Diketopyrrolopyrrole-based polymer:fullerene nanoparticle films with thermally stable morphology for organic photovoltaic applications

Holmes, Natalie P.; Vaughan, Ben; Williams, Evan L.; Kroon, Renee; Anderrson, Mats R.; Kilcoyne, A. L. David; Sonar, Prashant; Zhou, Xiaojing; Dastoor, Paul C.; Belcher, Warwick J.

doi:10.1557/mrc.2017.3

Title: Diketopyrrolopyrrole-based polymer:fullerene nanoparticle films with thermally stable morphology for organic photovoltaic applications

Journal Article · Thu Feb 02 00:00:00 EST 2017 · MRS Communications

DOI:https://doi.org/10.1557/mrc.2017.3· OSTI ID:1393119

Holmes, Natalie P. ^[1]; Vaughan, Ben ^[2]; Williams, Evan L. ^[3]; Kroon, Renee ^[4]; Anderrson, Mats R. ^[4]; Kilcoyne, A. L. David ^[5]; Sonar, Prashant ^[6]; Zhou, Xiaojing ^[1]; Dastoor, Paul C. ^[1]; Belcher, Warwick J. ^[1]

Univ. of Newcastle, Callaghan NSW (Australia). Centre for Organic Electronics
Univ. of Newcastle, Callaghan NSW (Australia). Centre for Organic Electronics; CSIRO Energy Technology, Newcastle (Australia)
Inst. of Materials Research and Engineering (IMRE), Agency for Science, Technology, and Research (A*STAR), Singapore (Singapore)
Univ. of South Australia, Mawson Lakes Campus, SA (Australia). Ian Wark Research Inst.; Chalmers Univ. of Technology, Goteborg (Sweden). Dept. of Chemical and Biological Engineering/Polymer Technology
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
Inst. of Materials Research and Engineering (IMRE), Agency for Science, Technology, and Research (A*STAR), Singapore (Singapore); Queensland Univ. of Technology (QUT), Brisbane (Australia). School of Chemistry, Physics and Mechanical Engineering

Polymer:fullerene nanoparticles (NPs) offer two key advantages over bulk heterojunction (BHJ) films for organic photovoltaics (OPVs), water-processability and potentially superior morphological control. Once an optimal active layer morphology is reached, maintaining this morphology at OPV operating temperatures is key to the lifetime of a device. Here in this paper we study the morphology of the PDPP-TNT (poly{3,6-dithiophene-2-yl-2,5-di(2-octyldodecyl)-pyrrolo[3,4-c]pyrrole-1,4-dione-alt-naphthalene}):PC₇₁BM ([6,6]-phenyl C₇₁ butyric acid methyl ester) NP system and then compare the thermal stability of NP and BHJ films to the common poly(3-hexylthiophene) (P3HT): phenyl C₆₁ butyric acid methyl ester (PC₆₁BM) system. We find that material T_g plays a key role in the superior thermal stability of the PDPP-TNT:PC₇₁BM system; whereas for the P3HT:PC₆₁BM system, domain structure is critical.

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Research Organization:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: AC02-05CH11231

OSTI ID:: 1393119

Journal Information:: MRS Communications, Vol. 7, Issue 01; ISSN 2159-6859

Publisher:: Materials Research Society - Cambridge University Press

Country of Publication:: United States

Language:: English

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