In Situ Doping Strategy for the Preparation of Conjugated Triazine Frameworks Displaying Efficient CO2 Capture Performance

Zhu, Xiang; Tian, Chengcheng; Veith, Gabriel M.; Abney, Carter W.; Dehaudt, Jérémy; Dai, Sheng

doi:10.1021/jacs.6b07644

In Situ Doping Strategy for the Preparation of Conjugated Triazine Frameworks Displaying Efficient CO₂ Capture Performance

Journal Article · Thu Sep 01 00:00:00 EDT 2016 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.6b07644· OSTI ID:1394558

Zhu, Xiang ^[1]; Tian, Chengcheng ^[1]; ^[2]; ^[2]; Dehaudt, Jérémy ^[1]; ^[3]

Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

An in situ doping strategy has been developed for the generation of a novel family of hexaazatriphenylene-based conjugated triazine frameworks (CTFs) for efficient CO₂ capture. The resulting task-specific materials exhibit an exceptionally high CO₂ uptake capacity (up to 4.8 mmol g^–1 at 297 K and 1 bar). The synergistic effects of ultrananoporosity and rich N/O codoped CO₂-philic sites bestow the framework with the highest CO₂ adsorption capacity among known porous organic polymers (POPs). This innovative approach not only enables superior CO₂ separation performance but also provides tunable control of surface features on POPs, thereby affording control over bulk material properties. In conclusion, we anticipate this novel strategy will facilitate new possibilities for the rational design and synthesis of nanoporous materials for carbon capture.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1394558

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 36 Vol. 138; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Achieving an exceptionally high loading of isolated cobalt single atoms on a porous carbon matrix for efficient visible-light-driven photocatalytic hydrogen production Shi, Rui; Tian, Chengcheng; Zhu, Xiang Chemical Science, Vol. 10, Issue 9 https://doi.org/10.1039/c8sc05540h	journal	January 2019
Mechanochemical synthesis of pillar[5]quinone derived multi-microporous organic polymers for radioactive organic iodide capture and storage. Jie, Kecheng; Zhou, Yujuan; Sun, Qi Springer Science and Business Media LLC https://doi.org/10.17863/cam.51415	journalarticle	January 2020

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
adsorption
carbon capture and storage
materials
selectivity
triazine