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Title: In-line monitoring of Li-ion battery electrode porosity and areal loading using active thermal scanning - modeling and initial experiment

Journal Article · · Journal of Power Sources

This work focuses on a new technique called active thermal scanning for in-line monitoring of porosity and areal loading of Li-ion battery electrodes. In this technique a moving battery electrode is subjected to thermal excitation and the induced temperature rise is monitored using an infra-red camera. Static and dynamic experiments with speeds up to 1.5 m min-1 are performed on both cathodes and anodes and a combined micro- and macro-scale finite element thermal model of the system is developed. It is shown experimentally and through simulations that during thermal scanning the temperature profile generated in an electrode depends on both coating porosity (or area loading) and thickness. Here, it is concluded that by inverting this relation the porosity (or areal loading) can be determined, if thermal response and thickness are simultaneously measured.

Research Organization:
National Renewable Energy Laboratory (NREL), Golden, CO (United States); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE Office of Energy Efficiency and Renewable Energy (EERE)
Grant/Contract Number:
AC36-08GO28308; AC05-00OR22725
OSTI ID:
1395099
Alternate ID(s):
OSTI ID: 1414705; OSTI ID: 1495801
Report Number(s):
NREL/JA-5900-67996
Journal Information:
Journal of Power Sources, Vol. 375; ISSN 0378-7753
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 3 works
Citation information provided by
Web of Science

References (9)

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Materials processing for lithium-ion batteries journal March 2011
Effect of Calendering on Electrode Wettability in Lithium-Ion Batteries journal December 2014
Local Tortuosity Inhomogeneities in a Lithium Battery Composite Electrode journal January 2011
Lithium-ion battery electrode inspection using pulse thermography journal June 2014
A method to quantify coating thickness and porosity of electrodes for lithium-ion-batteries journal July 2016
Evaluation Residual Moisture in Lithium-Ion Battery Electrodes and Its Effect on Electrode Performance journal January 2016
A Model for the Thermal Response of Polymer Composite Materials with Experimental Verification journal November 1985
Analysis of Electrochemical and Thermal Behavior of Li-Ion Cells journal January 2003