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Title: Bio-inspired surfactant assisted nano-catalyst impregnation of Solid-Oxide Fuel Cell (SOFC) electrodes

Journal Article · · Materials Letters
 [1];  [2];  [3];  [4];  [1]
  1. West Virginia Univ., Morgantown, WV (United States); National Energy Technology Lab. (NETL), Morgantown, WV (United States)
  2. West Virginia Univ., Morgantown, WV (United States)
  3. National Energy Technology Lab. (NETL), Morgantown, WV (United States); AECOM/GES, Morgantown, WV (United States)
  4. National Energy Technology Lab. (NETL), Morgantown, WV (United States)

A bio-inspired surfactant was utilized to assist in the efficient impregnation of a nano-CeO₂ catalyst throughout both porous Solid Oxide Fuel Cells (SOFC’s) electrodes simultaneously. The process included the initial modification of electrode pore walls with a polydopamine film. The cell was then submersed into a cerium salt solution. The amount of nano-CeO₂ deposited per impregnation step increased by 3.5 times by utilizing this two-step protocol in comparison to a conventional drip impregnation method. The impregnated cells exhibited a 20% higher power density than a baseline cell without the nano-catalyst at 750°C (using humid H₂ fuel).

Research Organization:
National Energy Technology Lab. (NETL), Morgantown, WV (United States)
Sponsoring Organization:
USDOE
Grant/Contract Number:
DE-FE0004000; FE0004000
OSTI ID:
1258574
Alternate ID(s):
OSTI ID: 1397540
Report Number(s):
A-CONTR-PUB-057; PII: S0167577X15308107
Journal Information:
Materials Letters, Vol. 164, Issue C; ISSN 0167-577X
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 6 works
Citation information provided by
Web of Science

References (23)

A review of wet impregnation—An alternative method for the fabrication of high performance and nano-structured electrodes of solid oxide fuel cells journal February 2006
Synthesis of Dispersed and Contiguous Nanoparticles in Solid Oxide Fuel Cell Electrodes journal October 2008
Ceria Nanocoating for Sulfur Tolerant Ni-Based Anodes of Solid Oxide Fuel Cells journal January 2007
A Study of SOFC Anodes Based on Cu-Ni and Cu-Co Bimetallics in CeO[sub 2]-YSZ journal January 2004
Effect of Precious-Metal Dopants on SOFC Anodes for Direct Utilization of Hydrocarbons journal January 2003
Ni/YSZ and Ni–CeO2/YSZ anodes prepared by impregnation for solid oxide fuel cells journal June 2007
Development of Nanostructured and Palladium Promoted (La,Sr)MnO[sub 3]-Based Cathodes for Intermediate-Temperature SOFCs journal January 2008
Fabrication and Performance of GDC-Impregnated (La,Sr)MnO[sub 3] Cathodes for Intermediate Temperature Solid Oxide Fuel Cells journal January 2005
Electrochemical characteristics of solid oxide fuel cell cathodes prepared by infiltrating (La,Sr)MnO3 nanoparticles into yttria-stabilized bismuth oxide backbones journal August 2010
Long-Term Stability of SOFC Composite Cathode Activated by Electrocatalyst Infiltration journal January 2012
Nanoscale and nano-structured electrodes of solid oxide fuel cells by infiltration: Advances and challenges journal January 2012
Measurements and Modeling of Sm[sub 0.5]Sr[sub 0.5]CoO[sub 3−x]–Ce[sub 0.9]Gd[sub 0.1]O[sub 1.95] SOFC Cathodes Produced Using Infiltrate Solution Additives journal January 2010
Active Cu/ZnO and Cu/ZnO/Al2O3 catalysts prepared by homogeneous precipitation method in steam reforming of methanol journal June 2004
Mussel-Inspired Surface Chemistry for Multifunctional Coatings journal October 2007
Polydopamine and Its Derivative Materials: Synthesis and Promising Applications in Energy, Environmental, and Biomedical Fields journal February 2014
Direct foamed and nano-catalyst impregnated solid-oxide fuel cell (SOFC) cathodes journal March 2013
Stability and robustness of metal-supported SOFCs journal January 2008
Thermal stability of nanometer-sized NiO and Sm-doped ceria powders journal September 2002
Microstrain and self-limited grain growth in nanocrystalline ceria ceramics journal April 2006
Stability and Performance of LSCF-Infiltrated SOFC Cathodes: Effect of Nano-Particle Coarsening journal April 2011
Evaluation and Modeling of the Cell Resistance in Anode-Supported Solid Oxide Fuel Cells journal January 2008
Identification of O2 reduction processes at yttria stabilized zirconia|doped lanthanum manganite interface journal September 2003
Time-Dependent Electrode Performance Changes in Intermediate Temperature Solid Oxide Fuel Cells journal January 2010

Cited By (1)

Versatile Surface Modification Using Polydopamine and Related Polycatecholamines: Chemistry, Structure, and Applications journal September 2017