Tuning Selectivity of CO2 Hydrogenation Reactions at the Metal/Oxide Interface

Kattel, Shyam; Liu, Ping; Chen, Jingguang G.

doi:10.1021/jacs.7b05362

Title: Tuning Selectivity of CO₂ Hydrogenation Reactions at the Metal/Oxide Interface

Journal Article · Mon Jun 26 00:00:00 EDT 2017 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.7b05362· OSTI ID:1395947

Kattel, Shyam ^[1];

^[1];

^[2]

Brookhaven National Lab. (BNL), Upton, NY (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States); Columbia Univ., New York, NY (United States)

The chemical transformation of CO₂ not only mitigates the anthropogenic CO₂ emission into the Earth’s atmosphere but also produces carbon compounds that can be used as precursors for the production of chemicals and fuels. The activation and conversion of CO₂ can be achieved on multifunctional catalytic sites available at the metal/oxide interface by taking advantage of the synergy between the metal nanoparticles and oxide support. In this paper, we look at the recent progress in mechanistic studies of CO₂ hydrogenation to C1 (CO, CH₃OH, and CH₄) compounds on metal/oxide catalysts. On this basis, we are able to provide a better understanding of the complex reaction network, grasp the capability of manipulating structure and combination of metal and oxide at the interface in tuning selectivity, and identify the key descriptors to control the activity and, in particular, the selectivity of catalysts. In conclusion, we also discuss challenges and future research opportunities for tuning the selective conversion of CO₂ on metal/oxide catalysts.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704

OSTI ID:: 1395947

Report Number(s):: BNL-114374-2017-JA; R&D Project: CO035; KC0302010; TRN: US1702389

Journal Information:: Journal of the American Chemical Society, Vol. 139, Issue 29; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 594 works

Citation information provided by
Web of Science

References (163)

Impact of CO ₂ -Induced Warming on Simulated Hurricane Intensity and Precipitation: Sensitivity to the Choice of Climate Model and Convective Parameterization Knutson, Thomas R.; Tuleya, Robert E. Journal of Climate, Vol. 17, Issue 18 https://doi.org/10.1175/1520-0442(2004)017<3477:IOCWOS>2.0.CO;2	journal	September 2004
Global temperature change Hansen, J.; Sato, M.; Ruedy, R. Proceedings of the National Academy of Sciences, Vol. 103, Issue 39 https://doi.org/10.1073/pnas.0606291103	journal	September 2006
CO ₂ chemical conversion to useful products: An engineering insight to the latest advances toward sustainability : CO Taheri Najafabadi, Amin International Journal of Energy Research, Vol. 37, Issue 6 https://doi.org/10.1002/er.3021	journal	March 2013
Recent Advances in Catalysts for Methanol Synthesis via Hydrogenation of CO and CO ₂ Liu, Xin-Mei; Lu, G. Q.; Yan, Zi-Feng Industrial & Engineering Chemistry Research, Vol. 42, Issue 25 https://doi.org/10.1021/ie020979s	journal	December 2003
Mitigation of CO₂ by Chemical Conversion: Plausible Chemical Reactions and Promising Products Xiaoding, Xu; Moulijn, J. A. Energy & Fuels, Vol. 10, Issue 2, p. 305-325 https://doi.org/10.1021/ef9501511	journal	March 1996
Catalysis for the Valorization of Exhaust Carbon: from CO ₂ to Chemicals, Materials, and Fuels. Technological Use of CO ₂ Aresta, Michele; Dibenedetto, Angela; Angelini, Antonella Chemical Reviews, Vol. 114, Issue 3 https://doi.org/10.1021/cr4002758	journal	November 2013
Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO ₂ Fixation Appel, Aaron M.; Bercaw, John E.; Bocarsly, Andrew B. Chemical Reviews, Vol. 113, Issue 8 https://doi.org/10.1021/cr300463y	journal	June 2013
Computational Approaches to the Chemical Conversion of Carbon Dioxide Cheng, Daojian; Negreiros, Fabio R.; Aprà, Edoardo ChemSusChem, Vol. 6, Issue 6 https://doi.org/10.1002/cssc.201200872	journal	May 2013
Heterogeneous catalytic conversion of CO ₂ : a comprehensive theoretical review Li, Yawei; Chan, Siew Hwa; Sun, Qiang Nanoscale, Vol. 7, Issue 19 https://doi.org/10.1039/C5NR00092K	journal	January 2015
Status and perspectives of CO2 conversion into fuels and chemicals by catalytic, photocatalytic and electrocatalytic processes Kondratenko, Evgenii V.; Mul, Guido; Baltrusaitis, Jonas Energy & Environmental Science, Vol. 6, Issue 11 https://doi.org/10.1039/c3ee41272e	journal	January 2013
Hydrogenation of CO2 to value-added products—A review and potential future developments Saeidi, Samrand; Amin, Nor Aishah Saidina; Rahimpour, Mohammad Reza Journal of CO2 Utilization, Vol. 5 https://doi.org/10.1016/j.jcou.2013.12.005	journal	March 2014
The changing paradigm in CO2 utilization Aresta, Michele; Dibenedetto, Angela; Angelini, Antonella Journal of CO2 Utilization, Vol. 3-4 https://doi.org/10.1016/j.jcou.2013.08.001	journal	December 2013
Thermal, electrochemical, and photochemical conversion of CO2 to fuels and value-added products Hu, Boxun; Guild, Curtis; Suib, Steven L. Journal of CO2 Utilization, Vol. 1 https://doi.org/10.1016/j.jcou.2013.03.004	journal	June 2013
Conversion of the greenhouse gas CO2 to the fuel gas CO via the Boudouard reaction: A review Lahijani, Pooya; Zainal, Zainal Alimuddin; Mohammadi, Maedeh Renewable and Sustainable Energy Reviews, Vol. 41 https://doi.org/10.1016/j.rser.2014.08.034	journal	January 2015
Catalytic reduction of CO ₂ by H ₂ for synthesis of CO, methanol and hydrocarbons: challenges and opportunities Porosoff, Marc D.; Yan, Binhang; Chen, Jingguang G. Energy & Environmental Science, Vol. 9, Issue 1 https://doi.org/10.1039/C5EE02657A	journal	January 2016
A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels Qiao, Jinli; Liu, Yuyu; Hong, Feng Chem. Soc. Rev., Vol. 43, Issue 2 https://doi.org/10.1039/C3CS60323G	journal	January 2014
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces Kuhl, Kendra P.; Cave, Etosha R.; Abram, David N. Energy & Environmental Science, Vol. 5, Issue 5 https://doi.org/10.1039/c2ee21234j	journal	January 2012
Electrocatalytic Conversion of Carbon Dioxide to Methane and Methanol on Transition Metal Surfaces Kuhl, Kendra P.; Hatsukade, Toru; Cave, Etosha R. Journal of the American Chemical Society, Vol. 136, Issue 40 https://doi.org/10.1021/ja505791r	journal	August 2014
Active and Selective Conversion of CO ₂ to CO on Ultrathin Au Nanowires Zhu, Wenlei; Zhang, Yin-Jia; Zhang, Hongyi Journal of the American Chemical Society, Vol. 136, Issue 46 https://doi.org/10.1021/ja5095099	journal	November 2014
Nickel–Gallium-Catalyzed Electrochemical Reduction of CO ₂ to Highly Reduced Products at Low Overpotentials Torelli, Daniel A.; Francis, Sonja A.; Crompton, J. Chance ACS Catalysis, Vol. 6, Issue 3 https://doi.org/10.1021/acscatal.5b02888	journal	February 2016
Synthesis of thin film AuPd alloys and their investigation for electrocatalytic CO ₂ reduction Hahn, Christopher; Abram, David N.; Hansen, Heine A. Journal of Materials Chemistry A, Vol. 3, Issue 40 https://doi.org/10.1039/C5TA04863J	journal	January 2015
How copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels Peterson, Andrew A.; Abild-Pedersen, Frank; Studt, Felix Energy & Environmental Science, Vol. 3, Issue 9 https://doi.org/10.1039/c0ee00071j	journal	January 2010
Structure Sensitivity of the Electrochemical Reduction of Carbon Monoxide on Copper Single Crystals Schouten, Klaas Jan P.; Pérez Gallent, Elena; Koper, Marc T. M. ACS Catalysis, Vol. 3, Issue 6 https://doi.org/10.1021/cs4002404	journal	April 2013
Theoretical Considerations on the Electroreduction of CO to C ₂ Species on Cu(100) Electrodes Calle-Vallejo, Federico; Koper, Marc T. M. Angewandte Chemie International Edition, Vol. 52, Issue 28 https://doi.org/10.1002/anie.201301470	journal	June 2013
Controlling Catalytic Selectivities during CO ₂ Electroreduction on Thin Cu Metal Overlayers Reske, Rulle; Duca, Matteo; Oezaslan, Mehtap The Journal of Physical Chemistry Letters, Vol. 4, Issue 15 https://doi.org/10.1021/jz401087q	journal	July 2013
Catalysts and Reaction Pathways for the Electrochemical Reduction of Carbon Dioxide Kortlever, Ruud; Shen, Jing; Schouten, Klaas Jan P. The Journal of Physical Chemistry Letters, Vol. 6, Issue 20 https://doi.org/10.1021/acs.jpclett.5b01559	journal	September 2015
A selective and efficient electrocatalyst for carbon dioxide reduction Lu, Qi; Rosen, Jonathan; Zhou, Yang Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4242	journal	January 2014
Highly active copper-ceria and copper-ceria-titania catalysts for methanol synthesis from CO2 Graciani, J.; Mudiyanselage, K.; Xu, F. Science, Vol. 345, Issue 6196 https://doi.org/10.1126/science.1253057	journal	July 2014
Quantifying the promotion of Cu catalysts by ZnO for methanol synthesis Kuld, S.; Thorhauge, M.; Falsig, H. Science, Vol. 352, Issue 6288 https://doi.org/10.1126/science.aaf0718	journal	May 2016
The Active Site of Methanol Synthesis over Cu/ZnO/Al₂O₃ Industrial Catalysts Behrens, M.; Studt, F.; Kasatkin, I. Science, Vol. 336, Issue 6083, p. 893-897 https://doi.org/10.1126/science.1219831	journal	April 2012
CO ₂ Hydrogenation to Methanol on Supported Au Catalysts under Moderate Reaction Conditions: Support and Particle Size Effects Hartadi, Yeusy; Widmann, Daniel; Behm, R. Jürgen ChemSusChem, Vol. 8, Issue 3 https://doi.org/10.1002/cssc.201402645	journal	October 2014
Heterogeneous catalytic CO2 conversion to value-added hydrocarbons Dorner, Robert W.; Hardy, Dennis R.; Williams, Frederick W. Energy & Environmental Science, Vol. 3, Issue 7 https://doi.org/10.1039/c001514h	journal	January 2010
Hydrogenation of CO ₂ to Methanol: Importance of Metal–Oxide and Metal–Carbide Interfaces in the Activation of CO ₂ Rodriguez, José A.; Liu, Ping; Stacchiola, Dario J. ACS Catalysis, Vol. 5, Issue 11 https://doi.org/10.1021/acscatal.5b01755	journal	October 2015
A comparison of electricity and hydrogen production systems with CO2 capture and storage. Part A: Review and selection of promising conversion and capture technologies Damen, Kay; Troost, Martijn van; Faaij, André Progress in Energy and Combustion Science, Vol. 32, Issue 2 https://doi.org/10.1016/j.pecs.2005.11.005	journal	January 2006
Recycling of carbon dioxide to methanol and derived products – closing the loop Goeppert, Alain; Czaun, Miklos; Jones, John-Paul Chem. Soc. Rev., Vol. 43, Issue 23 https://doi.org/10.1039/C4CS00122B	journal	January 2014
Low Pressure CO ₂ Hydrogenation to Methanol over Gold Nanoparticles Activated on a CeO _x /TiO ₂ Interface Yang, Xiaofang; Kattel, Shyam; Senanayake, Sanjaya D. Journal of the American Chemical Society, Vol. 137, Issue 32 https://doi.org/10.1021/jacs.5b06150	journal	August 2015
Optimizing Binding Energies of Key Intermediates for CO ₂ Hydrogenation to Methanol over Oxide-Supported Copper Kattel, Shyam; Yan, Binhang; Yang, Yixiong Journal of the American Chemical Society, Vol. 138, Issue 38 https://doi.org/10.1021/jacs.6b05791	journal	September 2016
CO ₂ Hydrogenation over Oxide-Supported PtCo Catalysts: The Role of the Oxide Support in Determining the Product Selectivity Kattel, Shyam; Yu, Weiting; Yang, Xiaofang Angewandte Chemie International Edition, Vol. 55, Issue 28 https://doi.org/10.1002/anie.201601661	journal	May 2016
Hydrogenation of CO ₂ to Methanol on CeO _x /Cu(111) and ZnO/Cu(111) Catalysts: Role of the Metal–Oxide Interface and Importance of Ce ³⁺ Sites Senanayake, Sanjaya D.; Ramírez, Pedro J.; Waluyo, Iradwikanari The Journal of Physical Chemistry C, Vol. 120, Issue 3 https://doi.org/10.1021/acs.jpcc.5b12012	journal	January 2016
Shape selective plate-form Ga2O3 with strong metal–support interaction to overlying Pd for hydrogenation of CO2 to CH3OH Zhou, Xiwen; Qu, Jin; Xu, Feng Chemical Communications, Vol. 49, Issue 17 https://doi.org/10.1039/c3cc38455a	journal	January 2013
Hydrogenation of CO2 over sprayed Ru/TiO2 fine particles and strong metal–support interaction Li, Di; Ichikuni, Nobuyuki; Shimazu, Shogo Applied Catalysis A: General, Vol. 180, Issue 1-2 https://doi.org/10.1016/S0926-860X(98)00335-4	journal	April 1999
Indications for Metal-support Interactions: The Case of CO2Adsorption on Cu/ZnO(0001) Wang, J.; Funk, S.; Burghaus, U. Catalysis Letters, Vol. 103, Issue 3-4 https://doi.org/10.1007/s10562-005-7157-3	journal	October 2005
Effects of metal-support interactions on the hydrogenation of CO over Pd/SiO2 and Pd/La2O3 Hicks, R. Journal of Catalysis, Vol. 90, Issue 2 https://doi.org/10.1016/0021-9517(84)90249-5	journal	December 1984
Active sites for CO ₂ hydrogenation to methanol on Cu/ZnO catalysts Kattel, Shyam; Ramírez, Pedro J.; Chen, Jingguang G. Science, Vol. 355, Issue 6331 https://doi.org/10.1126/science.aal3573	journal	March 2017
CO2 fixation into methanol at Cu/ZrO2 interface from first principles kinetic Monte Carlo Tang, Qian-Lin; Hong, Qi-Jun; Liu, Zhi-Pan Journal of Catalysis, Vol. 263, Issue 1 https://doi.org/10.1016/j.jcat.2009.01.017	journal	April 2009
CO ₂ -to-Methanol Hydrogenation on Zirconia-Supported Copper Nanoparticles: Reaction Intermediates and the Role of the Metal-Support Interface Larmier, Kim; Liao, Wei-Chih; Tada, Shohei Angewandte Chemie International Edition, Vol. 56, Issue 9 https://doi.org/10.1002/anie.201610166	journal	January 2017
Adsorption Energy Correlations at the Metal–Support Boundary Mehta, Prateek; Greeley, Jeffrey; Delgass, W. Nicholas ACS Catalysis, Vol. 7, Issue 7 https://doi.org/10.1021/acscatal.7b00979	journal	June 2017
CO2 hydrogenation on Pt, Pt/SiO2 and Pt/TiO2: Importance of synergy between Pt and oxide support Kattel, Shyam; Yan, Binhang; Chen, Jingguang G. Journal of Catalysis, Vol. 343 https://doi.org/10.1016/j.jcat.2015.12.019	journal	November 2016
The effect of the morphological characteristics of TiO2 supports on the reverse water–gas shift reaction over Pt/TiO2 catalysts Kim, Sung Su; Lee, Hyun Hee; Hong, Sung Chang Applied Catalysis B: Environmental, Vol. 119-120 https://doi.org/10.1016/j.apcatb.2012.02.023	journal	May 2012
Pulse-response TAP studies of the reverse water–gas shift reaction over a Pt/CeO2 catalyst Goguet, A.; Shekhtman, S.; Burch, R. Journal of Catalysis, Vol. 237, Issue 1 https://doi.org/10.1016/j.jcat.2005.10.020	journal	January 2006
Study of the origin of the deactivation of a Pt/CeO catalyst during reverse water gas shift (RWGS) reaction Goguet, A.; Meunier, F.; Breen, J. Journal of Catalysis, Vol. 226, Issue 2 https://doi.org/10.1016/j.jcat.2004.06.011	journal	September 2004
A study on the effect of support's reducibility on the reverse water-gas shift reaction over Pt catalysts Kim, Sung Su; Lee, Hyun Hee; Hong, Sung Chang Applied Catalysis A: General, Vol. 423-424 https://doi.org/10.1016/j.apcata.2012.02.021	journal	May 2012
The effects of rare earth oxides on the reverse water-gas shift reaction on palladium/alumina Pettigrew, D. J.; Trimm, D. L.; Cant, N. W. Catalysis Letters, Vol. 28, Issue 2-4 https://doi.org/10.1007/BF00806061	journal	January 1994
Hydrogenation of carbon dioxide and carbon monoxide over supported rhodium catalysts under 10 bar pressure Inoue, Takashi; Iizuka, Tokio; Tanabe, Kozo Applied Catalysis, Vol. 46, Issue 1 https://doi.org/10.1016/S0166-9834(00)81390-1	journal	January 1989
Selective synthesis of carbon monoxide via formates in reverse water–gas shift reaction over alumina-supported gold catalyst Ishito, Nobuhiro; Hara, Kenji; Nakajima, Kiyotaka Journal of Energy Chemistry, Vol. 25, Issue 2 https://doi.org/10.1016/j.jechem.2015.12.005	journal	March 2016
TAP reactor studies of the oxidizing capability of CO2 on a Au/CeO2 catalyst – A first step toward identifying a redox mechanism in the Reverse Water–Gas Shift reaction Wang, L. C.; Tahvildar Khazaneh, M.; Widmann, D. Journal of Catalysis, Vol. 302 https://doi.org/10.1016/j.jcat.2013.02.021	journal	June 2013
Structure Sensitivity for Forward and Reverse Water-Gas Shift Reactions on Copper Surfaces: A DFT Study Wang, Gui-Chang; Nakamura, Junji The Journal of Physical Chemistry Letters, Vol. 1, Issue 20 https://doi.org/10.1021/jz101150w	journal	October 2010
Enhanced activity and stability of a Cu/SiO2 catalyst for the reverse water gas shift reaction by an iron promoter Chen, Ching-Shiun; Cheng, Wu-Hsun; Lin, Shou-Shiun Chemical Communications, Issue 18 https://doi.org/10.1039/b104279n	journal	January 2001
Methanol synthesis and reverse water-gas shift kinetics over clean polycrystalline copper Yoshihara, Jun; Parker, S. C.; Schafer, Adam Catalysis Letters, Vol. 31, Issue 4 https://doi.org/10.1007/BF00808595	journal	January 1995
The synthesis of methanol and the reverse water-gas shift reaction over Zn-deposited Cu(100) and Cu(110) surfaces: comparison with Zn/Cu(111) Nakamura, I.; Fujitani, T.; Uchijima, T. Surface Science, Vol. 400, Issue 1-3 https://doi.org/10.1016/S0039-6028(97)00899-6	journal	March 1998
A theoretical study of surface-structural sensitivity of the reverse water-gas shift reaction over Cu(hkl) surfaces Wang, Gui-Chang; Jiang, Ling; Pang, Xian-Yong Surface Science, Vol. 543, Issue 1-3 https://doi.org/10.1016/S0039-6028(03)00876-8	journal	October 2003
Fe/γ-Al ₂ O ₃ and Fe–K/γ-Al ₂ O ₃ as reverse water-gas shift catalysts Loiland, Jason A.; Wulfers, Matthew J.; Marinkovic, Nebojsa S. Catalysis Science & Technology, Vol. 6, Issue 14 https://doi.org/10.1039/C5CY02111A	journal	January 2016
Syngas Production via Reverse Water-Gas Shift Reaction over a Ni-Al ₂ O ₃ Catalyst: Catalyst Stability, Reaction Kinetics, and Modeling Wolf, Andreas; Jess, Andreas; Kern, Christoph Chemical Engineering & Technology, Vol. 39, Issue 6 https://doi.org/10.1002/ceat.201500548	journal	February 2016
Effect of precipitants on Ni-CeO2 catalysts prepared by a co-precipitation method for the reverse water-gas shift reaction Wang, Luhui; Liu, Hui; Liu, Yuan Journal of Rare Earths, Vol. 31, Issue 10 https://doi.org/10.1016/S1002-0721(13)60014-9	journal	October 2013
Ni/Ce–Zr–O catalyst for high CO2 conversion during reverse water gas shift reaction (RWGS) Sun, Feng-man; Yan, Chang-feng; Wang, Zhi-da International Journal of Hydrogen Energy, Vol. 40, Issue 46 https://doi.org/10.1016/j.ijhydene.2015.10.004	journal	December 2015
Mechanism of the reverse water gas shift reaction over Cu/ZnO catalyst*1 Fujita, S. Journal of Catalysis, Vol. 134, Issue 1 https://doi.org/10.1016/0021-9517(92)90223-5	journal	March 1992
Trends in the catalytic reduction of CO2 by hydrogen over supported monometallic and bimetallic catalysts Porosoff, Marc D.; Chen, Jingguang G. Journal of Catalysis, Vol. 301 https://doi.org/10.1016/j.jcat.2013.01.022	journal	May 2013
CO2 hydrogenation reactivity and structure of Rh/SiO2 catalysts prepared from acetate, chloride and nitrate precursors Kusama, Hitoshi; Bando, Kyoko Kitamura; Okabe, Kiyomi Applied Catalysis A: General, Vol. 205, Issue 1-2 https://doi.org/10.1016/S0926-860X(00)00576-7	journal	January 2001
Isolated Metal Active Site Concentration and Stability Control Catalytic CO ₂ Reduction Selectivity Matsubu, John C.; Yang, Vanessa N.; Christopher, Phillip Journal of the American Chemical Society, Vol. 137, Issue 8 https://doi.org/10.1021/ja5128133	journal	February 2015
Molybdenum Carbide as Alternative Catalysts to Precious Metals for Highly Selective Reduction of CO ₂ to CO Porosoff, Marc D.; Yang, Xiaofang; Boscoboinik, J. Anibal Angewandte Chemie International Edition, Vol. 53, Issue 26 https://doi.org/10.1002/anie.201404109	journal	May 2014
Methanol synthesis from CO2 hydrogenation over a Pd4/In2O3 model catalyst: A combined DFT and kinetic study Ye, Jingyun; Liu, Chang-jun; Mei, Donghai Journal of Catalysis, Vol. 317 https://doi.org/10.1016/j.jcat.2014.06.002	journal	August 2014
Copper Cluster Size Effect in Methanol Synthesis from CO ₂ Yang, Bing; Liu, Cong; Halder, Avik The Journal of Physical Chemistry C, Vol. 121, Issue 19 https://doi.org/10.1021/acs.jpcc.7b01835	journal	May 2017
Effect of Surface Hydroxyls on CO ₂ Hydrogenation Over Cu/γ-Al ₂ O ₃ Catalyst: A Theoretical Study Zhang, Riguang; Wang, Baojun; Liu, Hongyan The Journal of Physical Chemistry C, Vol. 115, Issue 40 https://doi.org/10.1021/jp206065y	journal	September 2011
Effect of surface hydroxyls on selective CO2 hydrogenation over Ni4/γ-Al2O3: A density functional theory study Pan, Yun-xiang; Liu, Chang-jun; Ge, Qingfeng Journal of Catalysis, Vol. 272, Issue 2 https://doi.org/10.1016/j.jcat.2010.04.003	journal	June 2010
Hydrogen spillover in heterogeneous catalysis Rozanov, Valerii V.; Krylov, Oleg V. Russian Chemical Reviews, Vol. 66, Issue 2 https://doi.org/10.1070/RC1997v066n02ABEH000308	journal	February 1997
Spillover in Heterogeneous Catalysis Conner, W. Curtis.; Falconer, John L. Chemical Reviews, Vol. 95, Issue 3 https://doi.org/10.1021/cr00035a014	journal	May 1995
Active Oxygen Vacancy Site for Methanol Synthesis from CO ₂ Hydrogenation on In ₂ O ₃ (110): A DFT Study Ye, Jingyun; Liu, Changjun; Mei, Donghai ACS Catalysis, Vol. 3, Issue 6 https://doi.org/10.1021/cs400132a	journal	April 2013
Carbon dioxide activation and dissociation on ceria (110): A density functional theory study Cheng, Zhuo; Sherman, Brent J.; Lo, Cynthia S. The Journal of Chemical Physics, Vol. 138, Issue 1, Article No. 014702 https://doi.org/10.1063/1.4773248	journal	January 2013
How Oxygen Vacancies Activate CO ₂ Dissociation on TiO ₂ Anatase (001) Huygh, Stijn; Bogaerts, Annemie; Neyts, Erik C. The Journal of Physical Chemistry C, Vol. 120, Issue 38 https://doi.org/10.1021/acs.jpcc.6b07459	journal	September 2016
Effects of Hydration and Oxygen Vacancy on CO ₂ Adsorption and Activation on β-Ga ₂ O ₃ (100) Pan, Yun-xiang; Liu, Chang-jun; Mei, Donghai Langmuir, Vol. 26, Issue 8 https://doi.org/10.1021/la903836v	journal	April 2010
Au/ZnO as catalyst for methanol synthesis: The role of oxygen vacancies Strunk, Jennifer; Kähler, Kevin; Xia, Xinyu Applied Catalysis A: General, Vol. 359, Issue 1-2 https://doi.org/10.1016/j.apcata.2009.02.030	journal	May 2009
Support effects in the formation of methanol from carbon dioxide and hydrogen over rhenium catalysts Iizuka, Tokio; Kojima, Masanao; Tanabe, Kozo Journal of the Chemical Society, Chemical Communications, Issue 11 https://doi.org/10.1039/c39830000638	journal	January 1983
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces Man, Isabela C.; Su, Hai‐Yan; Calle‐Vallejo, Federico ChemCatChem, Vol. 3, Issue 7 https://doi.org/10.1002/cctc.201000397	journal	March 2011
Theoretical Study of Methanol Synthesis from CO ₂ Hydrogenation on Metal-Doped Cu(111) Surfaces Yang, Yixiong; White, Michael G.; Liu, Ping The Journal of Physical Chemistry C, Vol. 116, Issue 1 https://doi.org/10.1021/jp208448c	journal	December 2011
Operando Synchrotron X-ray Powder Diffraction and Modulated-Excitation Infrared Spectroscopy Elucidate the CO ₂ Promotion on a Commercial Methanol Synthesis Catalyst Martin, Oliver; Mondelli, Cecilia; Cervellino, Antonio Angewandte Chemie International Edition, Vol. 55, Issue 37 https://doi.org/10.1002/anie.201603204	journal	July 2016
Indium Oxide as a Superior Catalyst for Methanol Synthesis by CO ₂ Hydrogenation Martin, Oliver; Martín, Antonio J.; Mondelli, Cecilia Angewandte Chemie International Edition, Vol. 55, Issue 21 https://doi.org/10.1002/anie.201600943	journal	March 2016
A highly dispersed Pd–Mg/SiO2 catalyst active for methanation of CO2 Park, Jung-Nam; McFarland, Eric W. Journal of Catalysis, Vol. 266, Issue 1 https://doi.org/10.1016/j.jcat.2009.05.018	journal	August 2009
Development of an active Ga2O3 supported palladium catalyst for the synthesis of methanol from carbon dioxide and hydrogen Fujitani, T.; Saito, M.; Kanai, Y. Applied Catalysis A: General, Vol. 125, Issue 2 https://doi.org/10.1016/0926-860X(95)00049-6	journal	May 1995
Reaction Mechanism of Methanol Synthesis from Carbon Dioxide and Hydrogen on Ceria-Supported Palladium Catalysts with SMSI Effect Fan, Li; Fujimoto, Kaoru Journal of Catalysis, Vol. 172, Issue 1 https://doi.org/10.1006/jcat.1997.1866	journal	November 1997
Hydrogen Spillover in Ga2O3–Pd/SiO2 Catalysts for Methanol Synthesis from CO2/H2 Collins, Sebastián E.; Chiavassa, Dante L.; Bonivardi, Adrian L. Catalysis Letters, Vol. 103, Issue 1-2 https://doi.org/10.1007/s10562-005-6507-5	journal	September 2005
Shape Effect of Pd-Promoted Ga ₂ O ₃ Nanocatalysts for Methanol Synthesis by CO ₂ Hydrogenation Qu, Jin; Zhou, Xiwen; Xu, Feng The Journal of Physical Chemistry C, Vol. 118, Issue 42 https://doi.org/10.1021/jp5063379	journal	October 2014
Pd/ZnO catalysts for direct CO2 hydrogenation to methanol Bahruji, Hasliza; Bowker, Michael; Hutchings, Graham Journal of Catalysis, Vol. 343 https://doi.org/10.1016/j.jcat.2016.03.017	journal	November 2016
Synergism in methanol synthesis from carbon dioxide over gold catalysts supported on metal oxides Sakurai, H.; Haruta, M. Catalysis Today, Vol. 29, Issue 1-4 https://doi.org/10.1016/0920-5861(95)00305-3	journal	May 1996
Formation of a ZnO Overlayer in Industrial Cu/ZnO/Al ₂ O ₃ Catalysts Induced by Strong Metal-Support Interactions Lunkenbein, Thomas; Schumann, Julia; Behrens, Malte Angewandte Chemie International Edition, Vol. 54, Issue 15 https://doi.org/10.1002/anie.201411581	journal	February 2015
Structure sensitivity of Cu and CuZn catalysts relevant to industrial methanol synthesis van den Berg, Roy; Prieto, Gonzalo; Korpershoek, Gerda Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms13057	journal	October 2016
Bridging the Time Gap: A Copper/Zinc Oxide/Aluminum Oxide Catalyst for Methanol Synthesis Studied under Industrially Relevant Conditions and Time Scales Lunkenbein, Thomas; Girgsdies, Frank; Kandemir, Timur Angewandte Chemie International Edition, Vol. 55, Issue 41 https://doi.org/10.1002/anie.201603368	journal	September 2016
Methanol formation by CO2 hydrogenation on Au/ZnO catalysts – Effect of total pressure and influence of CO on the reaction characteristics Hartadi, Yeusy; Widmann, Daniel; Behm, R. Jürgen Journal of Catalysis, Vol. 333 https://doi.org/10.1016/j.jcat.2015.11.002	journal	January 2016
The Cu–ZnO synergy in methanol synthesis from CO2, Part 2: Origin of the methanol and CO selectivities explained by experimental studies and a sphere contact quantification model in randomly packed binary mixtures on Cu–ZnO coprecipitate catalysts Tisseraud, Céline; Comminges, Clément; Belin, Thomas Journal of Catalysis, Vol. 330 https://doi.org/10.1016/j.jcat.2015.04.035	journal	October 2015
The Cu–ZnO synergy in methanol synthesis Part 3: Impact of the composition of a selective Cu@ZnO core–shell catalyst on methanol rate explained by experimental studies and a concentric spheres model Tisseraud, Céline; Comminges, Clément; Pronier, Stéphane Journal of Catalysis, Vol. 343 https://doi.org/10.1016/j.jcat.2015.12.005	journal	November 2016
The Cu–ZnO synergy in methanol synthesis from CO2, Part 1: Origin of active site explained by experimental studies and a sphere contact quantification model on Cu + ZnO mechanical mixtures Le Valant, Anthony; Comminges, Clément; Tisseraud, Céline Journal of Catalysis, Vol. 324 https://doi.org/10.1016/j.jcat.2015.01.021	journal	April 2015
Catalytic hydrogenation of CO2 over supported palladium Erdohelyi, A. Journal of Catalysis, Vol. 98, Issue 1 https://doi.org/10.1016/0021-9517(86)90306-4	journal	March 1986
Development of an active and stable ceria-supported palladium catalyst for hydrogenation of carbon dioxide to methanol Fan, Li; Fujimoto, Kaoru Applied Catalysis A: General, Vol. 106, Issue 1 https://doi.org/10.1016/0926-860X(93)80152-G	journal	November 1993
Promotive SMSI Effect for Hydrogenation of Carbon Dioxide to Methanol on a Pd/CeO2 Catalyst Fan, L.; Fujimoto, K. Journal of Catalysis, Vol. 150, Issue 1 https://doi.org/10.1006/jcat.1994.1338	journal	November 1994
Hydrogenation of CO2 over gold supported on metal oxides Sakurai, H.; Tsubota, S.; Haruta, M. Applied Catalysis A: General, Vol. 102, Issue 2 https://doi.org/10.1016/0926-860X(93)80224-E	journal	August 1993
Mechanism of Methanol Synthesis on Cu through CO ₂ and CO Hydrogenation Grabow, L. C.; Mavrikakis, M. ACS Catalysis, Vol. 1, Issue 4 https://doi.org/10.1021/cs200055d	journal	February 2011
The Mechanism of CO and CO ₂ Hydrogenation to Methanol over Cu-Based Catalysts Studt, Felix; Behrens, Malte; Kunkes, Edward L. ChemCatChem, Vol. 7, Issue 7 https://doi.org/10.1002/cctc.201500123	journal	March 2015
Discovery of a Ni-Ga catalyst for carbon dioxide reduction to methanol Studt, Felix; Sharafutdinov, Irek; Abild-Pedersen, Frank Nature Chemistry, Vol. 6, Issue 4 https://doi.org/10.1038/nchem.1873	journal	March 2014
Insight into methanol synthesis from CO2 hydrogenation on Cu(111): Complex reaction network and the effects of H2O Zhao, Ya-Fan; Yang, Yong; Mims, Charles Journal of Catalysis, Vol. 281, Issue 2 https://doi.org/10.1016/j.jcat.2011.04.012	journal	July 2011
Carbon Dioxide Conversion to Methanol over Size-Selected Cu ₄ Clusters at Low Pressures Liu, Cong; Yang, Bing; Tyo, Eric Journal of the American Chemical Society, Vol. 137, Issue 27 https://doi.org/10.1021/jacs.5b03668	journal	July 2015
Highly active Ni-promoted mesostructured silica nanoparticles for CO2 methanation Aziz, M. A. A.; Jalil, A. A.; Triwahyono, S. Applied Catalysis B: Environmental, Vol. 147 https://doi.org/10.1016/j.apcatb.2013.09.015	journal	April 2014
Methanation of CO ₂ and reverse water gas shift reactions on Ni/SiO ₂ catalysts: the influence of particle size on selectivity and reaction pathway Wu, H. C.; Chang, Y. C.; Wu, J. H. Catalysis Science & Technology, Vol. 5, Issue 8 https://doi.org/10.1039/C5CY00667H	journal	January 2015
Preparation of highly active nickel catalysts supported on mesoporous nanocrystalline γ-Al2O3 for CO2 methanation Rahmani, Soudabeh; Rezaei, Mehran; Meshkani, Fereshteh Journal of Industrial and Engineering Chemistry, Vol. 20, Issue 4 https://doi.org/10.1016/j.jiec.2013.07.017	journal	July 2014
Kinetic studies of CO 2 methanation over a Ni/ γ -Al 2 O 3 catalyst using a batch reactor Yang Lim, Jin; McGregor, J.; Sederman, A. J. Chemical Engineering Science, Vol. 141 https://doi.org/10.1016/j.ces.2015.10.026	journal	February 2016
The role of the Boudouard and water–gas shift reactions in the methanation of CO or CO2 over Ni/γ-Al2O3 catalyst Lim, Jin Yang; McGregor, James; Sederman, Andrew J. Chemical Engineering Science, Vol. 152 https://doi.org/10.1016/j.ces.2016.06.042	journal	October 2016
Efficient CO 2 methanation over Ni/Al 2 O 3 coated structured catalysts Danaci, Simge; Protasova, Lidia; Lefevere, Jasper Catalysis Today, Vol. 273 https://doi.org/10.1016/j.cattod.2016.04.019	journal	September 2016
Density functional theory analysis of methanation reaction of CO2 on Ru nanoparticle supported on TiO2 (101) Akamaru, Satoshi; Shimazaki, Tomomi; Kubo, Momoji Applied Catalysis A: General, Vol. 470 https://doi.org/10.1016/j.apcata.2013.11.016	journal	January 2014
Ni/CeO2 catalysts with high CO2 methanation activity and high CH4 selectivity at low temperatures Tada, Shohei; Shimizu, Teruyuki; Kameyama, Hiromichi International Journal of Hydrogen Energy, Vol. 37, Issue 7 https://doi.org/10.1016/j.ijhydene.2011.12.122	journal	April 2012
Role of surface Ni and Ce species of Ni/CeO2 catalyst in CO2 methanation Zhou, Guilin; Liu, Huiran; Cui, Kaikai Applied Surface Science, Vol. 383 https://doi.org/10.1016/j.apsusc.2016.04.180	journal	October 2016
Catalytic CO2 valorization into CH4 on Ni-based ceria-zirconia. Reaction mechanism by operando IR spectroscopy Aldana, P. A. Ussa; Ocampo, F.; Kobl, K. Catalysis Today, Vol. 215 https://doi.org/10.1016/j.cattod.2013.02.019	journal	October 2013
The Ni/ZrO2 catalyst and the methanation of CO and CO2 da Silva, Daniela C. D.; Letichevsky, Sonia; Borges, Luiz E. P. International Journal of Hydrogen Energy, Vol. 37, Issue 11 https://doi.org/10.1016/j.ijhydene.2012.03.020	journal	June 2012
Effect of Ce/Zr composition and noble metal promotion on nickel based CexZr1−xO2 catalysts for carbon dioxide methanation Ocampo, Fabien; Louis, Benoit; Kiwi-Minsker, Lioubov Applied Catalysis A: General, Vol. 392, Issue 1-2 https://doi.org/10.1016/j.apcata.2010.10.025	journal	January 2011
Promotion of CO2 methanation activity and CH4 selectivity at low temperatures over Ru/CeO2/Al2O3 catalysts Tada, Shohei; Ochieng, Ochieng James; Kikuchi, Ryuji International Journal of Hydrogen Energy, Vol. 39, Issue 19 https://doi.org/10.1016/j.ijhydene.2014.04.133	journal	June 2014
CO2 methanation on Ru-doped ceria Sharma, Sudhanshu; Hu, Zhenpeng; Zhang, Peng Journal of Catalysis, Vol. 278, Issue 2 https://doi.org/10.1016/j.jcat.2010.12.015	journal	March 2011
Mechanistic Insights into CO ₂ Methanation over Ru-Substituted CeO ₂ Sharma, Sudhanshu; Sravan Kumar, K. B.; Chandnani, Yash M. The Journal of Physical Chemistry C, Vol. 120, Issue 26 https://doi.org/10.1021/acs.jpcc.6b03224	journal	June 2016
Water assisted dispersion of Ru nanoparticles: The impact of water on the activity and selectivity of supported Ru catalysts during the selective methanation of CO in CO2-rich reformate Abdel-Mageed, Ali M.; Eckle, S.; Widmann, D. Journal of Catalysis, Vol. 335 https://doi.org/10.1016/j.jcat.2015.12.013	journal	March 2016
Influence of the catalyst loading on the activity and the CO selectivity of supported Ru catalysts in the selective methanation of CO in CO2 containing feed gases Eckle, Stephan; Augustin, Matthias; Anfang, Hans-Georg Catalysis Today, Vol. 181, Issue 1 https://doi.org/10.1016/j.cattod.2011.08.035	journal	February 2012
Catalytic and adsorption studies for the hydrogenation of CO2 to methane Janke, C.; Duyar, M. S.; Hoskins, M. Applied Catalysis B: Environmental, Vol. 152-153 https://doi.org/10.1016/j.apcatb.2014.01.016	journal	June 2014
Kinetics of CO2 methanation over Ru/γ-Al2O3 and implications for renewable energy storage applications Duyar, Melis S.; Ramachandran, Arvind; Wang, Christine Journal of CO2 Utilization, Vol. 12 https://doi.org/10.1016/j.jcou.2015.10.003	journal	December 2015
CO2 methanation property of Ru nanoparticle-loaded TiO2 prepared by a polygonal barrel-sputtering method Abe, Takayuki; Tanizawa, Masaaki; Watanabe, Kuniaki Energy & Environmental Science, Vol. 2, Issue 3 https://doi.org/10.1039/b817740f	journal	January 2009
CO ₂ methanation by Ru-doped ceria: the role of the oxidation state of the surface Upham, D. Chester; Derk, Alan R.; Sharma, Sudanshu Catalysis Science & Technology, Vol. 5, Issue 3 https://doi.org/10.1039/C4CY01106F	journal	January 2015
Hydrogenation mechanism of carbon dioxide and carbon monoxide on Ru(0001) surface: a density functional theory study Zhang, Shi-Tong; Yan, Hong; Wei, Min RSC Advances, Vol. 4, Issue 57 https://doi.org/10.1039/C4RA01655F	journal	January 2014
Active Site Dependent Reaction Mechanism over Ru/CeO ₂ Catalyst toward CO ₂ Methanation Wang, Fei; He, Shan; Chen, Hao Journal of the American Chemical Society, Vol. 138, Issue 19 https://doi.org/10.1021/jacs.6b02762	journal	May 2016
Methanation of CO2: Further insight into the mechanism over Rh/γ-Al2O3 catalyst Beuls, Antoine; Swalus, Colas; Jacquemin, Marc Applied Catalysis B: Environmental, Vol. 113-114 https://doi.org/10.1016/j.apcatb.2011.02.033	journal	February 2012
Influence of pretreatment temperature on catalytic performance of rutile TiO2-supported ruthenium catalyst in CO2 methanation Xu, Jinghua; Su, Xiong; Duan, Hongmin Journal of Catalysis, Vol. 333 https://doi.org/10.1016/j.jcat.2015.10.025	journal	January 2016
Insights into the mechanisms of CO2 methanation on Ni(111) surfaces by density functional theory Ren, Jun; Guo, Hailong; Yang, Jinzhou Applied Surface Science, Vol. 351 https://doi.org/10.1016/j.apsusc.2015.05.173	journal	October 2015
Catalysis mechanisms of CO ₂ and CO methanation Miao, Bin; Ma, Su Su Khine; Wang, Xin Catalysis Science & Technology, Vol. 6, Issue 12 https://doi.org/10.1039/C6CY00478D	journal	January 2016
Methane formation from the hydrogenation of carbon dioxide on Ni(110) surface – a density functional theoretical study Bothra, Pallavi; Periyasamy, Ganga; Pati, Swapan K. Physical Chemistry Chemical Physics, Vol. 15, Issue 15 https://doi.org/10.1039/c3cp44495c	journal	January 2013
Mechanism of CO2 reduction by H2 on Ru(0 0 0 1) and general selectivity descriptors for late-transition metal catalysts Avanesian, Talin; Gusmão, Gabriel S.; Christopher, Phillip Journal of Catalysis, Vol. 343 https://doi.org/10.1016/j.jcat.2016.03.016	journal	November 2016
Catalytic Methanation of CO and CO ₂ in Coke Oven Gas over Ni–Co/ZrO ₂ –CeO ₂ Razzaq, Rauf; Zhu, Hongwei; Jiang, Li Industrial & Engineering Chemistry Research, Vol. 52, Issue 6 https://doi.org/10.1021/ie301399z	journal	February 2013
A kinetic study of the methanation of CO2 over Ni−Al2O3 catalyst Shashidhara, G. M.; Ravindram, M. Reaction Kinetics and Catalysis Letters, Vol. 37, Issue 2 https://doi.org/10.1007/BF02062098	journal	September 1988
Fundamental studies of methanol synthesis from CO2 hydrogenation on Cu(111), Cu clusters, and Cu/ZnO(0001̄) Yang, Yixiong; Evans, Jaime; Rodriguez, Jose A. Physical Chemistry Chemical Physics, Vol. 12, Issue 33 https://doi.org/10.1039/c001484b	journal	January 2010
Mechanistic studies of methanol synthesis over Cu from CO/CO2/H2/H2O mixtures: The source of C in methanol and the role of water Yang, Y.; Mims, C. A.; Mei, D. H. Journal of Catalysis, Vol. 298 https://doi.org/10.1016/j.jcat.2012.10.028	journal	February 2013
Scaled Degree of Rate Control: Identifying Elementary Steps That Control Differences in Performance of Transition-Metal Catalysts Avanesian, Talin; Christopher, Phillip ACS Catalysis, Vol. 6, Issue 8 https://doi.org/10.1021/acscatal.6b01547	journal	July 2016
Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode Nørskov, J. K.; Rossmeisl, J.; Logadottir, A. The Journal of Physical Chemistry B, Vol. 108, Issue 46 https://doi.org/10.1021/jp047349j	journal	November 2004
Alloys of platinum and early transition metals as oxygen reduction electrocatalysts Greeley, J.; Stephens, I. E. L.; Bondarenko, A. S. Nature Chemistry, Vol. 1, Issue 7, p. 552-556 https://doi.org/10.1038/nchem.367	journal	September 2009
Electrolysis of water on oxide surfaces Rossmeisl, J.; Qu, Z. -W.; Zhu, H. Journal of Electroanalytical Chemistry, Vol. 607, Issue 1-2 https://doi.org/10.1016/j.jelechem.2006.11.008	journal	September 2007
CO2 hydrogenation at low temperature over Rh/γ-Al2O3 catalysts: Effect of the metal particle size on catalytic performances and reaction mechanism Karelovic, Alejandro; Ruiz, Patricio Applied Catalysis B: Environmental, Vol. 113-114 https://doi.org/10.1016/j.apcatb.2011.11.043	journal	February 2012
Cobalt Particle Size Effects in the Fischer–Tropsch Synthesis and in the Hydrogenation of CO2 Studied with Nanoparticle Model Catalysts on Silica Melaet, Gérôme; Lindeman, Avery E.; Somorjai, Gabor A. Topics in Catalysis, Vol. 57, Issue 6-9 https://doi.org/10.1007/s11244-013-0206-z	journal	December 2013
Adsorbate-mediated strong metal–support interactions in oxide-supported Rh catalysts Matsubu, John C.; Zhang, Shuyi; DeRita, Leo Nature Chemistry, Vol. 9, Issue 2 https://doi.org/10.1038/nchem.2607	journal	September 2016
Copper/zirconia catalysts for the synthesis of methanol from carbon dioxide Koeppel, R. A.; Baiker, A.; Wokaun, A. Applied Catalysis A: General, Vol. 84, Issue 1 https://doi.org/10.1016/0926-860X(92)80340-I	journal	May 1992
Effect of the addition of chromium- and manganese oxides on structural and catalytic properties of copper/zirconia catalysts for the synthesis of methanol from carbon dioxide Kilo, M. Journal of Molecular Catalysis A: Chemical, Vol. 126, Issue 2-3 https://doi.org/10.1016/S1381-1169(97)00109-X	journal	December 1997
Hydrogenation of CO 2 to CH 3 OH over Cu/ZnO catalysts with different ZnO morphology Lei, Hong; Nie, Renfeng; Wu, Guoqiang Fuel, Vol. 154 https://doi.org/10.1016/j.fuel.2015.03.052	journal	August 2015
Development of highly stable catalyst for methanol synthesis from carbon dioxide Li, Congming; Yuan, Xingdong; Fujimoto, Kaoru Applied Catalysis A: General, Vol. 469 https://doi.org/10.1016/j.apcata.2013.10.010	journal	January 2014
Efficient Conversion of Carbon Dioxide to Methanol Using Copper Catalyst by a New Low-temperature Hydrogenation Process Liu, Yong; Zhang, Yi; Wang, Tiejun Chemistry Letters, Vol. 36, Issue 9 https://doi.org/10.1246/cl.2007.1182	journal	September 2007
Catalytic activity of the M/(3ZnO·ZrO2) system (M=Cu, Ag, Au) in the hydrogenation of CO2 to methanol Słoczyński, J.; Grabowski, R.; Kozłowska, A. Applied Catalysis A: General, Vol. 278, Issue 1 https://doi.org/10.1016/j.apcata.2004.09.014	journal	December 2004
Methanol synthesis from carbon dioxide and hydrogen over Mn-promoted copper/zinc/zirconia catalysts Lachowska, Maria; Skrzypek, Jerzy Reaction Kinetics and Catalysis Letters, Vol. 83, Issue 2 https://doi.org/10.1023/B:REAC.0000046086.93121.36	journal	January 2004
Morphology-Dependent Interactions of ZnO with Cu Nanoparticles at the Materials’ Interface in Selective Hydrogenation of CO2 to CH3OH Liao, Fenglin; Huang, Yaqun; Ge, Junwei Angewandte Chemie International Edition, Vol. 50, Issue 9 https://doi.org/10.1002/anie.201007108	journal	January 2011
An infrared study of the intermediates of methanol synthesis from carbon dioxide over Pd/-GaO Collins, S.; Baltanas, M.; Bonivardi, A. Journal of Catalysis, Vol. 226, Issue 2 https://doi.org/10.1016/j.jcat.2004.06.012	journal	September 2004
Comparative study of CO and CO2 hydrogenation over supported Rh–Fe catalysts Gogate, Makarand R.; Davis, Robert J. Catalysis Communications, Vol. 11, Issue 10 https://doi.org/10.1016/j.catcom.2010.03.020	journal	May 2010
Development of Ni–Mo/Al₂O₃ Catalyst for Reverse Water Gas Shift (RWGS) Reaction Kharaji, Abolfazl Gharibi; Shariati, Ahmad; Ostadi, Mohammad Journal of Nanoscience and Nanotechnology, Vol. 14, Issue 9 https://doi.org/10.1166/jnn.2014.8962	journal	September 2014
Study of bimetallic Cu–Ni/γ-Al2O3 catalysts for carbon dioxide hydrogenation Liu, Yan; Liu, Dazhuang International Journal of Hydrogen Energy, Vol. 24, Issue 4 https://doi.org/10.1016/S0360-3199(98)00038-X	journal	April 1999
A Novel γ-Alumina Supported Fe-Mo Bimetallic Catalyst for Reverse Water Gas Shift Reaction Kharaji, Abolfazl Gharibi; Shariati, Ahmad; Takassi, Mohammad Ali Chinese Journal of Chemical Engineering, Vol. 21, Issue 9 https://doi.org/10.1016/S1004-9541(13)60573-X	journal	September 2013
A highly active and stable Co4N/γ-Al2O3 catalyst for CO and CO2 methanation to produce synthetic natural gas (SNG) Razzaq, Rauf; Li, Chunshan; Usman, Muhammad Chemical Engineering Journal, Vol. 262 https://doi.org/10.1016/j.cej.2014.10.073	journal	February 2015

Cited By (68)

Effects of the fabrication strategy on the catalytic performances of Co–Ni bimetal ordered mesoporous catalysts toward CO ₂ methanation Xu, Leilei; Cui, Yan; Chen, Mindong Sustainable Energy & Fuels, Vol. 3, Issue 11 https://doi.org/10.1039/c9se00336c	journal	January 2019
Cooperative Co ⁰ /Co ^II Sites Stabilized by a Perovskite Matrix Enable Selective C−O and C−C bond Hydrogenolysis of Oxygenated Arenes Shetty, Manish; Zanchet, Daniela; Green, William H. ChemSusChem, Vol. 12, Issue 10 https://doi.org/10.1002/cssc.201900664	journal	April 2019
Efficient electron transmission in covalent organic framework nanosheets for highly active electrocatalytic carbon dioxide reduction Zhu, Hong-Jing; Lu, Meng; Wang, Yi-Rong Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-019-14237-4	journal	January 2020
Highly Dispersed Metal Carbide on ZIF-Derived Pyridinic-N-Doped Carbon for CO ₂ Enrichment and Selective Hydrogenation Li, Yunhua; Cai, Xiaohu; Chen, Sijing ChemSusChem, Vol. 11, Issue 6 https://doi.org/10.1002/cssc.201800016	journal	February 2018
Interplay between the metal-support interaction and stability in Pt/Co ₃ O ₄ (111) model catalysts Lykhach, Yaroslava; Faisal, Firas; Skála, Tomáš Journal of Materials Chemistry A, Vol. 6, Issue 45 https://doi.org/10.1039/c8ta08142e	journal	January 2018
Hydrogen Doping into MoO ₃ Supports toward Modulated Metal-Support Interactions and Efficient Furfural Hydrogenation on Iridium Nanocatalysts Xie, Lifang; Chen, Ting; Chan, Hang Cheong Chemistry - An Asian Journal, Vol. 13, Issue 6 https://doi.org/10.1002/asia.201701661	journal	February 2018
CO2 Hydrogenation over Nanoceria-Supported Transition Metal Catalysts: Role of Ceria Morphology (Nanorods versus Nanocubes) and Active Phase Nature (Co versus Cu) Konsolakis, Michalis; Lykaki, Maria; Stefa, Sofia Nanomaterials, Vol. 9, Issue 12 https://doi.org/10.3390/nano9121739	journal	December 2019
Exploring the ternary interactions in Cu–ZnO–ZrO2 catalysts for efficient CO2 hydrogenation to methanol Wang, Yuhao; Kattel, Shyam; Gao, Wengui Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-09072-6	journal	March 2019
Inorganic Photochemistry and Solar Energy Harvesting: Current Developments and Challenges to Solar Fuel Production Sousa, Sinval F.; Souza, Breno L.; Barros, Cristiane L. International Journal of Photoenergy, Vol. 2019 https://doi.org/10.1155/2019/9624092	journal	January 2019
Ordered Mesoporous CeO ₂ ‐supported Ag as an Effective Catalyst for Carboxylative Coupling Reaction Using CO ₂ Zhang, Xiao; Wang, Dingkun; Jing, Meizan ChemCatChem, Vol. 11, Issue 8 https://doi.org/10.1002/cctc.201900039	journal	April 2019
In situ observations of the structural dynamics of platinum–cobalt–hydroxide nanocatalysts under CO oxidation Huang, Li; Song, Xueyang; Lin, Yue Nanoscale, Vol. 12, Issue 5 https://doi.org/10.1039/c9nr10950a	journal	January 2020
Highly efficient reversible protonic ceramic electrochemical cells for power generation and fuel production Duan, Chuancheng; Kee, Robert; Zhu, Huayang Nature Energy, Vol. 4, Issue 3 https://doi.org/10.1038/s41560-019-0333-2	journal	March 2019
Nitrogen-Doped Graphene Quantum Dots Enhance the Activity of Bi ₂ O ₃ Nanosheets for Electrochemical Reduction of CO ₂ in a Wide Negative Potential Region Chen, Zhipeng; Mou, Kaiwen; Wang, Xiaohan Angewandte Chemie, Vol. 130, Issue 39 https://doi.org/10.1002/ange.201807643	journal	August 2018
Effect of aluminum vacancies on the H ₂ O ₂ or H ₂ O interaction with a gamma‐AlOOH surface. A solid‐state DFT study Medvedev, Alexander G.; Mikhaylov, Alexey A.; Chernyshov, Ivan Yu. International Journal of Quantum Chemistry, Vol. 119, Issue 13 https://doi.org/10.1002/qua.25920	journal	December 2018
Chemically and electrochemically catalysed conversion of CO2 to CO with follow-up utilization to value-added chemicals Nielsen, Dennis U.; Hu, Xin-Ming; Daasbjerg, Kim Nature Catalysis, Vol. 1, Issue 4 https://doi.org/10.1038/s41929-018-0051-3	journal	April 2018
Copper atom-pair catalyst anchored on alloy nanowires for selective and efficient electrochemical reduction of CO2 Jiao, Jiqing; Lin, Rui; Liu, Shoujie Nature Chemistry, Vol. 11, Issue 3 https://doi.org/10.1038/s41557-018-0201-x	journal	January 2019
Hydroxyl-mediated ethanol selectivity of CO ₂ hydrogenation Yang, Chengsheng; Mu, Rentao; Wang, Guishuo Chemical Science, Vol. 10, Issue 11 https://doi.org/10.1039/c8sc05608k	journal	January 2019
Direct coating copper–zinc–aluminum oxalate with H-ZSM-5 to fabricate a highly efficient capsule-structured bifunctional catalyst for dimethyl ether production from syngas Sun, Yingqi; Han, Xinghua; Zhao, Zhongkui Catalysis Science & Technology, Vol. 9, Issue 14 https://doi.org/10.1039/c9cy00980a	journal	January 2019
Remarkable Carbon Dioxide Hydrogenation to Ethanol on a Palladium/Iron Oxide Single-Atom Catalyst Caparrós, Francisco J.; Soler, Lluís; Rossell, Marta D. ChemCatChem, Vol. 10, Issue 11 https://doi.org/10.1002/cctc.201800362	journal	May 2018
Mechanisms of catalytic reduction of CO 2 with heme and nonheme metal complexes Fukuzumi, Shunichi; Lee, Yong-Min; Ahn, Hyun S. Chemical Science, Vol. 9, Issue 28 https://doi.org/10.1039/c8sc02220h	journal	January 2018
Capsule‐Structured Copper–Zinc Catalyst for Highly Efficient Hydrogenation of Carbon Dioxide to Methanol Guo, Yongle; Guo, Xinwen; Song, Chunshan ChemSusChem, Vol. 12, Issue 22 https://doi.org/10.1002/cssc.201902911	journal	November 2019
Ultrasmall Ni nanoparticles embedded in Zr-based MOFs provide high selectivity for CO ₂ hydrogenation to methane at low temperatures Zhao, Zhi-Wei; Zhou, Xiao; Liu, Ya-Nan Catalysis Science & Technology, Vol. 8, Issue 12 https://doi.org/10.1039/c8cy00468d	journal	January 2018
A short review of recent advances in CO 2 hydrogenation to hydrocarbons over heterogeneous catalysts Li, Wenhui; Wang, Haozhi; Jiang, Xiao RSC Advances, Vol. 8, Issue 14 https://doi.org/10.1039/c7ra13546g	journal	January 2018
The effects of bimetallic interactions for CO ₂ ‐assisted oxidative dehydrogenation and dry reforming of propane Gomez, Elaine; Xie, Zhenhua; Chen, Jingguang G. AIChE Journal, Vol. 65, Issue 8 https://doi.org/10.1002/aic.16670	journal	June 2019
Copper–Zirconia Catalysts: Powerful Multifunctional Catalytic Tools to Approach Sustainable Processes Scotti, Nicola; Bossola, Filippo; Zaccheria, Federica Catalysts, Vol. 10, Issue 2 https://doi.org/10.3390/catal10020168	journal	February 2020
Metal‐free graphene/boron nitride heterointerface for CO ₂ reduction: Surface curvature controls catalytic activity and selectivity Mao, Xin; Wijethunge, Dimuthu; Zhang, Lei EcoMat, Vol. 2, Issue 1 https://doi.org/10.1002/eom2.12013	journal	January 2020
Towards Solar Methanol: Past, Present, and Future Tountas, Athanasios A.; Peng, Xinyue; Tavasoli, Alexandra V. Advanced Science, Vol. 6, Issue 8 https://doi.org/10.1002/advs.201801903	journal	February 2019
Experimental performance investigation of a 2 kW methanation reactor Gallandat, Noris; Mutschler, Robin; Vernay, Vincent Sustainable Energy & Fuels, Vol. 2, Issue 5 https://doi.org/10.1039/c8se00073e	journal	January 2018
CO2 hydrogenation to high-value products via heterogeneous catalysis Ye, Run-Ping; Ding, Jie; Gong, Weibo Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-13638-9	journal	December 2019
Tuning Cu/Cu ₂ O Interfaces for the Reduction of Carbon Dioxide to Methanol in Aqueous Solutions Chang, Xiaoxia; Wang, Tuo; Zhao, Zhi‐Jian Angewandte Chemie, Vol. 130, Issue 47 https://doi.org/10.1002/ange.201805256	journal	November 2018
Fast real time and quantitative gas analysis method for the investigation of the CO ₂ reduction reaction mechanism Mutschler, Robin; Luo, Wen; Moioli, Emanuele Review of Scientific Instruments, Vol. 89, Issue 11 https://doi.org/10.1063/1.5047402	journal	November 2018
Silicon-doped graphene edges: an efficient metal-free catalyst for the reduction of CO ₂ into methanol and ethanol Mao, Xin; Kour, Gurpreet; Zhang, Lei Catalysis Science & Technology, Vol. 9, Issue 23 https://doi.org/10.1039/c9cy01709g	journal	January 2019
CO ₂ reactivity with Mg ₂ NiH ₄ synthesized by in situ monitoring of mechanical milling Grasso, M. L.; Puszkiel, J.; Gennari, F. C. Physical Chemistry Chemical Physics, Vol. 22, Issue 4 https://doi.org/10.1039/c9cp05697a	journal	January 2020
Kinetic control of CeO2 nanoparticles for catalytic CO oxidation Han, Bingqi; Li, Huixia; Li, Liping Journal of Materials Research, Vol. 34, Issue 13 https://doi.org/10.1557/jmr.2018.456	journal	February 2019
Electronic Tuning of Co, Ni-Based Nanostructured (Hydr)oxides for Aqueous Electrocatalysis Kuang, Min; Han, Peng; Huang, Linsong Advanced Functional Materials, Vol. 28, Issue 52 https://doi.org/10.1002/adfm.201804886	journal	November 2018
One-Step Synthesis of Metal/Oxide Nanocomposites by Gas Phase Condensation Patelli, Nicola; Migliori, Andrea; Morandi, Vittorio Nanomaterials, Vol. 9, Issue 2 https://doi.org/10.3390/nano9020219	journal	February 2019
Rethinking Co(CO ₃ ) _0.5 (OH)·0.11H ₂ O: a new property for highly selective electrochemical reduction of carbon dioxide to methanol in aqueous solution Huang, Jianzhi; Hu, Qiong; Guo, Xinrong Green Chemistry, Vol. 20, Issue 13 https://doi.org/10.1039/c7gc03744a	journal	January 2018
Layered Double Hydroxide-Based Catalysts: Recent Advances in Preparation, Structure, and Applications Xu, Ming; Wei, Min Advanced Functional Materials, Vol. 28, Issue 47 https://doi.org/10.1002/adfm.201802943	journal	September 2018
The Interplay between Structure and Product Selectivity of CO 2 Hydrogenation Yang, Chengsheng; Liu, Sihang; Wang, Yanan Angewandte Chemie International Edition, Vol. 58, Issue 33 https://doi.org/10.1002/anie.201904649	journal	June 2019
The renaissance of the Sabatier reaction and its applications on Earth and in space Vogt, Charlotte; Monai, Matteo; Kramer, Gert Jan Nature Catalysis, Vol. 2, Issue 3 https://doi.org/10.1038/s41929-019-0244-4	journal	March 2019
Implanting Copper−Zinc Nanoparticles into the Matrix of Mesoporous Alumina as a Highly Selective Bifunctional Catalyst for Direct Synthesis of Dimethyl Ether from Syngas Sun, Yingqi; Zhao, Zhongkui ChemCatChem, Vol. 12, Issue 5 https://doi.org/10.1002/cctc.201902166	journal	January 2020
Porous MoxCy/SiO2 Material for CO2 Hydrogenation García Blanco, Andrés A.; Furlong, Octavio J.; Stacchiola, Dario J. Topics in Catalysis, Vol. 62, Issue 12-16 https://doi.org/10.1007/s11244-019-01195-w	journal	August 2019
Highly efficient binary copper−iron catalyst for photoelectrochemical carbon dioxide reduction toward methane Zhou, Baowen; Ou, Pengfei; Pant, Nick Proceedings of the National Academy of Sciences, Vol. 117, Issue 3 https://doi.org/10.1073/pnas.1911159117	journal	January 2020
Two-dimensional-related catalytic materials for solar-driven conversion of CO _x into valuable chemical feedstocks Zhao, Yufei; Waterhouse, Geoffrey I. N.; Chen, Guangbo Chemical Society Reviews, Vol. 48, Issue 7 https://doi.org/10.1039/c8cs00607e	journal	January 2019
Selective hydrogenation of CO ₂ to methanol catalyzed by Cu supported on rod-like La ₂ O ₂ CO ₃ Chen, Kun; Duan, Xinping; Fang, Huihuang Catalysis Science & Technology, Vol. 8, Issue 4 https://doi.org/10.1039/c7cy01998j	journal	January 2018
The Methanol Economy: Methane and Carbon Dioxide Conversion Liu, Wen-Chi; Baek, Jayeon; Somorjai, Gabor A. Topics in Catalysis, Vol. 61, Issue 7-8 https://doi.org/10.1007/s11244-018-0907-4	journal	March 2018
Enhanced hot electron generation by inverse metal–oxide interfaces on catalytic nanodiode Lee, Hyosun; Yoon, Sinmyung; Jo, Jinwoung Faraday Discussions, Vol. 214 https://doi.org/10.1039/c8fd00136g	journal	January 2019
Nickel@Siloxene catalytic nanosheets for high-performance CO2 methanation Yan, Xiaoliang; Sun, Wei; Fan, Liming Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-10464-x	journal	June 2019
Recent advances in the nanoengineering of electrocatalysts for CO ₂ reduction Li, Fengwang; MacFarlane, Douglas R.; Zhang, Jie Nanoscale, Vol. 10, Issue 14 https://doi.org/10.1039/c7nr09620h	journal	January 2018
Recent Progress in the Theoretical Investigation of Electrocatalytic Reduction of CO ₂ Tian, Ziqi; Priest, Chad; Chen, Liang Advanced Theory and Simulations, Vol. 1, Issue 5 https://doi.org/10.1002/adts.201800004	journal	April 2018
Porous hypercrosslinked polymer-TiO2-graphene composite photocatalysts for visible-light-driven CO2 conversion Wang, Shaolei; Xu, Min; Peng, Tianyou Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-08651-x	journal	February 2019
Asymmetric nickel hollow fibres as the catalytic membrane reactor for CO ₂ hydrogenation into syngas Wang, Mingming; Tan, Xiaoyao; Wang, Xiaobin Chemical Communications, Vol. 55, Issue 29 https://doi.org/10.1039/c9cc00082h	journal	January 2019
Analysis of the autothermal operability of the Sabatier reaction in a heat-recirculating microreactor using CFD Raghu, Aswathy K.; Kaisare, Niket S. Reaction Chemistry & Engineering, Vol. 4, Issue 10 https://doi.org/10.1039/c9re00183b	journal	January 2019
Unravelling the Promotional Effect of La ₂ O ₃ in Pt/La‐TiO ₂ Catalysts for CO ₂ Hydrogenation Wang, Zhaoyu; Huang, Lijuan; Su, Bo Chemistry – A European Journal, Vol. 26, Issue 2 https://doi.org/10.1002/chem.201903946	journal	November 2019
Two-dimensional transition metal carbides as supports for tuning the chemistry of catalytic nanoparticles Li, Zhe; Yu, Liang; Milligan, Cory Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-07502-5	journal	December 2018
DFT study of In ₂ O ₃ -catalyzed methanol synthesis from CO ₂ and CO hydrogenation on the defective site Dou, Maobin; Zhang, Minhua; Chen, Yifei New Journal of Chemistry, Vol. 42, Issue 5 https://doi.org/10.1039/c7nj04273f	journal	January 2018
Optimized Pt-Based Catalysts for Oxygen Reduction Reaction in Alkaline Solution: A First Principle Study Liu, Shizhong; Liu, Ping Journal of The Electrochemical Society, Vol. 165, Issue 15 https://doi.org/10.1149/2.0171815jes	journal	January 2018
Surface chemistry imposes selective reduction of CO ₂ to CO over Ta ₃ N ₅ /LaTiO ₂ N photocatalyst Lu, Lei; Wang, Shaomang; Zhou, Chenguang Journal of Materials Chemistry A, Vol. 6, Issue 30 https://doi.org/10.1039/c8ta05339a	journal	January 2018
Confinement of subnanometric PdZn at a defect enriched ZnO/ZIF-8 interface for efficient and selective CO ₂ hydrogenation to methanol Li, Xinliang; Liu, Guoliang; Xu, Di Journal of Materials Chemistry A, Vol. 7, Issue 41 https://doi.org/10.1039/c9ta03410b	journal	January 2019
Selective transformation of carbon dioxide into lower olefins with a bifunctional catalyst composed of ZnGa ₂ O ₄ and SAPO-34 Liu, Xiaoliang; Wang, Mengheng; Zhou, Cheng Chemical Communications, Vol. 54, Issue 2 https://doi.org/10.1039/c7cc08642c	journal	January 2018
From CO ₂ methanation to ambitious long-chain hydrocarbons: alternative fuels paving the path to sustainability Marques Mota, Filipe; Kim, Dong Ha Chemical Society Reviews, Vol. 48, Issue 1 https://doi.org/10.1039/c8cs00527c	journal	January 2019
CO ₂ adsorption on hydroxylated In ₂ O ₃ (110) Posada-Borbón, Alvaro; Grönbeck, Henrik Physical Chemistry Chemical Physics, Vol. 21, Issue 39 https://doi.org/10.1039/c9cp04097h	journal	January 2019
Enhancing CO ₂ methanation over a metal foam structured catalyst by electric internal heating Dou, Liguang; Yan, Cunji; Zhong, Liangshu Chemical Communications, Vol. 56, Issue 2 https://doi.org/10.1039/c9cc07525a	journal	January 2020
Tuning Cu/Cu ₂ O Interfaces for the Reduction of Carbon Dioxide to Methanol in Aqueous Solutions Chang, Xiaoxia; Wang, Tuo; Zhao, Zhi‐Jian Angewandte Chemie International Edition, Vol. 57, Issue 47 https://doi.org/10.1002/anie.201805256	journal	November 2018
Capsule‐Structured Copper–Zinc Catalyst for Highly Efficient Hydrogenation of Carbon Dioxide to Methanol Guo, Yongle; Guo, Xinwen; Song, Chunshan ChemSusChem, Vol. 12, Issue 22 https://doi.org/10.1002/cssc.201902485	journal	October 2019
Nitrogen-Doped Graphene Quantum Dots Enhance the Activity of Bi ₂ O ₃ Nanosheets for Electrochemical Reduction of CO ₂ in a Wide Negative Potential Region Chen, Zhipeng; Mou, Kaiwen; Wang, Xiaohan Angewandte Chemie International Edition, Vol. 57, Issue 39 https://doi.org/10.1002/anie.201807643	journal	August 2018
Adsorption of SF₆ Decomposed Products over ZnO(101̅0): Effects of O and Zn Vacancies Chen, Dachang; Zhang, Xiaoxing; Tang, Ju ACS Omega, Vol. 3, Issue 12 https://doi.org/10.1021/acsomega.8b02933	journal	December 2018
Synthesis of PdS _x -Mediated Polydymite Heteronanorods and Their Long-Range Activation for Enhanced Water Electroreduction Gao, Qiang; Wu, Rui; Liu, Yang Research, Vol. 2019 https://doi.org/10.34133/2019/8078549	journal	January 2019

Similar Records

Hydrogenation of CO₂ to methanol: Importance of metal–oxide and metal–carbide interfaces in the activation of CO₂

Journal Article · Wed Sep 30 00:00:00 EDT 2015 · ACS Catalysis · OSTI ID:1395947

Rodriguez, José A.; Liu, Ping; Stacchiola, Dario J.; +3 more

Cesium-Induced Active Sites for C–C Coupling and Ethanol Synthesis from CO₂ Hydrogenation on Cu/ZnO(000$\bar{1}$) Surfaces

Journal Article · Fri Jul 23 00:00:00 EDT 2021 · Journal of the American Chemical Society · OSTI ID:1395947

Wang, Xuelong; Ramírez, Pedro J.; Liao, Wenjie; +2 more

Enhanced CO₂ Methanation Activity of Sm_0.25Ce_0.75O_2-δ–Ni by Modulating the Chelating Agents-to-Metal Cation Ratio and Tuning Metal–Support Interactions

Journal Article · Wed Mar 09 00:00:00 EST 2022 · ACS Applied Materials and Interfaces · OSTI ID:1395947

Liu, Fan; Park, Yoo Sei; Diercks, David; +2 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Title: Tuning Selectivity of CO2 Hydrogenation Reactions at the Metal/Oxide Interface

Citation Formats

References (163)

Cited By (68)

Similar Records

Related Subjects

Title: Tuning Selectivity of CO₂ Hydrogenation Reactions at the Metal/Oxide Interface