Tunable White-Light Emission in Single-Cation-Templated Three-Layered 2D Perovskites (CH 3 CH 2 NH 3 ) 4 Pb 3 Br 10–x Cl x

Mao, Lingling; Wu, Yilei; Stoumpos, Constantinos C.; Traore, Boubacar; Katan, Claudine; Even, Jacky; Wasielewski, Michael R.; Kanatzidis, Mercouri G.

doi:10.1021/jacs.7b06143

Tunable White-Light Emission in Single-Cation-Templated Three-Layered 2D Perovskites (CH ₃ CH ₂ NH ₃ ) ₄ Pb ₃ Br _10–x Cl _x

Journal Article · Wed Aug 16 04:00:00 EDT 2017 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.7b06143· OSTI ID:1395374

; ; ; Traore, Boubacar ^[1]; ^[1]; ^[2]; ;

Institut des sciences chimiques de Rennes, CNRS, Université de Rennes 1, Ecole Nationale Supérieure de Chimie de Rennes, INSA de Rennes, 35042 Rennes, France
Fonctions Optiques pour les Technologies de l’Information (FOTON), INSA de Rennes, UMR 6082, CNRS, 35708 Rennes, France

Two-dimensional (2D) hybrid halide perovskites come as a family (B)₂(A)_n-1PbnX_3n+1 (B and A= cations; X= halide). These perovskites are promising semiconductors for solar cells and optoelectronic applications. Among the fascinating properties of these materials is white-light emission, which has been mostly observed in single-layered 2D lead bromide or chloride systems (n = 1), where the broad emission comes from the transient photoexcited states generated by self-trapped excitons (STEs) from structural distortion. Here we report a multilayered 2D perovskite (n = 3) exhibiting a tunable white-light emission. Ethylammonium (EA+) can stabilize the 2D perovskite structure in EA₄Pb₃Br_10–xCl_x (x = 0, 2, 4, 6, 8, 9.5, and 10) with EA⁺ being both the A and B cations in this system. Because of the larger size of EA, these materials show a high distortion level in their inorganic structures, with EA4Pb3Cl10 having a much larger distortion than that of EA₄Pb₃Br₁₀, which results in broadband white-light emission of EA₄Pb₃Cl₁₀ in contrast to narrow blue emission of EA4Pb3Br10. The average lifetime of the series decreases gradually from the Cl end to the Br end, indicating that the larger distortion also prolongs the lifetime (more STE states). The band gap of EA₄Pb₃Br_10–xCl_x ranges from 3.45 eV (x = 10) to 2.75 eV (x = 0), following Vegard’s law. First-principles density functional theory calculations (DFT) show that both EA₄Pb₃Cl₁₀ and EA₄Pb₃Br₁₀ are direct band gap semiconductors. The color rendering index (CRI) of the series improves from 66 (EA₄Pb₃Cl₁₀) to 83 (EA₄Pb₃Br_0.5Cl_9.5), displaying high tunability and versatility of the title compounds.

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

OSTI ID:: 1395374

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 34 Vol. 139; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: ENGLISH

References (65)

How to produce white light in a single-phase host? Shang, Mengmeng; Li, Chunxia; Lin, Jun Chem. Soc. Rev., Vol. 43, Issue 5 https://doi.org/10.1039/C3CS60314H	journal	January 2014
Efficient pseudopotentials for plane-wave calculations Troullier, N.; Martins, José Luriaas Physical Review B, Vol. 43, Issue 3 https://doi.org/10.1103/PhysRevB.43.1993	journal	January 1991
Morphology-Independent Stable White-Light Emission from Self-Assembled Two-Dimensional Perovskites Driven by Strong Exciton–Phonon Coupling to the Organic Framework Thirumal, Krishnamoorthy; Chong, Wee Kiang; Xie, Wei Chemistry of Materials, Vol. 29, Issue 9 https://doi.org/10.1021/acs.chemmater.7b00073	journal	April 2017
Searching for promising new perovskite-based photovoltaic absorbers: the importance of electronic dimensionality Xiao, Zewen; Meng, Weiwei; Wang, Jianbo Materials Horizons, Vol. 4, Issue 2 https://doi.org/10.1039/C6MH00519E	journal	January 2017
Structural origins of broadband emission from layered Pb–Br hybrid perovskites Smith, Matthew D.; Jaffe, Adam; Dohner, Emma R. Chemical Science, Vol. 8, Issue 6 https://doi.org/10.1039/C7SC01590A	journal	January 2017
Lead Iodide Perovskite Sensitized All-Solid-State Submicron Thin Film Mesoscopic Solar Cell with Efficiency Exceeding 9% Kim, Hui-Seon; Lee, Chang-Ryul; Im, Jeong-Hyeok Scientific Reports, Vol. 2, Issue 1 https://doi.org/10.1038/srep00591	journal	August 2012
White-Light Emission of Amine-Functionalized Organic/Inorganic Hybrids: Emitting Centers and Recombination Mechanisms Carlos, L. D.; Sá Ferreira, R. A.; Pereira, R. N. The Journal of Physical Chemistry B, Vol. 108, Issue 39 https://doi.org/10.1021/jp049052r	journal	September 2004
Inorganic–organic hybrid white light phosphors Wang, Ming-Sheng; Guo, Guo-Cong Chemical Communications, Vol. 52, Issue 90 https://doi.org/10.1039/C6CC03184F	journal	January 2016
The rapid evolution of highly efficient perovskite solar cells Correa-Baena, Juan-Pablo; Abate, Antonio; Saliba, Michael Energy & Environmental Science, Vol. 10, Issue 3 https://doi.org/10.1039/C6EE03397K	journal	January 2017
Quantum confinement and dielectric profiles of colloidal nanoplatelets of halide inorganic and hybrid organic–inorganic perovskites Sapori, Daniel; Kepenekian, Mikaël; Pedesseau, Laurent Nanoscale, Vol. 8, Issue 12 https://doi.org/10.1039/C5NR07175E	journal	January 2016
Towards an accurate description of perovskite ferroelectrics: exchange and correlation effects Yuk, Simuck F.; Pitike, Krishna Chaitanya; Nakhmanson, Serge M. Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/srep43482	journal	March 2017
Cation-Induced Band-Gap Tuning in Organohalide Perovskites: Interplay of Spin–Orbit Coupling and Octahedra Tilting Amat, Anna; Mosconi, Edoardo; Ronca, Enrico Nano Letters, Vol. 14, Issue 6 https://doi.org/10.1021/nl5012992	journal	May 2014
Advances and Promises of Layered Halide Hybrid Perovskite Semiconductors Pedesseau, Laurent; Sapori, Daniel; Traore, Boubacar ACS Nano, Vol. 10, Issue 11 https://doi.org/10.1021/acsnano.6b05944	journal	October 2016
6.5% efficient perovskite quantum-dot-sensitized solar cell Im, Jeong-Hyeok; Lee, Chang-Ryul; Lee, Jin-Wook Nanoscale, Vol. 3, Issue 10, p. 4088-4093 https://doi.org/10.1039/c1nr10867k	journal	January 2011
Tunable Light-Emitting Diodes Utilizing Quantum-Confined Layered Perovskite Emitters Congreve, Daniel N.; Weidman, Mark C.; Seitz, Michael ACS Photonics, Vol. 4, Issue 3 https://doi.org/10.1021/acsphotonics.6b00963	journal	February 2017
Ruddlesden–Popper Hybrid Lead Iodide Perovskite 2D Homologous Semiconductors Stoumpos, Constantinos C.; Cao, Duyen H.; Clark, Daniel J. Chemistry of Materials, Vol. 28, Issue 8, p. 2852-2867 https://doi.org/10.1021/acs.chemmater.6b00847	journal	April 2016
Structure–Band Gap Relationships in Hexagonal Polytypes and Low-Dimensional Structures of Hybrid Tin Iodide Perovskites Stoumpos, Constantinos C.; Mao, Lingling; Malliakas, Christos D. Inorganic Chemistry, Vol. 56, Issue 1 https://doi.org/10.1021/acs.inorgchem.6b02764	journal	December 2016
Interplay of spin–orbit coupling and lattice distortion in metal substituted 3D tri-chloride hybrid perovskites Katan, C.; Pedesseau, L.; Kepenekian, M. Journal of Materials Chemistry A, Vol. 3, Issue 17 https://doi.org/10.1039/C4TA06418F	journal	January 2015
Strong Electron–Phonon Coupling and Self-Trapped Excitons in the Defect Halide Perovskites A ₃ M ₂ I ₉ (A = Cs, Rb; M = Bi, Sb) McCall, Kyle M.; Stoumpos, Constantinos C.; Kostina, Svetlana S. Chemistry of Materials, Vol. 29, Issue 9 https://doi.org/10.1021/acs.chemmater.7b01184	journal	April 2017
Van der Waals density functional: An appropriate exchange functional Cooper, Valentino R. Physical Review B, Vol. 81, Issue 16 https://doi.org/10.1103/PhysRevB.81.161104	journal	April 2010
Synthesis, structure, and photovoltaic property of a nanocrystalline 2H perovskite-type novel sensitizer (CH3CH2NH3)PbI3 Im, Jeong-Hyeok; Chung, Jaehoon; Kim, Seung-Joo Nanoscale Research Letters, Vol. 7, Issue 1 https://doi.org/10.1186/1556-276X-7-353	journal	January 2012
White-Light Emission and Structural Distortion in New Corrugated Two-Dimensional Lead Bromide Perovskites Mao, Lingling; Wu, Yilei; Stoumpos, Constantinos C. Journal of the American Chemical Society, Vol. 139, Issue 14 https://doi.org/10.1021/jacs.7b01312	journal	March 2017
Solid-state principles applied to organic–inorganic perovskites: new tricks for an old dog Kieslich, Gregor; Sun, Shijing; Cheetham, Anthony K. Chem. Sci., Vol. 5, Issue 12 https://doi.org/10.1039/C4SC02211D	journal	January 2014
Bright White-Light Emission from Semiconductor Nanocrystals: by Chance and by Design Sapra, S.; Mayilo, S.; Klar, T. A. Advanced Materials, Vol. 19, Issue 4 https://doi.org/10.1002/adma.200602267	journal	February 2007
Decreasing the electronic confinement in layered perovskites through intercalation Smith, Matthew D.; Pedesseau, Laurent; Kepenekian, Mikaël Chemical Science, Vol. 8, Issue 3 https://doi.org/10.1039/C6SC02848A	journal	January 2017
The SIESTA method for ab initio order- N materials simulation Soler, José M.; Artacho, Emilio; Gale, Julian D. Journal of Physics: Condensed Matter, Vol. 14, Issue 11 https://doi.org/10.1088/0953-8984/14/11/302	journal	March 2002
Role of Organic Counterion in Lead- and Tin-Based Two-Dimensional Semiconducting Iodide Perovskites and Application in Planar Solar Cells Mao, Lingling; Tsai, Hsinhan; Nie, Wanyi Chemistry of Materials, Vol. 28, Issue 21 https://doi.org/10.1021/acs.chemmater.6b03054	journal	October 2016
Intrinsic White-Light Emission from Layered Hybrid Perovskites Dohner, Emma R.; Jaffe, Adam; Bradshaw, Liam R. Journal of the American Chemical Society, Vol. 136, Issue 38 https://doi.org/10.1021/ja507086b	journal	September 2014
Tunable Emission from Binary Organic One-Dimensional Nanomaterials: An Alternative Approach to White-Light Emission Zhao, Y. S.; Fu, H. B.; Hu, F. Q. Advanced Materials, Vol. 20, Issue 1 https://doi.org/10.1002/adma.200700542	journal	January 2008
Conducting Layered Organic-inorganic Halides Containing <110>-Oriented Perovskite Sheets Mitzi, D. B.; Wang, S.; Feild, C. A. Science, Vol. 267, Issue 5203, p. 1473-1476 https://doi.org/10.1126/science.267.5203.1473	journal	March 1995
Optical Investigation of Broadband White-Light Emission in Self-Assembled Organic–Inorganic Perovskite (C ₆ H ₁₁ NH ₃ ) ₂ PbBr ₄ Yangui, A.; Garrot, D.; Lauret, J. S. The Journal of Physical Chemistry C, Vol. 119, Issue 41 https://doi.org/10.1021/acs.jpcc.5b06211	journal	October 2015
Electronic surface states and dielectric self-energy profiles in colloidal nanoscale platelets of CdSe Even, Jacky; Pedesseau, Laurent; Kepenekian, Mikaël Phys. Chem. Chem. Phys., Vol. 16, Issue 45 https://doi.org/10.1039/C4CP03267E	journal	January 2014
Principles and Techniques of Diffuse-Reflectance Spectroscopy Kortüm, G.; Braun, W.; Herzog, G. Angewandte Chemie International Edition in English, Vol. 2, Issue 7 https://doi.org/10.1002/anie.196303331	journal	July 1963
Inhomogeneous Electron Gas Hohenberg, P.; Kohn, W. Physical Review, Vol. 136, Issue 3B, p. B864-B871 https://doi.org/10.1103/PhysRev.136.B864	journal	November 1964
Halide Perovskites: Poor Man's High-Performance Semiconductors Stoumpos, Constantinos C.; Kanatzidis, Mercouri G. Advanced Materials, Vol. 28, Issue 28 https://doi.org/10.1002/adma.201600265	journal	May 2016
High-efficiency two-dimensional Ruddlesden–Popper perovskite solar cells Tsai, Hsinhan; Nie, Wanyi; Blancon, Jean-Christophe Nature, Vol. 536, Issue 7616 https://doi.org/10.1038/nature18306	journal	July 2016
Self-Assembly of Broadband White-Light Emitters Dohner, Emma R.; Hoke, Eric T.; Karunadasa, Hemamala I. Journal of the American Chemical Society, Vol. 136, Issue 5 https://doi.org/10.1021/ja411045r	journal	January 2014
Crystal structure of tetrakis(ethylammonium) decachlorotriplumbate(II), (C2H5NH3)4Pb3Cl10 Geselle, M.; Fuess, H. Zeitschrift für Kristallographie - New Crystal Structures, Vol. 212, Issue 1 https://doi.org/10.1524/ncrs.1997.212.1.241	journal	December 1997
Organic–Inorganic Perovskites: Structural Versatility for Functional Materials Design Saparov, Bayrammurad; Mitzi, David B. Chemical Reviews, Vol. 116, Issue 7 https://doi.org/10.1021/acs.chemrev.5b00715	journal	March 2016
Perovskite energy funnels for efficient light-emitting diodes Yuan, Mingjian; Quan, Li Na; Comin, Riccardo Nature Nanotechnology, Vol. 11, Issue 10 https://doi.org/10.1038/nnano.2016.110	journal	June 2016
White-Light Emission from Magic-Sized Cadmium Selenide Nanocrystals Bowers, Michael J.; McBride, James R.; Rosenthal, Sandra J. Journal of the American Chemical Society, Vol. 127, Issue 44 https://doi.org/10.1021/ja055470d	journal	November 2005
Layered organic–inorganic hybrid perovskites: structure, optical properties, film preparation, patterning and templating engineering Cheng, Ziyong; Lin, Jun CrystEngComm, Vol. 12, Issue 10 https://doi.org/10.1039/c001929a	journal	January 2010
Novel 〈110〉-Oriented Organic−Inorganic Perovskite Compound Stabilized by N -(3-Aminopropyl)imidazole with Improved Optical Properties Li, Y. Y.; Lin, C. K.; Zheng, G. L. Chemistry of Materials, Vol. 18, Issue 15 https://doi.org/10.1021/cm060714u	journal	July 2006
The Renaissance of Halide Perovskites and Their Evolution as Emerging Semiconductors Stoumpos, Constantinos C.; Kanatzidis, Mercouri G. Accounts of Chemical Research, Vol. 48, Issue 10 https://doi.org/10.1021/acs.accounts.5b00229	journal	September 2015
Two Dimensional Organometal Halide Perovskite Nanorods with Tunable Optical Properties Aharon, Sigalit; Etgar, Lioz Nano Letters, Vol. 16, Issue 5 https://doi.org/10.1021/acs.nanolett.6b00665	journal	April 2016
Evolution of the Jahn−Teller Distortion of MnO ₆ Octahedra in RMnO ₃ Perovskites (R = Pr, Nd, Dy, Tb, Ho, Er, Y): A Neutron Diffraction Study Alonso, J. A.; Martínez-Lope, M. J.; Casais, M. T. Inorganic Chemistry, Vol. 39, Issue 5 https://doi.org/10.1021/ic990921e	journal	March 2000
High Members of the 2D Ruddlesden-Popper Halide Perovskites: Synthesis, Optical Properties, and Solar Cells of (CH 3 (CH 2 ) 3 NH 3 ) 2 (CH 3 NH 3 ) 4 Pb 5 I 16 Stoumpos, Constantinos C.; Soe, Chan Myae Myae; Tsai, Hsinhan Chem, Vol. 2, Issue 3 https://doi.org/10.1016/j.chempr.2017.02.004	journal	March 2017
Mechanism for Broadband White-Light Emission from Two-Dimensional (110) Hybrid Perovskites Hu, Te; Smith, Matthew D.; Dohner, Emma R. The Journal of Physical Chemistry Letters, Vol. 7, Issue 12 https://doi.org/10.1021/acs.jpclett.6b00793	journal	May 2016
Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells Kojima, Akihiro; Teshima, Kenjiro; Shirai, Yasuo Journal of the American Chemical Society, Vol. 131, Issue 17, p. 6050-6051 https://doi.org/10.1021/ja809598r	journal	May 2009
Conducting tin halides with a layered organic-based perovskite structure Mitzi, D. B.; Feild, C. A.; Harrison, W. T. A. Nature, Vol. 369, Issue 6480, p. 467-469 https://doi.org/10.1038/369467a0	journal	June 1994
Towards stable and commercially available perovskite solar cells Park, Nam-Gyu; Grätzel, Michael; Miyasaka, Tsutomu Nature Energy, Vol. 1, Issue 11 https://doi.org/10.1038/nenergy.2016.152	journal	October 2016
Self-Consistent Equations Including Exchange and Correlation Effects Kohn, W.; Sham, L. J. Physical Review, Vol. 140, Issue 4A, p. A1133-A1138 https://doi.org/10.1103/PhysRev.140.A1133	journal	November 1965
General Synthesis and White Light Emission of Diluted Magnetic Semiconductor Nanowires Using Single-Source Precursors Yang, Gaoling; Xu, Guangyuan; Chen, Bingkun Chemistry of Materials, Vol. 25, Issue 15 https://doi.org/10.1021/cm401864d	journal	July 2013
Metal-halide perovskites for photovoltaic and light-emitting devices Stranks, Samuel D.; Snaith, Henry J. Nature Nanotechnology, Vol. 10, Issue 5 https://doi.org/10.1038/nnano.2015.90	journal	May 2015
A Layered Hybrid Perovskite Solar-Cell Absorber with Enhanced Moisture Stability Smith, Ian C.; Hoke, Eric T.; Solis-Ibarra, Diego Angewandte Chemie, Vol. 126, Issue 42 https://doi.org/10.1002/ange.201406466	journal	September 2014
Comment on “Generalized Gradient Approximation Made Simple” Zhang, Yingkai; Yang, Weitao Physical Review Letters, Vol. 80, Issue 4 https://doi.org/10.1103/PhysRevLett.80.890	journal	January 1998
Jahn–Teller distortions, cation ordering and octahedral tilting in perovskites Lufaso, Michael W.; Woodward, Patrick M. Acta Crystallographica Section B Structural Science, Vol. 60, Issue 1 https://doi.org/10.1107/S0108768103026661	journal	January 2004
Organic-Inorganic Hybrid Materials as Semiconducting Channels in Thin-Film Field-Effect Transistors Kagan, C. R.; Mitzi, D. B.; Dimitrakopoulos, C. D. Science, Vol. 286, Issue 5441, p. 945-947 https://doi.org/10.1126/science.286.5441.945	journal	October 1999
Steric engineering of metal-halide perovskites with tunable optical band gaps Filip, Marina R.; Eperon, Giles E.; Snaith, Henry J. Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms6757	journal	December 2014
Role of Polar Phonons in the Photo Excited State of Metal Halide Perovskites Bokdam, Menno; Sander, Tobias; Stroppa, Alessandro Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep28618	journal	June 2016
2D Homologous Perovskites as Light-Absorbing Materials for Solar Cell Applications Cao, Duyen H.; Stoumpos, Constantinos C.; Farha, Omar K. Journal of the American Chemical Society, Vol. 137, Issue 24 https://doi.org/10.1021/jacs.5b03796	journal	June 2015
Electronic model for self-assembled hybrid organic/perovskite semiconductors: Reverse band edge electronic states ordering and spin-orbit coupling Even, J.; Pedesseau, L.; Dupertuis, M. -A. Physical Review B, Vol. 86, Issue 20 https://doi.org/10.1103/PhysRevB.86.205301	journal	November 2012
Tuning the Band Gap in Hybrid Tin Iodide Perovskite Semiconductors Using Structural Templating Knutson, Jeremy L.; Martin, James D.; Mitzi, David B. Inorganic Chemistry, Vol. 44, Issue 13 https://doi.org/10.1021/ic050244q	journal	June 2005
Structure-Tuned Lead Halide Perovskite Nanocrystals Hassan, Yasser; Song, Yin; Pensack, Ryan D. Advanced Materials, Vol. 28, Issue 3 https://doi.org/10.1002/adma.201503461	journal	November 2015
Halide Effects in Transition Metal Catalysis Fagnou, Keith; Lautens, Mark Angewandte Chemie International Edition, Vol. 41, Issue 1 https://doi.org/10.1002/1521-3773(20020104)41:1<26::AID-ANIE26>3.0.CO;2-9	journal	January 2002

Cited By (58)

Rational chemical doping of metal halide perovskites Zhang, Xinyuan; Li, Lina; Sun, Zhihua Chemical Society Reviews, Vol. 48, Issue 2 https://doi.org/10.1039/c8cs00563j	journal	January 2019
Efficient ambient-air-stable HTM-free carbon-based perovskite solar cells with hybrid 2D–3D lead halide photoabsorbers Zhou, Junshuai; Ye, Zhili; Hou, Jie Journal of Materials Chemistry A, Vol. 6, Issue 45 https://doi.org/10.1039/c8ta07836j	journal	January 2018
Microstructure and elastic constants of AlTiVMoNb refractory high-entropy alloy coating on Ti6Al4V by laser cladding Chen, Lin; Zhang, Xiaowei; Wang, Yueyi Materials Research Express, Vol. 6, Issue 11 https://doi.org/10.1088/2053-1591/ab49e7	journal	September 2019
Negative Thermal Quenching of Efficient White‐Light Emission in a 1D Ladder‐Like Organic/Inorganic Hybrid Material Barkaoui, Hamdi; Abid, Haitham; Zelewski, Szymon Advanced Optical Materials, Vol. 7, Issue 20 https://doi.org/10.1002/adom.201900763	journal	July 2019
(C ₃ H ₉ NI) ₄ AgBiI ₈ : a direct-bandgap layered double perovskite based on a short-chain spacer cation for light absorption Yao, Yunpeng; Kou, Bo; Peng, Yu Chemical Communications, Vol. 56, Issue 21 https://doi.org/10.1039/c9cc07796k	journal	January 2020
Structure-controlled optical thermoresponse in Ruddlesden-Popper layered perovskites Cortecchia, D.; Neutzner, S.; Yin, J. APL Materials, Vol. 6, Issue 11 https://doi.org/10.1063/1.5045782	journal	November 2018
Extra thermo- and water-stable one-dimensional organic–inorganic hybrid perovskite [ N -methyldabconium]PbI ₃ showing switchable dielectric behaviour, conductivity and bright yellow-green emission Xue, Chen; Yao, Zhi-Yuan; Zhang, Jin Chemical Communications, Vol. 54, Issue 34 https://doi.org/10.1039/c8cc00786a	journal	January 2018
Compositional and Solvent Engineering in Dion-Jacobson 2D Perovskites Boosts Solar Cell Efficiency and Stability Ke, Weijun; Mao, Lingling; Stoumpos, Constantinos C. Advanced Energy Materials, Vol. 9, Issue 10 https://doi.org/10.1002/aenm.201803384	journal	January 2019
White perovskite based lighting devices Bidikoudi, M.; Fresta, E.; Costa, R. D. Chemical Communications, Vol. 54, Issue 59 https://doi.org/10.1039/c8cc03166e	journal	January 2018
Recent Progress in Metal Halide Perovskite Micro‐ and Nanolasers Wei, Qi; Li, Xiaojun; Liang, Chao Advanced Optical Materials, Vol. 7, Issue 17 https://doi.org/10.1002/adom.201900080	journal	April 2019
Prediction of Novel p -Type Transparent Conductors in Layered Double Perovskites: A First-Principles Study Xu, Jian; Liu, Jian-Bo; Wang, Jianfeng Advanced Functional Materials, Vol. 28, Issue 26 https://doi.org/10.1002/adfm.201800332	journal	April 2018
Merits and Challenges of Ruddlesden-Popper Soft Halide Perovskites in Electro-Optics and Optoelectronics Chen, Zhizhong; Guo, Yuwei; Wertz, Esther Advanced Materials, Vol. 31, Issue 1 https://doi.org/10.1002/adma.201803514	journal	October 2018
Fluorination of Organic Spacer Impacts on the Structural and Optical Response of 2D Perovskites García-Benito, Inés; Quarti, Claudio; Queloz, Valentin I. E. Frontiers in Chemistry, Vol. 7 https://doi.org/10.3389/fchem.2019.00946	journal	January 2020
Dual phosphorescence from the organic and inorganic moieties of 1D hybrid perovskites of the Pb _n′ Br _4n′+2 series ( n ′ = 2, 3, 4, 5) Ben Haj Salah, Maroua; Mercier, Nicolas; Allain, Magali Journal of Materials Chemistry C, Vol. 7, Issue 15 https://doi.org/10.1039/c9tc00340a	journal	January 2019
Molecular engineering of organic–inorganic hybrid perovskites quantum wells Gao, Yao; Shi, Enzheng; Deng, Shibin Nature Chemistry, Vol. 11, Issue 12 https://doi.org/10.1038/s41557-019-0354-2	journal	November 2019
Recent Advances toward High-Efficiency Halide Perovskite Light-Emitting Diodes: Review and Perspective Van Le, Quyet; Jang, Ho Won; Kim, Soo Young Small Methods, Vol. 2, Issue 10 https://doi.org/10.1002/smtd.201700419	journal	July 2018
Surface Termination, Morphology, and Bright Photoluminescence of Cesium Lead Halide Perovskite Nanocrystals ten Brinck, Stephanie; Infante, Ivan ACS Energy Letters, Vol. 1, Issue 6 https://doi.org/10.1021/acsenergylett.6b00595	journal	November 2016
Exploring Organic Metal Halides with Reversible Temperature‐Responsive Dual‐Emissive Photoluminescence Jiang, Xiaomei; Xia, Shengqing; Zhang, Jian ChemSusChem, Vol. 12, Issue 24 https://doi.org/10.1002/cssc.201902481	journal	October 2019
Highly efficient white-light emission in a polar two-dimensional hybrid perovskite Wang, Sasa; Yao, Yunpeng; Kong, Jintao Chemical Communications, Vol. 54, Issue 32 https://doi.org/10.1039/c8cc01663a	journal	January 2018
Broadband white light emission from one-dimensional zigzag edge-sharing perovskite Jung, Mi-Hee New Journal of Chemistry, Vol. 44, Issue 1 https://doi.org/10.1039/c9nj04758a	journal	January 2020
A 3D Iodoplumbate Semiconducting Open Framework with Visible‐light‐induced Photocatalytic Performance Ge, Bang‐Di; Wei, Qi; Sun, Ai‐Huan Chemistry – An Asian Journal, Vol. 14, Issue 12 https://doi.org/10.1002/asia.201900392	journal	May 2019
Tracking the dimensional conversion process of semiconducting lead bromide perovskites by mass spectroscopy, powder X-ray diffraction, microcalorimetry and crystallography Hu, Yue-Qiao; Hui, Hong-Yan; Wen, Hong-Qiang Dalton Transactions, Vol. 48, Issue 34 https://doi.org/10.1039/c9dt02068c	journal	January 2019
Realization of “warm” white light via halide substitution in polar two-dimensional hybrid perovskites (2meptH ₂ )PbCl _x Br _4−x Wang, Sasa; Yao, Yunpeng; Wu, Zhenyue Journal of Materials Chemistry C, Vol. 6, Issue 45 https://doi.org/10.1039/c8tc03167c	journal	January 2018
Luminescent perovskites: recent advances in theory and experiments Song, Zhen; Zhao, Jing; Liu, Quanlin Inorganic Chemistry Frontiers, Vol. 6, Issue 11 https://doi.org/10.1039/c9qi00777f	journal	January 2019
Broadband white-light emission with a high color rendering index in a two-dimensional organic–inorganic hybrid perovskite Wu, Zhenyue; Ji, Chengmin; Sun, Zhihua Journal of Materials Chemistry C, Vol. 6, Issue 5 https://doi.org/10.1039/c7tc04868h	journal	January 2018
Highly Emissive Self-Trapped Excitons in Fully Inorganic Zero-Dimensional Tin Halides Benin, Bogdan M.; Dirin, Dmitry N.; Morad, Viktoriia Angewandte Chemie, Vol. 130, Issue 35 https://doi.org/10.1002/ange.201806452	journal	July 2018
Influence of π -conjugated cations and halogen substitution on the optoelectronic and excitonic properties of layered hybrid perovskites Leveillee, Joshua; Katan, Claudine; Zhou, Liujiang Physical Review Materials, Vol. 2, Issue 10 https://doi.org/10.1103/physrevmaterials.2.105406	journal	October 2018
Molecular engineering of two-dimensional hybrid perovskites with broadband emission for white light-emitting diodes Hu, Hongwei; Morris, Samuel A.; Qiao, Xianfeng Journal of Materials Chemistry C, Vol. 6, Issue 38 https://doi.org/10.1039/c8tc03001d	journal	January 2018
Piperidine-induced Switching of the direct band gaps of Ag( i )/Bi( iii ) bimetallic iodide double perovskites Lassoued, Mohamed Saber; Bi, Le-Yu; Wu, Zhaoxin Journal of Materials Chemistry C https://doi.org/10.1039/d0tc01017k	journal	January 2020
White light emission in low-dimensional perovskites Cortecchia, Daniele; Yin, Jun; Petrozza, Annamaria Journal of Materials Chemistry C, Vol. 7, Issue 17 https://doi.org/10.1039/c9tc01036j	journal	January 2019
Perovskites for Light Emission Quan, Li Na; García de Arquer, F. Pelayo; Sabatini, Randy P. Advanced Materials, Vol. 30, Issue 45 https://doi.org/10.1002/adma.201801996	journal	August 2018
Structural and thermodynamic limits of layer thickness in 2D halide perovskites Soe, Chan Myae Myae; Nagabhushana, G. P.; Shivaramaiah, Radha Proceedings of the National Academy of Sciences, Vol. 116, Issue 1 https://doi.org/10.1073/pnas.1811006115	journal	December 2018
Highly Emissive Self-Trapped Excitons in Fully Inorganic Zero-Dimensional Tin Halides Benin, Bogdan M.; Dirin, Dmitry N.; Morad, Viktoriia Angewandte Chemie International Edition, Vol. 57, Issue 35 https://doi.org/10.1002/anie.201806452	journal	July 2018
Two-dimensional halide perovskite nanomaterials and heterostructures Shi, Enzheng; Gao, Yao; Finkenauer, Blake P. Chemical Society Reviews, Vol. 47, Issue 16 https://doi.org/10.1039/c7cs00886d	journal	January 2018
Organic intercalation engineering of quasi-2D Dion–Jacobson α-CsPbI ₃ perovskites Fang, Zhi; Shang, Minghui; Zheng, Yapeng Materials Horizons, Vol. 7, Issue 4 https://doi.org/10.1039/c9mh01788g	journal	January 2020
Melting temperature suppression of layered hybrid lead halide perovskites via organic ammonium cation branching Li, Tianyang; Dunlap-Shohl, Wiley A.; Reinheimer, Eric W. Chemical Science, Vol. 10, Issue 4 https://doi.org/10.1039/c8sc03863e	journal	January 2019
Organic cation directed hybrid lead halides of zero-dimensional to two-dimensional structures with tunable photoluminescence properties Yue, Cheng-Yang; Sun, Hai-Xiao; Liu, Quan-Xiu Inorganic Chemistry Frontiers, Vol. 6, Issue 10 https://doi.org/10.1039/c9qi00684b	journal	January 2019
Intrinsic Self‐Trapped Emission in 0D Lead‐Free (C ₄ H ₁₄ N ₂ ) ₂ In ₂ Br ₁₀ Single Crystal Zhou, Lei; Liao, Jin‐Feng; Huang, Zeng‐Guang Angewandte Chemie International Edition, Vol. 58, Issue 43 https://doi.org/10.1002/anie.201907503	journal	October 2019
Syntheses of two-dimensional propylammonium lead halide perovskite microstructures by a solution route Ma, Dewei; Xu, Zhousu; Wang, Fangjie CrystEngComm, Vol. 21, Issue 9 https://doi.org/10.1039/c8ce02005a	journal	January 2019
Two‐Step Structure Phase Transition, Dielectric Anomalies, and Thermochromic Luminescence Behavior in a Direct Band Gap 2D Corrugated Layer Lead Chloride Hybrid of [(CH ₃ ) ₄ N ] ₄ Pb ₃ Cl ₁₀ Xue, Chen; Wang, Shu; Liu, Wen‐Long Chemistry – A European Journal, Vol. 25, Issue 20 https://doi.org/10.1002/chem.201806032	journal	March 2019
Single‐Component White‐Light Emission in 2D Hybrid Perovskites with Hybridized Halogen Atoms Zhou, Guojun; Li, Mingze; Zhao, Jing Advanced Optical Materials, Vol. 7, Issue 24 https://doi.org/10.1002/adom.201901335	journal	September 2019
Unraveling the mechanochemical synthesis and luminescence in MnII-based two-dimensional hybrid perovskite (C4H9NH3)2PbCl4 Zhou, Guojun; Guo, Shaoqiang; Zhao, Jing Science China Materials, Vol. 62, Issue 7 https://doi.org/10.1007/s40843-018-9404-4	journal	March 2019
Polarization‐Dependent Photoluminescence of a Highly (100)‐Oriented Perovskite Film Yun, Sangeun; Kim, Taehee; Choi, Yung Ji ChemPhysChem, Vol. 21, Issue 3 https://doi.org/10.1002/cphc.201901085	journal	January 2020
A 3D Haloplumbate Framework Constructed From Unprecedented Lindqvist-like Highly Coordinated [Pb ₆ Br ₂₅ ] ¹³⁻ Nanoclusters with Temperature-Dependent Emission Li, Xinxiong; Do, T. Thu Ha; Granados del Águila, A. Chemistry - An Asian Journal, Vol. 13, Issue 21 https://doi.org/10.1002/asia.201801292	journal	October 2018
Organic cation directed one-dimensional cuprous halide compounds: syntheses, crystal structures and photoluminescence properties Yue, Cheng-Yang; Lin, Na; Gao, Lu Dalton Transactions, Vol. 48, Issue 27 https://doi.org/10.1039/c9dt01460h	journal	January 2019
Edge stabilization in reduced-dimensional perovskites Na Quan, Li; Ma, Dongxin; Zhao, Yongbiao Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-019-13944-2	journal	January 2020
Solution Route to Single-Crystalline Ethylammonium Lead Halide Microstructures Ma, Dewei; Dai, Ning; Lan, Yuguo ChemistrySelect, Vol. 4, Issue 7 https://doi.org/10.1002/slct.201804046	journal	February 2019
Copper Iodide Based Hybrid Phosphors for Energy-Efficient General Lighting Technologies Liu, Wei; Fang, Yang; Li, Jing Advanced Functional Materials, Vol. 28, Issue 8 https://doi.org/10.1002/adfm.201705593	journal	January 2018
An ultrastable metal–organic material emits efficient and broadband bluish white-light emission for luminescent thermometers Yin, Jinlin; Zhang, Guiyang; Peng, Chengdong Chemical Communications, Vol. 55, Issue 12 https://doi.org/10.1039/c8cc08726a	journal	January 2019
Two low-dimensional metal halides: ionothermal synthesis, photoluminescence, and nonlinear optical properties Deng, Yuandan; Dong, Xuehua; Yang, Meng Dalton Transactions, Vol. 48, Issue 47 https://doi.org/10.1039/c9dt04102h	journal	January 2019
Broadband white-light emission from supramolecular piperazinium-based lead halide perovskites linked by hydrogen bonds Jung, Mi-Hee; Ko, Kyoung Chul; Lee, Woo Ram Dalton Transactions, Vol. 48, Issue 40 https://doi.org/10.1039/c9dt03469b	journal	January 2019
Perovskite-Based Nanocrystals: Synthesis and Applications beyond Solar Cells Wang, Ning; Liu, Wenbo; Zhang, Qichun Small Methods, Vol. 2, Issue 6 https://doi.org/10.1002/smtd.201700380	journal	April 2018
Pressure‐Induced Emission (PIE) and Phase Transition of a Two‐dimensional Halide Double Perovskite (BA) ₄ AgBiBr ₈ (BA=CH ₃ (CH ₂ ) ₃ NH ₃ ⁺ ) Fang, Yuanyuan; Zhang, Long; Wu, Lianwei Angewandte Chemie International Edition, Vol. 58, Issue 43 https://doi.org/10.1002/anie.201906311	journal	October 2019
Pressure‐Induced Emission (PIE) and Phase Transition of a Two‐dimensional Halide Double Perovskite (BA) ₄ AgBiBr ₈ (BA=CH ₃ (CH ₂ ) ₃ NH ₃ ⁺ ) Fang, Yuanyuan; Zhang, Long; Wu, Lianwei Angewandte Chemie, Vol. 131, Issue 43 https://doi.org/10.1002/ange.201906311	journal	October 2019
High perovskite-to-manganese energy transfer efficiency in single-component white-emitting Mn-doped halide perovskite quantum dots Qin, Heming; Wang, Chunlei; Xu, Jingkun Journal of Materials Science, Vol. 55, Issue 7 https://doi.org/10.1007/s10853-019-04185-1	journal	November 2019
Intrinsic Self‐Trapped Emission in 0D Lead‐Free (C ₄ H ₁₄ N ₂ ) ₂ In ₂ Br ₁₀ Single Crystal Zhou, Lei; Liao, Jin‐Feng; Huang, Zeng‐Guang Angewandte Chemie, Vol. 131, Issue 43 https://doi.org/10.1002/ange.201907503	journal	September 2019
Chirality control in white-light emitting 2D perovskites Trujillo-Hernández, Karla; Rodríguez-López, Germán; Espinosa-Roa, Arian Journal of Materials Chemistry C, Vol. 8, Issue 28 https://doi.org/10.1039/d0tc02118k	journal	January 2020
Self‐Trapped Exciton to Dopant Energy Transfer in Rare Earth Doped Lead‐Free Double Perovskite Li, Shunran; Hu, Qingsong; Luo, Jiajun Advanced Optical Materials, Vol. 7, Issue 23 https://doi.org/10.1002/adom.201901098	journal	September 2019

Similar Records

Tunable White-Light Emission in Single-Cation-Templated Three-Layered 2D Perovskites (CH₃CH₂NH₃)₄Pb₃Br_10–xCl_x

Journal Article · Tue Jul 25 20:00:00 EDT 2017 · Journal of the American Chemical Society · OSTI ID:1599737

Small Cyclic Diammonium Cation Templated (110)-Oriented 2D Halide (X = I, Br, Cl) Perovskites with White-Light Emission

Journal Article · Sun Apr 21 20:00:00 EDT 2019 · Chemistry of Materials · OSTI ID:1558606

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

CCDC 1573847: Experimental Crystal Structure Determination Mao, Lingling; Wu, Yilei; Stoumpos, Constantinos C. https://doi.org/10.5517/ccdc.csd.cc1ptq8h The current record is supplemented by this dataset	dataset	January 2017
CCDC 1573846: Experimental Crystal Structure Determination Mao, Lingling; Wu, Yilei; Stoumpos, Constantinos C. https://doi.org/10.5517/ccdc.csd.cc1ptq7g The current record is supplemented by this dataset	dataset	January 2017