramics, Vol. 22, Issue 4, p. 383-389 https://doi.org/10.1007/s10832-007-9410-1	journal	January 2008
Enhanced dielectric properties of Pb _0.92 La _0.08 Zr _0.52 Ti _0.48 O ₃ films with compressive stress Ma, Beihai; Liu, Shanshan; Tong, Sheng Journal of Applied Physics, Vol. 112, Issue 11 https://doi.org/10.1063/1.4768926	journal	December 2012
Nonlinear dielectric thin films for high-power electric storage with energy density comparable with electrochemical supercapacitors No authors listed IEEE Transactions on Ultrasonics, Ferroelectrics and Frequency Control, Vol. 58, Issue 9 https://doi.org/10.1109/TUFFC.2011.2039	journal	September 2011
The Rayleigh law in piezoelectric ceramics Damjanovic, Dragan; Demartin, Marlyse Journal of Physics D: Applied Physics, Vol. 29, Issue 7 https://doi.org/10.1088/0022-3727/29/7/046	journal	July 1996
High Energy Density Nanocomposites Based on Surface-Modified BaTiO ₃ and a Ferroelectric Polymer Kim, Philseok; Doss, Natalie M.; Tillotson, John P. ACS Nano, Vol. 3, Issue 9 https://doi.org/10.1021/nn9006412	journal	August 2009
A Dielectric Polymer with High Electric Energy Density and Fast Discharge Speed Chu, B. Science, Vol. 313, Issue 5785 https://doi.org/10.1126/science.1127798	journal	July 2006
Nonlinear dielectric ceramics and their applications to capacitors and tunable dielectrics No authors listed IEEE Electrical Insulation Magazine, Vol. 27, Issue 2 https://doi.org/10.1109/MEI.2011.5739422	journal	March 2011
Dielectric properties and energy storage capability of antiferroelectric Pb _0.92 La _0.08 Zr _0.95 Ti _0.05 O ₃ film-on-foil capacitors Ma, Beihai; Kwon, Do-Kyun; Narayanan, Manoj Journal of Materials Research, Vol. 24, Issue 9 https://doi.org/10.1557/jmr.2009.0349	journal	September 2009
Critical thickness for extrinsic contributions to the dielectric and piezoelectric response in lead zirconate titanate ultrathin films Bastani, Yaser; Schmitz-Kempen, Thorsten; Roelofs, Andreas Journal of Applied Physics, Vol. 109, Issue 1 https://doi.org/10.1063/1.3527970	journal	January 2011
Temperature-dependent energy storage properties of antiferroelectric Pb _0.96 La _0.04 Zr _0.98 Ti _0.02 O ₃ thin films Hu, Zhongqiang; Ma, Beihai; Koritala, R. E. Applied Physics Letters, Vol. 104, Issue 26 https://doi.org/10.1063/1.4887066	journal	June 2014

Similar Records

Fabrication of antiferroelectric PLZT films on metal foils.

Journal Article · Wed Dec 31 23:00:00 EST 2008 · Mater. Res. Bull. · OSTI ID:942105

Fabrication of antiferroelectric PLZT films on metal foils

Journal Article · Wed Jan 07 23:00:00 EST 2009 · Materials Research Bulletin · OSTI ID:21195051

Fabrication and dielectric property of ferroelectric PLZT films grown on metal foils.

Journal Article · Fri Jul 01 00:00:00 EDT 2011 · Mater. Res. Bull. · OSTI ID:1014837

Related Subjects

Ferroelectricity
PLZT
ceramic film capacitor
energy storage
residual stress

PLZT Film Capacitors for Power Electronics and Energy Storage Applications

Citation Formats

References (20)

Similar Records

Related Subjects