Application of Pulse Radiolysis to Mechanistic Investigations of Catalysis Relevant to Artificial Photosynthesis

Fujita, Etsuko; Grills, David C.; Polyansky, Dmitry E.

doi:10.1002/cssc.201701559

Title: Application of Pulse Radiolysis to Mechanistic Investigations of Catalysis Relevant to Artificial Photosynthesis

Journal Article · Tue Sep 12 00:00:00 EDT 2017 · ChemSusChem

DOI:https://doi.org/10.1002/cssc.201701559· OSTI ID:1395945

Fujita, Etsuko ^[1]; Grills, David C. ^[1]; Polyansky, Dmitry E. ^[1]

Brookhaven National Lab. (BNL), Upton, NY (United States)

Taking inspiration from natural photosystems, the goal of artificial photosynthesis is to harness solar energy to convert abundant materials, such as CO₂ and H₂O, into solar fuels. Catalysts are required to ensure that the necessary redox half-reactions proceed in the most energy-efficient manner. It is thus critical to gain a detailed mechanistic understanding of these catalytic reactions in order to develop new and improved catalysts. Many of the key catalytic intermediates are short-lived transient species, requiring time-resolved spectroscopic techniques for their observation. The two main methods for rapidly generating such species on the sub-microsecond timescale are laser flash photolysis and pulse radiolysis. These methods complement one another, and both can provide important spectroscopic and kinetic information. However, pulse radiolysis proves to be superior in systems with significant spectroscopic overlap between photosensitizer and other species present during the reaction. In this paper, we review the pulse radiolysis technique and how it has been applied to mechanistic investigations of half-reactions relevant to artificial photosynthesis.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704

OSTI ID:: 1395945

Alternate ID(s):: OSTI ID: 1407812

Report Number(s):: BNL-114372-2017-JA; R&D Project: CO026; KC0304030

Journal Information:: ChemSusChem, Vol. 10, Issue 22; ISSN 1864-5631

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 21 works

Citation information provided by
Web of Science

References (71)

Application of Pulse Radiolysis to Mechanistic Investigations of Water Oxidation Catalysis: Mechanistic Investigations of Water Oxidation Catalysis Polyansky, Dmitry E.; Hurst, James K.; Lymar, Sergei V. European Journal of Inorganic Chemistry, Vol. 2014, Issue 4 https://doi.org/10.1002/ejic.201300753	journal	September 2013
Formation and decay of zinc tetrakis (N-methyl-3-pyridyl)porphine π-radical cation in water Richoux, Marie-Claude; Neta, Pedatsur; Christensen, Paul A. J. Chem. Soc., Faraday Trans. 2, Vol. 82, Issue 2 https://doi.org/10.1039/F29868200235	journal	January 1986
Photochemical and Radiolytic Production of an Organic Hydride Donor with a RuII Complex Containing an NAD+ Model Ligand Polyansky, Dmitry; Cabelli, Diane; Muckerman, James T. Angewandte Chemie, Vol. 119, Issue 22 https://doi.org/10.1002/ange.200700304	journal	May 2007
Polyelectrolyte-stabilized metal oxide hydrosols as catalysts for the photooxidation of water by zinc porphyrins Nahor, Gad S.; Mosseri, S.; Neta, P. The Journal of Physical Chemistry, Vol. 92, Issue 15 https://doi.org/10.1021/j100326a049	journal	July 1988
Mechanism of Hydride Donor Generation Using a Ru(II) Complex Containing an NAD ⁺ Model Ligand: Pulse and Steady-State Radiolysis Studies Polyansky, Dmitry E.; Cabelli, Diane; Muckerman, James T. Inorganic Chemistry, Vol. 47, Issue 10 https://doi.org/10.1021/ic702139n	journal	May 2008
A New Family of Ru Complexes for Water Oxidation Zong, Ruifa; Thummel, Randolph P. Journal of the American Chemical Society, Vol. 127, Issue 37 https://doi.org/10.1021/ja054791m	journal	September 2005
Binding of carbon dioxide to cobalt and nickel tetra-aza macrocycles Gangi, Dorothea A.; Durand, Richard R. Journal of the Chemical Society, Chemical Communications, Issue 9 https://doi.org/10.1039/c39860000697	journal	January 1986
Reduction of Cobalt and Iron Phthalocyanines and the Role of the Reduced Species in Catalyzed Photoreduction of CO ₂ Grodkowski, J.; Dhanasekaran, T.; Neta, P. The Journal of Physical Chemistry A, Vol. 104, Issue 48 https://doi.org/10.1021/jp002709y	journal	December 2000
Iron Porphyrin-Catalyzed Reduction of CO ₂ . Photochemical and Radiation Chemical Studies Grodkowski, J.; Behar, D.; Neta, P. The Journal of Physical Chemistry A, Vol. 101, Issue 3 https://doi.org/10.1021/jp9628139	journal	January 1997
Direct XANES Evidence for Charge Transfer in Co−CO ₂ Complexes Fujita, Etsuko; Furenlid, Lars R.; Renner, Mark W. Journal of the American Chemical Society, Vol. 119, Issue 19 https://doi.org/10.1021/ja970151a	journal	May 1997
Tetraaza-macrocyclic cobalt(II) and nickel(II) complexes as electron-transfer agents in the photo(electro)chemical and electrochemical reduction of carbon dioxide Tinnemans, A. H. A.; Koster, T. P. M.; Thewissen, D. H. M. W. Recueil des Travaux Chimiques des Pays-Bas, Vol. 103, Issue 10 https://doi.org/10.1002/recl.19841031004	journal	January 1984
Reversible Hydride Generation and Release from the Ligand of [Ru(pbn)(bpy)2](PF6)2 Driven by a pbn-Localized Redox Reaction Koizumi, Take-aki; Tanaka, Koji Angewandte Chemie, Vol. 117, Issue 36 https://doi.org/10.1002/ange.200500760	journal	September 2005
Catalysis of the electrochemical reduction of carbon dioxide Costentin, Cyrille; Robert, Marc; Savéant, Jean-Michel Chem. Soc. Rev., Vol. 42, Issue 6 https://doi.org/10.1039/C2CS35360A	journal	January 2013
Mechanistic Information from Pressure Acceleration of Hydride Formation via Proton Binding to a Cobalt(I) Macrocycle Fujita, Etsuko; Wishart, James F.; van Eldik, Rudi Inorganic Chemistry, Vol. 41, Issue 6 https://doi.org/10.1021/ic011109q	journal	March 2002
Syntheses and Redox Properties of Bis(hydroxoruthenium) Complexes with Quinone and Bipyridine Ligands. Water-Oxidation Catalysis Wada, Tohru; Tsuge, Kiyoshi; Tanaka, Koji Inorganic Chemistry, Vol. 40, Issue 2 https://doi.org/10.1021/ic000552i	journal	January 2001
Carbon dioxide activation by cobalt(I) macrocycles: factors affecting carbon dioxide and carbon monoxide binding Fujita, Etsuko; Creutz, Carol; Sutin, Norman Journal of the American Chemical Society, Vol. 113, Issue 1 https://doi.org/10.1021/ja00001a048	journal	January 1991
Metal oxides as heterogeneous catalysts for oxygen evolution under photochemical conditions Harriman, Anthony; Pickering, Ingrid J.; Thomas, John M. Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 84, Issue 8 https://doi.org/10.1039/f19888402795	journal	January 1988
Carbon dioxide activation by cobalt macrocycles: evidence of hydrogen bonding between bound CO2 and the macrocycle in solution Fujita, Etsuko; Creutz, Carol; Sutin, Norman Inorganic Chemistry, Vol. 32, Issue 12 https://doi.org/10.1021/ic00064a015	journal	June 1993
p -Terphenyl-Sensitized Photoreduction of CO ₂ with Cobalt and Iron Porphyrins. Interaction between CO and Reduced Metalloporphyrins Dhanasekaran, T.; Grodkowski, J.; Neta, P. The Journal of Physical Chemistry A, Vol. 103, Issue 38 https://doi.org/10.1021/jp991423u	journal	September 1999
Optical spectra and reactivities of radical anions of 4-nitrobenzyl compounds produced by pulse radiolysis of acetonitrile solutions Burrows, H. D.; Kosower, Edward M. The Journal of Physical Chemistry, Vol. 78, Issue 2 https://doi.org/10.1021/j100595a006	journal	January 1974
Steric effect for proton, hydrogen-atom, and hydride transfer reactions with geometric isomers of NADH–model ruthenium complexes Cohen, Brian W.; Polyansky, Dmitry E.; Achord, Patrick Faraday Discuss., Vol. 155 https://doi.org/10.1039/C1FD00094B	journal	January 2012
The reactivity of cobalt(I) complexes containing unsaturated macrocyclic ligands in aqueous solution Tait, A. Martin; Hoffman, Morton Z.; Hayon, E. Journal of the American Chemical Society, Vol. 98, Issue 1 https://doi.org/10.1021/ja00417a015	journal	January 1976
Decay of high-valent manganese porphyrins in aqueous solution and catalysed formation of oxygen Harriman, Anthony; Christensen, Paul A.; Porter, George Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 82, Issue 10 https://doi.org/10.1039/f19868203215	journal	January 1986
A review of iron and cobalt porphyrins, phthalocyanines and related complexes for electrochemical and photochemical reduction of carbon dioxide Manbeck, Gerald F.; Fujita, Etsuko Journal of Porphyrins and Phthalocyanines, Vol. 19, Issue 01-03 https://doi.org/10.1142/S1088424615300013	journal	January 2015
Reaction of tris(bipyridine)ruthenium(III) with hydroxide and its application in a solar energy storage system Creutz, C.; Sutin, N. Proceedings of the National Academy of Sciences, Vol. 72, Issue 8 https://doi.org/10.1073/pnas.72.8.2858	journal	August 1975
The Pulse Radiolysis of Deaerated Aqueous Carbonate Solutions. I. Transient Optical Spectrum and Mechanism. II. pK for OH Radicals ¹ Weeks, James L.; Rabani, Joseph The Journal of Physical Chemistry, Vol. 70, Issue 7 https://doi.org/10.1021/j100879a005	journal	July 1966
Artificial analogues of the oxygen-evolving complex in photosynthesis: the oxo-bridged ruthenium dimer L2(H2O)RuIII-O-RuIII(H2O)L2, L = 2,2'-bipyridyl-4,4'-dicarboxylate Comte, Pascal; Nazeeruddin, Mohammad K.; Rotzinger, Francois P. Journal of Molecular Catalysis, Vol. 52, Issue 1 https://doi.org/10.1016/0304-5102(89)80082-3	journal	June 1989
Oxidation of Water to Dioxygen by Intrazeolitic Ru(bpy)33+ Ledney, Michael; Dutta, Prabir K. Journal of the American Chemical Society, Vol. 117, Issue 29 https://doi.org/10.1021/ja00134a013	journal	July 1995
Solution studies of the cobalt(II) N-rac- and N-meso-Col2+ isomers and molecular and crystal structures of the low-spin, five-coordinate cobalt(II) macrocyclic complexes N-rac-[CoL(H2O)](ClO4)2.cntdot.0.6H2O (1) and N-rac-[CoL(OC103)]ClO4 (2) (L = 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4, 11-diene) Szalda, David J.; Schwarz, Carolyn L.; Endicott, John F. Inorganic Chemistry, Vol. 28, Issue 16 https://doi.org/10.1021/ic00315a026	journal	August 1989
Thermodynamics and kinetics of carbon dioxide binding to two stereoisomers of a cobalt(I) macrocycle in aqueous solution Creutz, Carol; Schwarz, Harold A.; Wishart, James F. Journal of the American Chemical Society, Vol. 113, Issue 9 https://doi.org/10.1021/ja00009a022	journal	April 1991
Iridium oxide hydrosols as catalysts for the decay of zinc porphyrin radical cations in water Harriman, Anthony; Nahor, Gad S.; Mosseri, Shlomo Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 84, Issue 8 https://doi.org/10.1039/f19888402821	journal	January 1988
Pulse radiolysis of titanium(III) and other metal(III) ions in the presence of formic acid Ellis, J. David; Green, Mark; Sykes, A. Geoffrey Journal of the Chemical Society, Dalton Transactions, Issue 16 https://doi.org/10.1039/dt9730001724	journal	January 1973
Water Oxidation by a Ruthenium Complex with Noninnocent Quinone Ligands: Possible Formation of an O−O Bond at a Low Oxidation State of the Metal Muckerman, James T.; Polyansky, Dmitry E.; Wada, Tohru Inorganic Chemistry, Vol. 47, Issue 6 https://doi.org/10.1021/ic701892v	journal	March 2008
Reversible Hydride Generation and Release from the Ligand of [Ru(pbn)(bpy)2](PF6)2 Driven by a pbn-Localized Redox Reaction Koizumi, Take-aki; Tanaka, Koji Angewandte Chemie International Edition, Vol. 44, Issue 36 https://doi.org/10.1002/anie.200500760	journal	September 2005
Calculation of thermodynamic hydricities and the design of hydride donors for CO2 reduction Muckerman, J. T.; Achord, P.; Creutz, C. Proceedings of the National Academy of Sciences, Vol. 109, Issue 39 https://doi.org/10.1073/pnas.1201026109	journal	July 2012
The Thermodynamics and Kinetics of CO2 and H+ Binding to Ni(cyclam)+ in Aqueous Solution Kelly, Craig A.; Mulazzani, Quinto G.; Venturi, Margherita Journal of the American Chemical Society, Vol. 117, Issue 17 https://doi.org/10.1021/ja00122a023	journal	May 1995
Mechanistic Studies of Hydrogen Evolution in Aqueous Solution Catalyzed by a Tertpyridine–Amine Cobalt Complex Lewandowska-Andralojc, Anna; Baine, Teera; Zhao, Xuan Inorganic Chemistry, Vol. 54, Issue 9 https://doi.org/10.1021/ic5031137	journal	April 2015
A pulse-radiolytic and photochemical study of the oxidation of water by zinc porphyrin π-radical cations Christensen, Paul A.; Harriman, Anthony; Porter, George J. Chem. Soc., Faraday Trans. 2, Vol. 80, Issue 11 https://doi.org/10.1039/F29848001451	journal	January 1984
Radiolytic study of the reactions of hydroxyl radical with cobalt(III), iron(II), and ruthenium(II) complexes containing 2,2'-bipyridyl and cyano ligands Maliyackel, A. C.; Waltz, W. L.; Lilie, J. Inorganic Chemistry, Vol. 29, Issue 2 https://doi.org/10.1021/ic00327a037	journal	January 1990
Effects of redox potential, steric configuration, solvent, and alkali metal cations on the binding of carbon dioxide to cobalt(I) and nickel(I) macrocycles Schmidt, Michael H.; Miskelly, Gordon M.; Lewis, Nathan S. Journal of the American Chemical Society, Vol. 112, Issue 9 https://doi.org/10.1021/ja00165a027	journal	April 1990
Reactions of magnesium porphyrin radical cations in water. Disproportionation, oxygen production, and comparison with other metalloporphyrins Harriman, Anthony; Neta, P.; Richoux, Marie Claude The Journal of Physical Chemistry, Vol. 90, Issue 15 https://doi.org/10.1021/j100406a028	journal	July 1986
Photochemical Stereospecific Hydrogenation of a Ru Complex with an NAD ⁺ /NADH-Type Ligand Fukushima, Takashi; Fujita, Etsuko; Muckerman, James T. Inorganic Chemistry, Vol. 48, Issue 24 https://doi.org/10.1021/ic901935u	journal	December 2009
Cobalt Corrin Catalyzed Photoreduction of CO ₂ Grodkowski, J.; Neta, P. The Journal of Physical Chemistry A, Vol. 104, Issue 9 https://doi.org/10.1021/jp9939569	journal	March 2000
Characterization of Intermediary Redox States of the Water Oxidation Catalyst, [Ru(bpy) ₂ (OH ₂ )] ₂ O ⁴⁺ Cape, Jonathan L.; Lymar, Sergei V.; Lightbody, Travis Inorganic Chemistry, Vol. 48, Issue 10 https://doi.org/10.1021/ic9001219	journal	May 2009
Photochemical and Radiolytic Production of an Organic Hydride Donor with a RuII Complex Containing an NAD+ Model Ligand Polyansky, Dmitry; Cabelli, Diane; Muckerman, James T. Angewandte Chemie International Edition, Vol. 46, Issue 22 https://doi.org/10.1002/anie.200700304	journal	May 2007
Resonance stabilisation of zinc porphyrin π-radical cations Neta, Pedatsur; Richoux, Marie-Claude; Harriman, Anthony J. Chem. Soc., Faraday Trans. 2, Vol. 82, Issue 2 https://doi.org/10.1039/F29868200209	journal	January 1986
Acid−Base and Electrochemical Properties of the MLCT Excited States and One-Electron-Reduced Forms of Ruthenium(II) Complexes Containing 2-(2‘-Pyridyl)pyrimidine and 2,2‘-Bipyridine in Aqueous Solution Casalboni, Fiorella; Mulazzani, Quinto G.; Clark, Catherine D. Inorganic Chemistry, Vol. 36, Issue 11 https://doi.org/10.1021/ic960657e	journal	May 1997
A Local Proton Source Enhances CO ₂ Electroreduction to CO by a Molecular Fe Catalyst Costentin, Cyrille; Drouet, Samuel; Robert, Marc Science, Vol. 338, Issue 6103 https://doi.org/10.1126/science.1224581	journal	October 2012
Catalytic oxidation of water by an oxo-bridged ruthenium dimer Gersten, Susan W.; Samuels, George J.; Meyer, Thomas J. Journal of the American Chemical Society, Vol. 104, Issue 14 https://doi.org/10.1021/ja00378a053	journal	July 1982
A dissociative pathway for equilibration of a hydrido CoL(H)2+ complex with carbon dioxide and carbon monoxide. Ligand binding constants in the macrocyclic [14]-dienecobalt(I) system Creutz, Carol; Schwarz, Harold A.; Wishart, James F. Journal of the American Chemical Society, Vol. 111, Issue 3 https://doi.org/10.1021/ja00185a069	journal	February 1989
Kinetic Studies of the Reduction of [Co(dmgH) ₂ (py)(Cl)] Revisited: Mechanisms, Products, and Implications Kahnt, Axel; Peuntinger, Katrin; Dammann, Claudia The Journal of Physical Chemistry A, Vol. 118, Issue 25 https://doi.org/10.1021/jp501947y	journal	June 2014
Mechanism of CO ₂ and H ⁺ Reduction by Ni(cyclam) ⁺ in Aqueous Solution. A Pulse and Continuous Radiolysis Study Kelly, Craig A.; Blinn, Elliott L.; Camaioni, Nadia Inorganic Chemistry, Vol. 38, Issue 7 https://doi.org/10.1021/ic980902p	journal	April 1999
Turning on the Protonation-First Pathway for Electrocatalytic CO ₂ Reduction by Manganese Bipyridyl Tricarbonyl Complexes Ngo, Ken T.; McKinnon, Meaghan; Mahanti, Bani Journal of the American Chemical Society, Vol. 139, Issue 7 https://doi.org/10.1021/jacs.6b08776	journal	February 2017
The radiation chemistry of metal ions in aqueous solution Buxton, George V.; Sellers, Robin M. Coordination Chemistry Reviews, Vol. 22, Issue 3 https://doi.org/10.1016/S0010-8545(00)80328-8	journal	April 1977
Mechanistic and Kinetic Studies of Cobalt Macrocycles in a Photochemical CO2 Reduction System: Evidence of Co-CO2 Adducts as Intermediates Ogata, Tomoyuki; Yanagida, Shozo; Brunschwig, Bruce S. Journal of the American Chemical Society, Vol. 117, Issue 25 https://doi.org/10.1021/ja00130a009	journal	June 1995
Catalysis of the Electrochemical Reduction of Carbon Dioxide by Iron(0) Porphyrins: Synergystic Effect of Weak Brönsted Acids Bhugun, Iqbal; Lexa, Doris; Savéant, Jean-Michel Journal of the American Chemical Society, Vol. 118, Issue 7 https://doi.org/10.1021/ja9534462	journal	January 1996
Formation and decomposition of iron-carbon .sigma.-bonds in the reaction of iron(II)-poly(amino carboxylate) complexes with CO2-free radicals. A pulse radiolysis study Goldstein, Sara.; Czapski, Gidon.; Cohen, Haim. Journal of the American Chemical Society, Vol. 110, Issue 12 https://doi.org/10.1021/ja00220a030	journal	June 1988
Water Oxidation with Mononuclear Ruthenium(II) Polypyridine Complexes Involving a Direct Ru ^IV ═O Pathway in Neutral and Alkaline Media Badiei, Yosra M.; Polyansky, Dmitry E.; Muckerman, James T. Inorganic Chemistry, Vol. 52, Issue 15 https://doi.org/10.1021/ic401023w	journal	July 2013
Metalloporphyrin-sensitized photooxidation of water to oxygen on the surface of colloidal iridium oxides: photochemical and pulse radiolytic studies Nahor, G. S.; Neta, P.; Hambright, P. The Journal of Physical Chemistry, Vol. 93, Issue 16 https://doi.org/10.1021/j100353a044	journal	August 1989
Cobalt Porphyrin Catalyzed Reduction of CO ₂ . Radiation Chemical, Photochemical, and Electrochemical Studies Behar, D.; Dhanasekaran, T.; Neta, P. The Journal of Physical Chemistry A, Vol. 102, Issue 17 https://doi.org/10.1021/jp9807017	journal	April 1998
Water Oxidation by a Mononuclear Ruthenium Catalyst: Characterization of the Intermediates Polyansky, Dmitry E.; Muckerman, James T.; Rochford, Jonathan Journal of the American Chemical Society, Vol. 133, Issue 37 https://doi.org/10.1021/ja203249e	journal	September 2011
Mechanism of the Formation of a Mn-Based CO ₂ Reduction Catalyst Revealed by Pulse Radiolysis with Time-Resolved Infrared Detection Grills, David C.; Farrington, Jaime A.; Layne, Bobby H. Journal of the American Chemical Society, Vol. 136, Issue 15 https://doi.org/10.1021/ja501051s	journal	April 2014
Zinc porphyrin π-radical cations in aqueous solution. Formation, spectra and decay kinetics Neta, Pedatsur; Harriman, Anthony J. Chem. Soc., Faraday Trans. 2, Vol. 81, Issue 1 https://doi.org/10.1039/F29858100123	journal	January 1985
Chemical Approaches to Artificial Photosynthesis. 2 Alstrum-Acevedo, James H.; Brennaman, M. Kyle; Meyer, Thomas J. Inorganic Chemistry, Vol. 44, Issue 20 https://doi.org/10.1021/ic050904r	journal	October 2005
Development of nanosecond time-resolved infrared detection at the LEAF pulse radiolysis facility Grills, David C.; Farrington, Jaime A.; Layne, Bobby H. Review of Scientific Instruments, Vol. 86, Issue 4 https://doi.org/10.1063/1.4918728	journal	April 2015
Changes in the redox state of iridium oxide clusters and their relation to catalytic water oxidation: radiolytic and electrochemical studies Nahor, G. S.; Hapiot, P.; Neta, P. The Journal of Physical Chemistry, Vol. 95, Issue 2 https://doi.org/10.1021/j100155a024	journal	January 1991
Differences of pH-Dependent Mechanisms on Generation of Hydride Donors using Ru(II) Complexes Containing Geometric Isomers of NAD ⁺ Model Ligands: NMR and Radiolysis Studies in Aqueous Solution Cohen, Brian W.; Polyansky, Dmitry E.; Zong, Ruifa Inorganic Chemistry, Vol. 49, Issue 17 https://doi.org/10.1021/ic101098v	journal	September 2010
Chemical Redox Agents for Organometallic Chemistry Connelly, Neil G.; Geiger, William E. Chemical Reviews, Vol. 96, Issue 2 https://doi.org/10.1021/cr940053x	journal	January 1996
Characterization of Redox States of Ru(OH ₂ )(Q)(tpy) ²⁺ (Q = 3,5-di- tert -butyl-1,2-benzoquinone, tpy = 2,2′:6′,2″-terpyridine) and Related Species through Experimental and Theoretical Studies Tsai, Ming-Kang; Rochford, Jonathan; Polyansky, Dmitry E. Inorganic Chemistry, Vol. 48, Issue 10 https://doi.org/10.1021/ic900057y	journal	May 2009
Nickel(II)-cyclam: an extremely selective electrocatalyst for reduction of CO2 in water Beley, Marc; Collin, Jean-Paul; Ruppert, Romain Journal of the Chemical Society, Chemical Communications, Issue 19 https://doi.org/10.1039/c39840001315	journal	January 1984
High Electrocatalytic Activity of RRSS-[NiIIHTIM](ClO4)2 and [NiIIDMC](ClO4)2 for Carbon Dioxide Reduction (HTIM = 2,3,9,10-Tetramethyl-1,4,8,11-tetraazacyclotetradecane, DMC = C-meso-5,12-Dimethyl-1,4,8,11-tetraazacyclotetradecane) Fujita, Etsuko; Haff, Janet; Sanzenbacher, Ralf Inorganic Chemistry, Vol. 33, Issue 21 https://doi.org/10.1021/ic00099a011	journal	October 1994

Cited By (7)

Mechanistic Insights into Light-Activated Catalysis for Water Oxidation: Mechanistic Insights into Light-Activated Catalysis for Water Oxidation Natali, Mirco; Nastasi, Francesco; Puntoriero, Fausto European Journal of Inorganic Chemistry, Vol. 2019, Issue 15 https://doi.org/10.1002/ejic.201801236	journal	January 2019
Radiolytic formation of the carbon dioxide radical anion in acetonitrile revealed by transient IR spectroscopy Grills, David C.; Lymar, Sergei V. Physical Chemistry Chemical Physics, Vol. 20, Issue 15 https://doi.org/10.1039/c8cp00977e	journal	January 2018
Mechanisms of catalytic reduction of CO 2 with heme and nonheme metal complexes Fukuzumi, Shunichi; Lee, Yong-Min; Ahn, Hyun S. Chemical Science, Vol. 9, Issue 28 https://doi.org/10.1039/c8sc02220h	journal	January 2018
Electrodeposition behavior of homoleptic transition metal acetonitrile complexes interrogated with piezoelectric gravimetry Sconyers, David J.; Blakemore, James D. The Analyst, Vol. 145, Issue 2 https://doi.org/10.1039/c9an01952a	journal	January 2020
Distinguishing deposition, corrosion, and stripping of transient heterogeneous materials during molecular electrocatalysis Sconyers, David J.; Blakemore, James D. Dalton Transactions, Vol. 48, Issue 19 https://doi.org/10.1039/c9dt00584f	journal	January 2019
Single-Electron Redox Chemistry on the [Cp*Rh] Platform Enabled by a Nitrated Bipyridyl Ligand Moore, William; Henke, Wade; Lionetti, Davide Molecules, Vol. 23, Issue 11 https://doi.org/10.3390/molecules23112857	journal	November 2018
Mechanistic Insights into Light‐Activated Catalysis for Water Oxidation Natali, Mirco; Nastasi, Francesco; Puntoriero, Fausto European Journal of Inorganic Chemistry, Vol. 2019, Issue 15 https://doi.org/10.1002/ejic.201900365	journal	April 2019

Similar Records

Hierarchical Inorganic Assemblies for Artificial Photosynthesis

Journal Article · Tue Aug 30 00:00:00 EDT 2016 · Accounts of Chemical Research · OSTI ID:1395945

Kim, Wooyul; Edri, Eran; Frei, Heinz

Structural and mechanistic studies of natural and artificial photosynthesis

Conference · Sat Jan 01 00:00:00 EST 1983 · OSTI ID:1395945

Norris, J R; Bowman, M K; Thurnauer, M C; +1 more

Artificial Photosynthesis with Next Generation Molecular Catalysts

Technical Report · Mon Sep 28 00:00:00 EDT 2020 · OSTI ID:1395945

Wiedner, Eric S.; Andersen, Amity; Ginovska, Bojana; +1 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
artificial photosynthesis
pulse radiolysis
mechanism
fuel generation

Title: Application of Pulse Radiolysis to Mechanistic Investigations of Catalysis Relevant to Artificial Photosynthesis

Citation Formats

References (71)

Cited By (7)

Similar Records

Related Subjects