Produktion von Methanol und Ethanol aus Methan in einem einzigen Reaktor mit einem Nickeloxid auf Ceroxid‐Zirconiumoxid‐Katalysator

Okolie, Chukwuemeka; Belhseine, Yasmeen F.; Lyu, Yimeng; Yung, Matthew M.; Engelhard, Mark H.; Kovarik, Libor; Stavitski, Eli; Sievers, Carsten

doi:10.1002/ange.201704704

Title: Produktion von Methanol und Ethanol aus Methan in einem einzigen Reaktor mit einem Nickeloxid auf Ceroxid‐Zirconiumoxid‐Katalysator

Journal Article · Tue Sep 26 00:00:00 EDT 2017 · Angewandte Chemie

DOI:https://doi.org/10.1002/ange.201704704· OSTI ID:1394848

Okolie, Chukwuemeka ^[1]; Belhseine, Yasmeen F. ^[1]; Lyu, Yimeng ^[1]; Yung, Matthew M. ^[2]; Engelhard, Mark H. ^[3]; Kovarik, Libor ^[3]; Stavitski, Eli ^[4];

^[1]

School of Chemical &, Biomolecular Engineering Georgia Institute of Technology 311 Ferst Drive NW Atlanta GA 30332 USA
National Renewable Energy Laboratory Golden CO USA
Environmental Molecular Sciences Laboratory Pacific Northwest National Lab Richland WA USA
National Synchrotron Light Source II Brookhaven National Laboratory Upton NY USA

Abstract Die Umwandlung von Methan in Alkohole unter milden Reaktionsbedingungen ist eine vielversprechende Technologie für die Nutzung abgelegener Methanvorkommen. Die flüssigen Alkohole können in Pipelines transportiert und zu wertvolleren Chemikalien weiterverarbeitet werden. Hier wird gezeigt, dass ein Katalysator aus Nickeloxidpartikeln auf einen Ceroxid‐Zirconiumoxid‐Träger (NiO/CZ) Methan in einem einzigen, kontinuierlich betriebenen Reaktor zu Methanol und Ethanol umwandeln kann. Die Reaktion geschieht bei milden Temperaturen (723 K) mit O ₂ als Oxidationsmittel. Die Produktion von Alkoholen erfordert die Gegenwart von Wasserdampf, um die vollständige Oxidation zu CO ₂ zu unterdrücken. Die Synergie zwischen Lewis‐aciden NiO‐Partikeln und dem redoxaktiven Ceroxid‐Zirconiumoxid‐Träger ermöglicht die ungewöhnliche Reaktivität dieses Katalysators.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1394848

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Vol. 129 Journal Issue: 44; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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