Kinetic and potential sputtering of an anorthite-like glassy thin film

Hijazi, H.; Bannister, M. E.; Meyer, H. M.; Rouleau, C. M.; Meyer, F. W.

doi:10.1002/2017JE005300

Title: Kinetic and potential sputtering of an anorthite-like glassy thin film

Journal Article · Fri Jul 28 00:00:00 EDT 2017 · Journal of Geophysical Research. Planets

DOI:https://doi.org/10.1002/2017JE005300· OSTI ID:1394230

Hijazi, H. ^[1]; Bannister, M. E. ^[1]; Meyer, H. M. ^[2]; Rouleau, C. M. ^[3]; Meyer, F. W. ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Physics Division
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science

Abstract In this paper, we present measurements of He ⁺ and He ⁺² ion‐induced sputtering of an anorthite‐like thin film at a fixed solar wind‐relevant impact energy of ~0.5 keV/amu using a quartz crystal microbalance approach (QCM) for determination of total absolute sputtering yields. He ⁺² ions are the most abundant multicharged ions in the solar wind, and increased sputtering by these ions in comparison to equivelocity He ⁺ ions is expected to have the biggest effect on the overall sputtering efficiency of solar wind impact on the Moon. Our measurements indicate an almost 70% increase of the sputtering yield for doubly charged incident He ions compared to that for same velocity He ⁺ impact (14.6 amu/ion for He ⁺² vs. 8.7 amu/ion for He ⁺ ). Using a selective sputtering model, the new QCM results presented here, together with previously published results for Ar ^+q ions and SRIM results for the relevant kinetic‐sputtering yields, the effect due to multicharged‐solar‐wind‐ion impact on local near‐surface modification of lunar anorthite‐like soil is explored. It is shown that the multicharged‐solar‐wind component leads to a more pronounced and significant differentiation of depleted and enriched surface elements as well as a shortening of the timescale over which such surface‐compositional modifications might occur in astrophysical settings. In addition, to validate previous and future determinations of multicharged‐ion‐induced sputtering enhancement for those cases where the QCM approach cannot be used, relative quadrupole mass spectrometry (QMS)‐based measurements are presented for the same anorthite‐like thin film as were investigated by QCM, and their suitability and limitations for charge state‐enhanced yield measurements are discussed.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1394230

Alternate ID(s):: OSTI ID: 1374763

Journal Information:: Journal of Geophysical Research. Planets, Vol. 122, Issue 7; ISSN 2169-9097

Publisher:: American Geophysical UnionCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 6 works

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References (28)

Sputtering of ice by low-energy ions Famá, M.; Shi, J.; Baragiola, R. A. Surface Science, Vol. 602, Issue 1 https://doi.org/10.1016/j.susc.2007.10.002	journal	January 2008
Evidence of Coulomb explosion sputtering of ultra-thin Pt films due to impact of multi-charged Ar ions Ghose, D.; Karmakar, P.; Parilis, E. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 212 https://doi.org/10.1016/S0168-583X(03)01743-9	journal	December 2003
Mass fractionation of the lunar surface by solar wind sputtering Switkowski, Z. E.; Haff, P. K.; Tombrello, T. A. Journal of Geophysical Research, Vol. 82, Issue 26 https://doi.org/10.1029/JB082i026p03797	journal	September 1977
Solar-wind protons and heavy ions sputtering of lunar surface materials Barghouty, A. F.; Meyer, F. W.; Harris, P. R. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 269, Issue 11 https://doi.org/10.1016/j.nimb.2010.12.033	journal	June 2011
The lunar exosphere: The sputtering contribution Wurz, P.; Rohner, U.; Whitby, J. A. Icarus, Vol. 191, Issue 2 https://doi.org/10.1016/j.icarus.2007.04.034	journal	November 2007
Luminescence excitation characteristics of Ca, Na and K-aluminosilicates (feldspars) in the stimulation range 5–40 eV: determination of the band-gap energies Malins, A. E. R.; Poolton, N. R. J.; Quinn, F. M. Journal of Physics D: Applied Physics, Vol. 37, Issue 10 https://doi.org/10.1088/0022-3727/37/10/005	journal	April 2004
Potential Sputtering of Clean ${SiO}_{2}$ by Slow Highly Charged Ions Sporn, M.; Libiseller, G.; Neidhart, T. Physical Review Letters, Vol. 79, Issue 5 https://doi.org/10.1103/PhysRevLett.79.945	journal	August 1997
Solar-Storm/Lunar Atmosphere Model (SSLAM): An overview of the effort and description of the driving storm environment: SSLAM DESCRIPTION Farrell, W. M.; Halekas, J. S.; Killen, R. M. Journal of Geophysical Research: Planets, Vol. 117, Issue E10 https://doi.org/10.1029/2012JE004070	journal	October 2012
Sputtering rates under solar-wind bombardment Wehner, G. K.; Kenknight, C.; Rosenberg, D. L. Planetary and Space Science, Vol. 11, Issue 8 https://doi.org/10.1016/0032-0633(63)90120-X	journal	August 1963
Sputtering and surface topography of oxides Nenadović, T.; Perraillon, B.; Bogdanov, Ž. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 48, Issue 1-4 https://doi.org/10.1016/0168-583X(90)90178-W	journal	March 1990
Angular and charge state distributions of highly charged ions scattered during low energy surface-channeling interactions with Au(110) Meyer, F. W.; Folkerts, L.; Schippers, S. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 100, Issue 2-3 https://doi.org/10.1016/0168-583X(94)00830-2	journal	June 1995
Threshold for Potential Sputtering of LiF Hayderer, G.; Schmid, M.; Varga, P. Physical Review Letters, Vol. 83, Issue 19 https://doi.org/10.1103/PhysRevLett.83.3948	journal	November 1999
Characterization of the calcium-fluoroaluminosilicate glass prepared by a non-hydrolytic sol-gel route for future dental application as glass ionomer cement Cestari, Alexandre; Avila, Lilian Rodrigues; Nassor, Evelisy Cristina Oliveira Materials Research, Vol. 12, Issue 2 https://doi.org/10.1590/S1516-14392009000200005	journal	June 2009
The lunar surface-exosphere connection: Measurement of secondary-ions from Apollo soils Dukes, C. A.; Baragiola, R. A. Icarus, Vol. 255 https://doi.org/10.1016/j.icarus.2014.11.032	journal	July 2015
Time Scales for Charge Equilibration of $O^{q +}$ $(3 \leq q \leq 8)$ Ions during Surface-Channeling Interactions with Au(110) Folkerts, L.; Schippers, S.; Zehner, D. M. Physical Review Letters, Vol. 74, Issue 12 https://doi.org/10.1103/PhysRevLett.74.2204	journal	March 1995
Potential sputtering: desorption from insulator surfaces by impact of slow multicharged ions Aumayr, F.; Varga, P.; Winter, H. P. International Journal of Mass Spectrometry, Vol. 192, Issue 1-3 https://doi.org/10.1016/S1387-3806(99)00075-5	journal	September 1999
Coulomb explosion potential sputtering induced by slow highly charged ion impact Tona, Masahide; Takahashi, Satoshi; Nagata, Kazuo Applied Physics Letters, Vol. 87, Issue 22 https://doi.org/10.1063/1.2136361	journal	November 2005
Modification of the lunar surface by the solar-wind bombardment Wehner, G. K.; Kenknight, C. E.; Rosenberg, D. Planetary and Space Science, Vol. 11, Issue 11 https://doi.org/10.1016/0032-0633(63)90229-0	journal	November 1963
Solar wind heavy ion abundances Bame, S. J.; Asbridge, J. R.; Feldman, W. C. Solar Physics, Vol. 43, Issue 2 https://doi.org/10.1007/BF00152368	journal	August 1975
Composition of quasi-stationary solar wind flows from Ulysses/Solar Wind Ion Composition Spectrometer von Steiger, R.; Schwadron, N. A.; Fisk, L. A. Journal of Geophysical Research: Space Physics, Vol. 105, Issue A12 https://doi.org/10.1029/1999JA000358	journal	December 2000
Srim-2003 Ziegler, James F. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 219-220 https://doi.org/10.1016/j.nimb.2004.01.208	journal	June 2004
Sputtering of lunar regolith simulant by protons and singly and multicharged Ar ions at solar wind energies Meyer, F. W.; Harris, P. R.; Taylor, C. N. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 269, Issue 11 https://doi.org/10.1016/j.nimb.2010.11.091	journal	June 2011
Anorthite and CaAl2Si2O8 glass: low frequency Raman spectroscopy and neutron scattering Le Parc, R.; Champagnon, B.; Dianoux, J. Journal of Non-Crystalline Solids, Vol. 323, Issue 1-3 https://doi.org/10.1016/S0022-3093(03)00302-8	journal	August 2003
Sputtering: survey of observations and derived principles Baragiola, Raúl A. Philosophical Transactions of the Royal Society of London. Series A: Mathematical, Physical and Engineering Sciences, Vol. 362, Issue 1814 https://doi.org/10.1098/rsta.2003.1301	journal	November 2003
Potential sputtering Aumayr, Friedrich; Winter, Hannspeter Philosophical Transactions of the Royal Society of London. Series A: Mathematical, Physical and Engineering Sciences, Vol. 362, Issue 1814 https://doi.org/10.1098/rsta.2003.1300	journal	November 2003
Recent advances in pulsed-laser deposition of complex oxides Christen, H. M.; Eres, G. Journal of Physics: Condensed Matter, Vol. 20, Issue 26 https://doi.org/10.1088/0953-8984/20/26/264005	journal	June 2008
Sputtering of Au and Al2O3 surfaces by slow highly charged ions Hayderer, G.; Cernusca, S.; Hoffmann, V. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 182, Issue 1-4 https://doi.org/10.1016/S0168-583X(01)00668-1	journal	August 2001
Anorthite sputtering by H ⁺ and Ar ^{q +} ( q = 1-9) at solar wind velocities Hijazi, H.; Bannister, M. E.; Meyer, H. M. Journal of Geophysical Research: Space Physics, Vol. 119, Issue 10 https://doi.org/10.1002/2014JA020140	journal	October 2014

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