Electroreduction of CO 2 Catalyzed by a Heterogenized Zn–Porphyrin Complex with a Redox-Innocent Metal Center

Wu, Yueshen; Jiang, Jianbing; Weng, Zhe; Wang, Maoyu; Broere, Daniël L.  J.; Zhong, Yiren; Brudvig, Gary W.; Feng, Zhenxing; Wang, Hailiang

doi:10.1021/acscentsci.7b00160

Electroreduction of CO ₂ Catalyzed by a Heterogenized Zn–Porphyrin Complex with a Redox-Innocent Metal Center

Journal Article · Wed Jul 26 04:00:00 EDT 2017 · ACS Central Science

DOI:https://doi.org/10.1021/acscentsci.7b00160· OSTI ID:1397287

Wu, Yueshen ^[1]; Jiang, Jianbing ^[1]; Weng, Zhe ^[1]; Wang, Maoyu ^[2]; Broere, Daniël L. J. ^[3]; Zhong, Yiren ^[1]; ^[1]; ^[2]; ^[1]

Department of Chemistry, Yale University, New Haven, Connecticut 06520, United States; Energy Sciences Institute, Yale University, West Haven, Connecticut 06516, United States
School of Chemical, Biological, and Environmental Engineering, Oregon State University, Corvallis, Oregon 97331, United States
Department of Chemistry, Yale University, New Haven, Connecticut 06520, United States

Transition-metal-based molecular complexes are a class of catalyst materials for electrochemical CO2 reduction to CO that can be rationally designed to deliver high catalytic performance. One common mechanistic feature of these electrocatalysts developed thus far is an electrogenerated reduced metal center associated with catalytic CO2 reduction. Here we report a heterogenized zinc–porphyrin complex (zinc(II) 5,10,15,20-tetramesitylporphyrin) as an electrocatalyst that delivers a turnover frequency as high as 14.4 site–1 s–1 and a Faradaic efficiency as high as 95% for CO2 electroreduction to CO at -1.7 V vs the standard hydrogen electrode in an organic/water mixed electrolyte. While the Zn center is critical to the observed catalysis, in situ and operando X-ray absorption spectroscopic studies reveal that it is redox-innocent throughout the potential range. Cyclic voltammetry indicates that the porphyrin ligand may act as a redox mediator. Chemical reduction of the zinc–porphyrin complex further confirms that the reduction is ligand-based and the reduced species can react with CO2. This represents the first example of a transition-metal complex for CO2 electroreduction catalysis with its metal center being redox-innocent under working conditions.

Research Organization:: Yale Univ., New Haven, CT (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Chemical Sciences, Geosciences & Biosciences Division; National Science Foundation (NSF); American Chemical Society Petroleum Research Fund; Institute of International Education (IIE); TomKat Foundation; Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division and Advanced Photon Source; Dupont Research and Development, Wilmington, DE (United States). DuPont Experimental Station; Northwestern Univ., Evanston, IL (United States); Oregon State Univ., Corvallis, OR (United States); Netherlands Organization for Scientific Research (NWO)

DOE Contract Number:: FG02-07ER15909; AC02-06CH11357

OSTI ID:: 1397287

Journal Information:: ACS Central Science, Journal Name: ACS Central Science Journal Issue: 8 Vol. 3; ISSN 2374-7943

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: ENGLISH

References (41)

PRODUCTION OF CO AND CH ₄ IN ELECTROCHEMICAL REDUCTION OF CO ₂ AT METAL ELECTRODES IN AQUEOUS HYDROGENCARBONATE SOLUTION Hori, Yoshio; Kikuchi, Katsuhei; Suzuki, Shin Chemistry Letters, Vol. 14, Issue 11 https://doi.org/10.1246/cl.1985.1695	journal	November 1985
Catalysis of the electrochemical reduction of carbon dioxide by iron(“0”) porphyrins Hammouche, M.; Lexa, D.; Savéant, J. M. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 249, Issue 1-2 https://doi.org/10.1016/0022-0728(88)80372-3	journal	July 1988
A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels Qiao, Jinli; Liu, Yuyu; Hong, Feng Chem. Soc. Rev., Vol. 43, Issue 2 https://doi.org/10.1039/C3CS60323G	journal	January 2014
[Mn(bipyridyl)(CO)3Br]: An Abundant Metal Carbonyl Complex as Efficient Electrocatalyst for CO2 Reduction Bourrez, Marc; Molton, Florian; Chardon-Noblat, Sylvie Angewandte Chemie International Edition, Vol. 50, Issue 42 https://doi.org/10.1002/anie.201103616	journal	September 2011
Highly Efficient, Selective, and Stable CO ₂ Electroreduction on a Hexagonal Zn Catalyst Won, Da Hye; Shin, Hyeyoung; Koh, Jaekang Angewandte Chemie International Edition, Vol. 55, Issue 32 https://doi.org/10.1002/anie.201602888	journal	June 2016
Chemical Redox Agents for Organometallic Chemistry Connelly, Neil G.; Geiger, William E. Chemical Reviews, Vol. 96, Issue 2 https://doi.org/10.1021/cr940053x	journal	January 1996
Nanostructured Metallic Electrocatalysts for Carbon Dioxide Reduction Lu, Qi; Rosen, Jonathan; Jiao, Feng ChemCatChem, Vol. 7, Issue 1 https://doi.org/10.1002/cctc.201402669	journal	October 2014
Electrochemical CO ₂ Reduction to Hydrocarbons on a Heterogeneous Molecular Cu Catalyst in Aqueous Solution Weng, Zhe; Jiang, Jianbing; Wu, Yueshen Journal of the American Chemical Society, Vol. 138, Issue 26 https://doi.org/10.1021/jacs.6b04746	journal	June 2016
Electrochemical reduction of CO2 at metal-porphyrin supported gas diffusion electrodes under high pressure CO2 Sonoyama, Noriyuki; Kirii, Masakazu; Sakata, Tadayoshi Electrochemistry Communications, Vol. 1, Issue 6 https://doi.org/10.1016/S1388-2481(99)00041-7	journal	June 1999
Current Issues in Molecular Catalysis Illustrated by Iron Porphyrins as Catalysts of the CO ₂ -to-CO Electrochemical Conversion Costentin, Cyrille; Robert, Marc; Savéant, Jean-Michel Accounts of Chemical Research, Vol. 48, Issue 12 https://doi.org/10.1021/acs.accounts.5b00262	journal	November 2015
Electrochemical reduction of carbon dioxide catalyzed by [CoI(salophen)Li] Isse, Abdirisak Ahmed; Gennaro, Armando; Vianello, Elio Journal of Molecular Catalysis, Vol. 70, Issue 2 https://doi.org/10.1016/0304-5102(91)80161-U	journal	December 1991
Electrochemical CO2 reduction catalyzed by ruthenium complexes [Ru(bpy)2(CO)2]2+ and [Ru(bpy)2(CO)Cl]+. Effect of pH on the formation of CO and HCOO- Ishida, Hitoshi.; Tanaka, Koji.; Tanaka, Toshio. Organometallics, Vol. 6, Issue 1 https://doi.org/10.1021/om00144a033	journal	January 1987
Electrochemical CO₂ Reduction on Metal Electrodes Hori, Y.; Vayenas, Constantinos G.; White, Ralph E. Modern Aspects of Electrochemistry, p. 89-189 https://doi.org/10.1007/978-0-387-49489-0_3	book	January 2008
Covalent organic frameworks comprising cobalt porphyrins for catalytic CO ₂ reduction in water Lin, Song; Diercks, Christian S.; Zhang, Yue-Biao Science, Vol. 349, Issue 6253 https://doi.org/10.1126/science.aac8343	journal	August 2015
Tin Oxide Dependence of the CO ₂ Reduction Efficiency on Tin Electrodes and Enhanced Activity for Tin/Tin Oxide Thin-Film Catalysts Chen, Yihong; Kanan, Matthew W. Journal of the American Chemical Society, Vol. 134, Issue 4 https://doi.org/10.1021/ja2108799	journal	January 2012
Nickel N-heterocyclic carbene–pyridine complexes that exhibit selectivity for electrocatalytic reduction of carbon dioxide over water Thoi, V. Sara; Chang, Christopher J. Chemical Communications, Vol. 47, Issue 23 https://doi.org/10.1039/c1cc10449g	journal	January 2011
Nickel(II)-cyclam: an extremely selective electrocatalyst for reduction of CO2 in water Beley, Marc; Collin, Jean-Paul; Ruppert, Romain Journal of the Chemical Society, Chemical Communications, Issue 19 https://doi.org/10.1039/c39840001315	journal	January 1984
Robust carbon dioxide reduction on molybdenum disulphide edges Asadi, Mohammad; Kumar, Bijandra; Behranginia, Amirhossein Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5470	journal	July 2014
Facile electrosynthesis of π-extended porphyrins Fang, Yuanyuan; Koszelewski, Dominik; Kadish, Karl M. Chem. Commun., Vol. 50, Issue 64 https://doi.org/10.1039/C4CC02759K	journal	January 2014
Electrochemical Studies of Zinc Tetraphenylporphin Lanese, J. G.; Wilson, George S. Journal of The Electrochemical Society, Vol. 119, Issue 8 https://doi.org/10.1149/1.2404391	journal	January 1972
Electrocatalytic process of CO selectivity in electrochemical reduction of CO₂ at metal electrodes in aqueous media Hori, Yoshio; Wakebe, Hidetoshi; Tsukamoto, Toshio Electrochimica Acta, Vol. 39, Issue 11-12, p. 1833-1839 https://doi.org/10.1016/0013-4686(94)85172-7	journal	August 1994
Electrochemical reduction of carbon dioxide mediated by molecular catalysts Collin, J. Coordination Chemistry Reviews, Vol. 93, Issue 2 https://doi.org/10.1016/0010-8545(89)80018-9	journal	March 1989
Molecular Catalysis of Electrochemical Reactions. Mechanistic Aspects Savéant, Jean-Michel Chemical Reviews, Vol. 108, Issue 7, p. 2348-2378 https://doi.org/10.1021/cr068079z	journal	July 2008
Electronic Structure of a Formal Iron(0) Porphyrin Complex Relevant to CO ₂ Reduction Römelt, Christina; Song, Jinshuai; Tarrago, Maxime Inorganic Chemistry, Vol. 56, Issue 8 https://doi.org/10.1021/acs.inorgchem.7b00401	journal	April 2017
Substituent and axial ligand effects on the electrochemistry of zinc porphyrins Lin, Chia-ling; Fang, May-Yang; Cheng, Shu-Hua Journal of Electroanalytical Chemistry, Vol. 531, Issue 2 https://doi.org/10.1016/S0022-0728(02)01056-2	journal	August 2002
One- and two-electron pathways in the electrocatalytic reduction of CO ₂ by fac-Re(bpy)(CO) ₃ Cl (bpy = 2,2′-bipyridine) Sullivan, B. Patrick; Bolinger, C. Mark; Conrad, David J. Chem. Soc., Chem. Commun., Issue 20 https://doi.org/10.1039/C39850001414	journal	January 1985
Study of the structure and spectral properties of radical anions of Zn complexes of porphyrins by the method of density functional theory Parkhots, O. P.; Ivashin, N. V. Optics and Spectroscopy, Vol. 106, Issue 2 https://doi.org/10.1134/S0030400X0902009X	journal	February 2009
Facilitated carbon dioxide reduction using a Zn( ii ) complex Donovan, Elizabeth S.; Barry, Brian M.; Larsen, Christopher A. Chemical Communications, Vol. 52, Issue 8 https://doi.org/10.1039/C5CC07318A	journal	January 2016
Metal–Organic Frameworks for Electrocatalytic Reduction of Carbon Dioxide Kornienko, Nikolay; Zhao, Yingbo; Kley, Christopher S. Journal of the American Chemical Society, Vol. 137, Issue 44 https://doi.org/10.1021/jacs.5b08212	journal	October 2015
Investigation of the synthesis of ortho-substituted tetraphenylporphyrins Lindsey, Jonathan S.; Wagner, Richard W. The Journal of Organic Chemistry, Vol. 54, Issue 4 https://doi.org/10.1021/jo00265a021	journal	February 1989
Electrons, Photons, Protons and Earth-Abundant Metal Complexes for Molecular Catalysis of CO ₂ Reduction Takeda, Hiroyuki; Cometto, Claudio; Ishitani, Osamu ACS Catalysis, Vol. 7, Issue 1 https://doi.org/10.1021/acscatal.6b02181	journal	November 2016
Nanostructured transition metal dichalcogenide electrocatalysts for CO ₂ reduction in ionic liquid Asadi, Mohammad; Kim, Kibum; Liu, Cong Science, Vol. 353, Issue 6298 https://doi.org/10.1126/science.aaf4767	journal	July 2016
Negative Ions of Porphin Metal Complexes Closs, G. L.; Closs, L. E. Journal of the American Chemical Society, Vol. 85, Issue 6 https://doi.org/10.1021/ja00889a038	journal	March 1963
A selective and efficient electrocatalyst for carbon dioxide reduction Lu, Qi; Rosen, Jonathan; Zhou, Yang Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4242	journal	January 2014
CO and CO2 hydrogenation study on supported cobalt Fischer–Tropsch synthesis catalysts Zhang, Yongqing; Jacobs, Gary; Sparks, Dennis E. Catalysis Today, Vol. 71, Issue 3-4 https://doi.org/10.1016/S0920-5861(01)00468-0	journal	January 2002
Electrochemistry of iron(I) porphyrins in the presence of carbon monoxide. Comparison with zinc porphyrins Balducci, Gabriele; Chottard, Genevieve; Gueutin, Claire Inorganic Chemistry, Vol. 33, Issue 9 https://doi.org/10.1021/ic00087a038	journal	April 1994
Highly selective and active CO2 reduction electrocatalysts based on cobalt phthalocyanine/carbon nanotube hybrid structures Zhang, Xing; Wu, Zishan; Zhang, Xiao Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14675	journal	March 2017
Valence Change Ability and Geometrical Occupation of Substitution Cations Determine the Pseudocapacitance of Spinel Ferrite XFe ₂ O ₄ (X = Mn, Co, Ni, Fe) Wei, Chao; Feng, Zhenxing; Baisariyev, Murat Chemistry of Materials, Vol. 28, Issue 12 https://doi.org/10.1021/acs.chemmater.6b00713	journal	June 2016
A Local Proton Source Enhances CO ₂ Electroreduction to CO by a Molecular Fe Catalyst Costentin, Cyrille; Drouet, Samuel; Robert, Marc Science, Vol. 338, Issue 6103 https://doi.org/10.1126/science.1224581	journal	October 2012
Mechanism of Rubisco: The Carbamate as General Base ^✗ Cleland, W. Wallace; Andrews, T. John; Gutteridge, Steven Chemical Reviews, Vol. 98, Issue 2 https://doi.org/10.1021/cr970010r	journal	April 1998
Electroreduction of carbon dioxide on gas-diffusion electrodes modified by metal phthalocyanines Furuya, Nagakazu; Matsui, Kuniyasu Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 271, Issue 1-2 https://doi.org/10.1016/0022-0728(89)80074-9	journal	January 1989

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