Alcohol Oxidation at Platinum–Gas and Platinum–Liquid Interfaces: The Effect of Platinum Nanoparticle Size, Water Coadsorption, and Alcohol Concentration

Tatsumi, Hironori; Liu, Fudong; Han, Hui-Ling; Carl, Lindsay M.; Sapi, Andras; Somorjai, Gabor A.

doi:10.1021/acs.jpcc.7b01432

Alcohol Oxidation at Platinum–Gas and Platinum–Liquid Interfaces: The Effect of Platinum Nanoparticle Size, Water Coadsorption, and Alcohol Concentration

Journal Article · Tue Mar 21 00:00:00 EDT 2017 · Journal of Physical Chemistry. C

DOI:https://doi.org/10.1021/acs.jpcc.7b01432· OSTI ID:1393219

^[1]; Liu, Fudong ^[1]; Han, Hui-Ling ^[1]; Carl, Lindsay M. ^[2]; ^[1]; Somorjai, Gabor A. ^[2]

Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Berkeley, CA (United States)

Platinum nanoparticles size range from 1 to 8 nm deposited on mesoporous silica MCF-17 catalyzed alcohol oxidations were studied in the gas and liquid phases. Among methanol, ethanol, 2- propanol and 2-butanol reactions, the turnover frequency increased with Pt nanoparticle size for all the alcohols utilized. The activation energies for the oxidations were almost same among all alcohol species, but higher in the gas phase than those in the liquid phase. Water coadsorption poisoned the reaction in the gas phase, while it increased the reaction turnover rates in the liquid phase. Sum frequency generation (SFG) vibrational spectroscopy studies and DFT calculations revealed that the alcohol molecules pack horizontally on the metal surface in low concentrations and stand up in high concentrations, which affect the dissociation of β-hydrogen of the alcohols as the critical step in alcohol oxidations.

View Accepted Manuscript (DOE)

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1393219

Journal Information:: Journal of Physical Chemistry. C, Journal Name: Journal of Physical Chemistry. C Journal Issue: 13 Vol. 121; ISSN 1932-7447

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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