Electrochromic performance of nanocomposite nickel oxide counter electrodes containing lithium and zirconium
Nickel oxide materials are suitable for counter electrodes in complementary electrochromic devices. The state-of-the-art nickel oxide counter electrode materials are typically prepared with multiple additives to enhance peformance. Herein, nanocomposite nickel oxide counter electrodes were fabricated via RF magnetron co-sputtering from Ni-Zr alloy and Li2O ceramic targets. The as-deposited nanocomposite counter electrodes were characterized with inductively coupled plasma mass spectrometry (ICP-MS), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD), and X-ray absorption spectroscopy (XAS). It was found that the stoichiometry, crystal structure and electronic structure of the nickel oxide-based materials could be readily tuned by varying the Li2O sputter deposition power level. Comprehensive electrochromic evaluation demonstrated that the performance of the nickel oxide-based materials was dependent on the overall Li stoichiometry. Overall, the nanocomposite nickel oxide counter electrode containing lithium and zirconium synthesized with a Li2O deposition power of 45 W exhibited the optimal performance with an optical modulation of 71% and coloration efficiency of 30 cm2/C at 670 nm in Li-ion electrolyte.
- Research Organization:
- National Renewable Energy Lab. (NREL), Golden, CO (United States)
- Sponsoring Organization:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Energy Efficiency Office. Building Technologies Office
- DOE Contract Number:
- AC36-08GO28308
- OSTI ID:
- 1392778
- Report Number(s):
- NREL/JA-5900-70123
- Journal Information:
- Solar Energy Materials and Solar Cells, Vol. 126, Issue C; ISSN 0927-0248
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
Similar Records
Electrochromic Properties of Perovskite NdNiO3 Thin Films for Smart Windows
Decreased electrochromism in Li-intercalated Ti oxide films containing La, Ce, and Pr