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Prospects for spinel-stabilized, high-capacity lithium-ion battery cathodes

Journal Article · · Journal of Power Sources
 [1];  [1];  [2];  [1];  [3];  [1];  [3];  [1]
  1. Argonne National Lab. (ANL), Argonne, IL (United States). Electrochemical Energy Storage Dept.
  2. Argonne National Lab. (ANL), Argonne, IL (United States). Materials Engineering Research Facility
  3. Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source
+ Show Author Affiliations
Herein we report early results on efforts to optimize the electrochemical performance of a cathode composed of a lithium- and manganese-rich “layered-layered-spinel” material for lithium-ion battery applications. Pre-pilot scale synthesis leads to improved particle properties compared with lab-scale efforts, resulting in high capacities (≳200 mAh/g) and good energy densities (>700 Wh/kg) in tests with lithium-ion cells. Subsequent surface modifications give further improvements in rate capabilities and high-voltage stability. These results bode well for advances in the performance of this class of lithium- and manganese-rich cathode materials.
Research Organization:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE); USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Grant/Contract Number:
AC02-06CH11357
OSTI ID:
1392305
Alternate ID(s):
OSTI ID: 1397467
Journal Information:
Journal of Power Sources, Journal Name: Journal of Power Sources Journal Issue: C Vol. 334; ISSN 0378-7753
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English

References (38)

Structural and Electrochemical Study of Al 2 O 3 and TiO 2 Coated Li 1.2 Ni 0.13 Mn 0.54 Co 0.13 O 2 Cathode Material Using ALD journal June 2013
Structure and electrochemistry of lithium cobalt oxide synthesised at 400°C journal March 1992
Spinel versus layered structures for lithium cobalt oxide synthesised at 400°C journal March 1993
Lithium-cobalt-nickel-oxide cathode materials prepared at 400°C for rechargeable lithium batteries journal July 1992
Manganese oxides for lithium batteries journal January 1997
Lithium–manganese oxide electrodes with layered–spinel composite structures xLi2MnO3·(1−x)Li1+yMn2−yO4 (0 journal May 2005
Lithium–manganese–nickel-oxide electrodes with integrated layered–spinel structures for lithium batteries journal February 2007
Enhancing the rate capability of high capacity xLi2MnO3 · (1−x)LiMO2 (M=Mn, Ni, Co) electrodes by Li–Ni–PO4 treatment journal April 2009
Li2MnO3-based composite cathodes for lithium batteries: A novel synthesis approach and new structures journal October 2011
Effect of interface modifications on voltage fade in 0.5Li2MnO3·0.5LiNi0.375Mn0.375Co0.25O2 cathode materials journal March 2014
Effect of lithium content on spinel phase evolution in the composite material LixNi0.25Co0.10Mn0.65O(3.4+x)/2 (0.8≤x≤1.6) for Li-ion batteries journal October 2016
Review of the U.S. Department of Energy’s “Deep Dive” Effort to Understand Voltage Fade in Li- and Mn-Rich Cathodes journal October 2015
Amorphous Metal Fluoride Passivation Coatings Prepared by Atomic Layer Deposition on LiCoO 2 for Li-Ion Batteries journal March 2015
Designing High-Capacity, Lithium-Ion Cathodes Using X-ray Absorption Spectroscopy journal December 2011
Neutron Diffraction and Magnetic Susceptibility Studies on a High-Voltage Li 1.2 Mn 0.55 Ni 0.15 Co 0.10 O 2 Lithium Ion Battery Cathode: Insight into the Crystal Structure journal September 2013
Unraveling the Voltage-Fade Mechanism in High-Energy-Density Lithium-Ion Batteries: Origin of the Tetrahedral Cations for Spinel Conversion journal October 2014
Demonstrating Oxygen Loss and Associated Structural Reorganization in the Lithium Battery Cathode Li[Ni0.2Li0.2Mn0.6]O2 journal June 2006
Re-entrant Lithium Local Environments and Defect Driven Electrochemistry of Li- and Mn-Rich Li-Ion Battery Cathodes journal February 2015
High-Energy Cathode Materials (Li 2 MnO 3 –LiMO 2 ) for Lithium-Ion Batteries journal March 2013
Charge-compensation in 3d-transition-metal-oxide intercalation cathodes through the generation of localized electron holes on oxygen journal March 2016
The structural and chemical origin of the oxygen redox activity in layered and cation-disordered Li-excess cathode materials journal May 2016
First-charge instabilities of layered-layered lithium-ion-battery materials journal January 2015
Performance and design considerations for lithium excess layered oxide positive electrode materials for lithium ion batteries journal January 2016
Advances in manganese-oxide ‘composite’ electrodes for lithium-ion batteries
  • Thackeray, Michael M.; Johnson, Christopher S.; Vaughey, John T.
  • Journal of Materials Chemistry, Vol. 15, Issue 23, p. 2257-2267 https://doi.org/10.1039/b417616m
journal March 2005
Li2MnO3-stabilized LiMO2 (M = Mn, Ni, Co) electrodes for lithium-ion batteries journal January 2007
High-capacity lithium insertion materials of lithium nickel manganese oxides for advanced lithium-ion batteries: toward rechargeable capacity more than 300 mA h g−1 journal January 2011
Electrical energy storage for transportation—approaching the limits of, and going beyond, lithium-ion batteries journal January 2012
Correlating cation ordering and voltage fade in a lithium–manganese-rich lithium-ion battery cathode oxide: a joint magnetic susceptibility and TEM study journal January 2013
Investigating phase transformation in the Li1.2Co0.1Mn0.55Ni0.15O2 lithium-ion battery cathode during high-voltage hold (4.5 V) via magnetic, X-ray diffraction and electron microscopy studies journal January 2013
Unlocking the Potential of Cation-Disordered Oxides for Rechargeable Lithium Batteries journal January 2014
Aluminum and Gallium Substitution into 0.5Li 2 MnO 3 ·0.5Li(Ni 0.375 Mn 0.375 Co 0.25 )O 2 Layered Composite and the Voltage Fade Effect journal December 2014
Voltage Fade of Layered Oxides: Its Measurement and Impact on Energy Density journal January 2013
Composite ‘Layered-Layered-Spinel’ Cathode Structures for Lithium-Ion Batteries journal November 2012
Quantifying Hysteresis and Voltage Fade in xLi 2 MnO 3 ● (1-x)LiMn 0.5 Ni 0.5 O 2 Electrodes as a Function of Li 2 MnO 3 Content journal December 2013
Advances in Stabilizing ‘Layered-Layered’ xLi2MnO3·(1-x)LiMO2(M=Mn, Ni, Co) Electrodes with a Spinel Component journal January 2014
Countering the Voltage Decay in High Capacity xLi 2 MnO 3 •(1–x)LiMO 2 Electrodes (M=Mn, Ni, Co) for Li + -Ion Batteries journal January 2012
First-Principles Calculations, Electrochemical and X-ray Absorption Studies of Li-Ni-PO 4 Surface-Treated x Li 2 MnO 3 ·(1− x )LiMO 2 (M = Mn, Ni, Co) Electrodes for Li-Ion Batteries journal January 2011
Solid State NMR Studies of Li 2 MnO 3 and Li-Rich Cathode Materials: Proton Insertion, Local Structure, and Voltage Fade journal November 2014

Cited By (4)

Separator modified by Y2O3 nanoparticles-Ketjen Black hybrid and its application in lithium-sulfur battery journal June 2017
Toward Low-Cost, High-Energy Density, and High-Power Density Lithium-Ion Batteries journal June 2017
Improvement of the electrochemical performance of a nickel rich LiNi 0.5 Co 0.2 Mn 0.3 O 2 cathode material by reduced graphene oxide/SiO 2 nanoparticle double-layer coating journal January 2019
The quest for manganese-rich electrodes for lithium batteries: strategic design and electrochemical behavior journal January 2018

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Related Subjects

25 ENERGY STORAGE
36 MATERIALS SCIENCE
battery
cathode
composite
lithium rich
lithium-ion
manganese rich
scale up