skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Investigation of the two- and three-fragment photodissociation of the tert -butyl peroxy radical at 248 nm

Journal Article · · Journal of Chemical Physics
DOI:https://doi.org/10.1063/1.4994713· OSTI ID:1398133

Sponsoring Organization:
USDOE
Grant/Contract Number:
AC02-05CH11231
OSTI ID:
1398133
Journal Information:
Journal of Chemical Physics, Journal Name: Journal of Chemical Physics Vol. 147 Journal Issue: 13; ISSN 0021-9606
Publisher:
American Institute of PhysicsCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 6 works
Citation information provided by
Web of Science

References (51)

New Scale Factors for Harmonic Vibrational Frequencies Using the B3LYP Density Functional Method with the Triple-ζ Basis Set 6-311+G(d,p) journal March 2005
The Kinetics of the Recombination of Methyl Radicals and Iodine Atoms. journal June 1951
Near-IR Cavity Ringdown Spectroscopy and Kinetics of the Isomers and Conformers of the Butyl Peroxy Radical journal December 2005
Characterization of the t -Butyl Radical and Its Elusive Anion journal October 2012
Tropospheric Air Pollution: Ozone, Airborne Toxics, Polycyclic Aromatic Hydrocarbons, and Particles journal May 1997
Further studies into the photodissociation pathways of phenylperoxyl radicals journal September 2015
Photo induced three body decay journal January 1997
Fast beam photodissociation of the CH 2 NO 2 radical journal December 1993
A beam-modulated time-of-flight mass spectrometer. I. Theoretical considerations journal August 1973
Infrared frequency-modulation probing of product formation in alkyl + O2 reactions. Part IV.For Part III see ref. 12. Reactions of propyl and butyl radicals with O2Electronic Supplementary Information available. See http://www.rsc.org/suppdata/fd/b1/b102237g/ journal October 2001
Directly measuring reaction kinetics of ˙QOOH – a crucial but elusive intermediate in hydrocarbon autoignition journal January 2013
Photodissociation Dynamics of the Thiophenoxy Radical at 248, 193, and 157 nm journal May 2013
Reconstruction of Abel-transformable images: The Gaussian basis-set expansion Abel transform method journal July 2002
UV absorption cross sections and reaction kinetics and mechanisms for peroxy radicals in the gas phase journal June 1992
Thermochemical studies of carbonyl compounds. 5. Enthalpies of reduction of carbonyl groups journal April 1991
Three-Body Dissociative Charge Exchange Dynamics of sym -Triazine journal April 2009
Effect of peroxy radical reactions on the predicted concentrations of ozone, nitrogenous compounds, and radicals journal September 1996
Kinetics of elementary reactions in low-temperature autoignition chemistry journal August 2011
Study of the thermochemistry of the ethyl + molecular oxygen .dblharw. ethylperoxy (C2H5O2) and tert-butyl + molecular oxygen .dblharw. tert-butylperoxy (tert-C4H9O2) reactions and of the trend in the alkylperoxy bond strengths journal January 1986
Photoelectron spectroscopy, gas phase acidity, and thermochemistry of tert -butyl hydroperoxide: Mechanisms for the rearrangement of peroxyl radicals journal December 1998
Photodissociation dynamics of the N 3 radical journal August 1993
Heats of combustion, formation, and insomerization of ten C4 hydrocarbons journal February 1951
Dalitz plot analysis of three-body fragmentation of Na[sub 3][sup +] excited by He impact journal January 2002
Algorithm 448: number of multiply-restricted partitions journal June 1973
Three-body photodissociation dynamics of (CO2) journal August 2011
Kinetics and thermochemistry of R + hydrogen bromide .dblarw. RH + bromine atom reactions: determinations of the heat of formation of ethyl, isopropyl, sec-butyl and tert-butyl radicals journal November 1992
Alkylperoxy and alkyl radicals. 5. IR spectra and UV photolysis of tert-butylperoxy radicals in argon plus oxygen matrixes journal November 1987
Slow photoelectron velocity-map imaging of cold tert -butyl peroxide journal July 2017
Two- and three-body photodissociation dynamics of diiodobromide (I 2 Br ) anion journal April 2011
Investigation of 3-fragment photodissociation of O 3 at 193.4 and 157.6 nm by coincident measurements journal June 2014
Ground and lower excited states of methylperoxy radical, CH3O2: a computational investigation journal March 1990
Photodissociation Dynamics of HO2 at 220 nm: Determination of the O(1D):O(3P) Branching Ratio journal December 1994
A short pulse (7 μs FWHM) and high repetition rate (dc-5kHz) cantilever piezovalve for pulsed atomic and molecular beams journal November 2009
A beam-modulated time-of-flight mass spectrometer. II. Experimental work journal May 1974
Photodissociation dynamics of the methyl perthiyl radical at 248 and 193 nm using fast-beam photofragment translational spectroscopy journal July 2016
Multiple Explosion Pathways of the Deuterated Benzene Trication in 9-fs Intense Laser Fields journal March 2009
Slow photoelectron velocity-map imaging spectroscopy of C2N−, C4N−, and C6N− journal February 2009
Measured Correlated Motion of Three Massive Coulomb Interacting Particles journal December 1997
Direct Observation of Photodissociation Products from Phenylperoxyl Radicals Isolated in the Gas Phase journal June 2013
Atmospheric chemistry of small organic peroxy radicals journal June 2001
The 248-nm photofragmentation of the peroxymethyl radical journal April 1990
Analysis of kinetic energy release distributions by the maximum entropy method journal March 2006
Fast beam photodissociation spectroscopy and dynamics of the vinoxy radical journal February 1997
Role of O 2 + QOOH in Low-Temperature Ignition of Propane. 1. Temperature and Pressure Dependent Rate Coefficients journal March 2012
CXII. On the analysis of τ-meson data and the nature of the τ-meson journal October 1953
Hydrocarbon Bond Dissociation Energies journal October 1982
Active Thermochemical Tables:  Accurate Enthalpy of Formation of Hydroperoxyl Radical, HO 2 journal June 2006
Thermodynamic Properties and Kinetic Parameters for Cyclic Ether Formation from Hydroperoxyalkyl Radicals journal June 2003
Analysis of Tertiary Butyl Radical + O 2 , Isobutene + HO 2 , Isobutene + OH, and Isobutene−OH Adducts + O 2 :  A Detailed Tertiary Butyl Oxidation Mechanism journal December 1999
Photodissociation of tert-butyl hypochlorite and decomposition of the tert-butoxy radical fragment journal June 1993
The fate of the tert-butyl radical in low-temperature autoignition reactions journal May 2017

Similar Records

Photodissociation dynamics of the simplest alkyl peroxy radicals, CH3OO and C2H5OO, at 248 nm
Journal Article · Sun Jan 28 00:00:00 EST 2018 · Journal of Chemical Physics · OSTI ID:1398133

Photodissociation dynamics of the tert-butyl perthiyl radical
Journal Article · Mon Jun 22 00:00:00 EDT 2020 · Journal of Chemical Physics · OSTI ID:1398133

Photodissociation of iso-propoxy (i-C3H7O) radical at 248 nm
Journal Article · Mon Jul 27 00:00:00 EDT 2020 · Physical Chemistry Chemical Physics. PCCP · OSTI ID:1398133

Related Subjects