In-line monitoring of Li-ion battery electrode porosity and areal loading using active thermal scanning - modeling and initial experiment
- National Renewable Energy Lab. (NREL), Golden, CO (United States)
- Oak Ridge National Lab., Knoxville, TN (United States)
This work focuses on a new technique called active thermal scanning for in-line monitoring of porosity and areal loading of Li-ion battery electrodes. In this technique a moving battery electrode is subjected to thermal excitation and the induced temperature rise is monitored using an infra-red camera. Static and dynamic experiments with speeds up to 1.5 m min-1 are performed on both cathodes and anodes and a combined micro- and macro-scale finite element thermal model of the system is developed. It is shown experimentally and through simulations that during thermal scanning the temperature profile generated in an electrode depends on both coating porosity (or area loading) and thickness. Here, it is concluded that by inverting this relation the porosity (or areal loading) can be determined, if thermal response and thickness are simultaneously measured.
- Research Organization:
- National Renewable Energy Laboratory (NREL), Golden, CO (United States); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Organization:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE Office of Energy Efficiency and Renewable Energy (EERE)
- Grant/Contract Number:
- AC36-08GO28308; AC05-00OR22725
- OSTI ID:
- 1395099
- Alternate ID(s):
- OSTI ID: 1414705; OSTI ID: 1495801
- Report Number(s):
- NREL/JA-5900-67996
- Journal Information:
- Journal of Power Sources, Vol. 375; ISSN 0378-7753
- Publisher:
- ElsevierCopyright Statement
- Country of Publication:
- United States
- Language:
- English
Web of Science
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