Extreme Confinement of Xenon by Cryptophane-111 in the Solid State

Joseph, Akil I.; Lapidus, Saul H.; Kane, Christopher M.; Holman, K. Travis

doi:10.1002/anie.201409415

Title: Extreme Confinement of Xenon by Cryptophane-111 in the Solid State

Journal Article · Thu Dec 11 00:00:00 EST 2014 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.201409415· OSTI ID:1396175

Joseph, Akil I.; Lapidus, Saul H.; Kane, Christopher M.; Holman, K. Travis

Solids that sorb, capture and/or store the heavier noble gases are of interest because of their potential for transformative rare gas separation/production, storage, or recovery technologies. Herein, we report the isolation, crystal structures, and thermal stabilities of a series of xenon and krypton clathrates of (±)-cryptophane-111 (111). One trigonal crystal form, Xe@111•y(solvent), is exceptionally stable, retaining xenon at temperatures of up to about 300 °C. The high kinetic stability is attributable not only to the high xenon affinity and cage-like nature of the host, but also to the crystal packing of the clathrate, wherein each window of the molecular container is blocked by the bridges of adjacent containers, effectively imprisoning the noble gas in the solid state. The results highlight the potential of discrete molecule materials exhibiting intrinsic microcavities or zero-dimensional pores.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)

DOE Contract Number:: AC02-06CH11357

OSTI ID:: 1396175

Journal Information:: Angewandte Chemie (International Edition), Vol. 54, Issue 5; ISSN 1433-7851

Publisher:: Wiley

Country of Publication:: United States

Language:: English

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