Characterization of magnetic properties of Sr2 CuWO6 and Sr2 CuMoO6

Vasala, Sami; Saadaoui, Hassan; Morenzoni, Elvezio; Chmaissem, Omar; Chan, Ting-Shan; Chen, Jin-Ming; Hsu, Ying-Ya; Yamauchi, Hisao; Karppinen, Maarit

doi:10.1103/PhysRevB.89.134419

Characterization of magnetic properties of ${Sr}_{2}$ ${CuWO}_{6}$ and ${Sr}_{2}$ ${CuMoO}_{6}$

Journal Article · Tue Apr 01 00:00:00 EDT 2014 · Physical Review. B, Condensed Matter and Materials Physics

DOI:https://doi.org/10.1103/PhysRevB.89.134419· OSTI ID:1392128

Vasala, Sami; Saadaoui, Hassan; Morenzoni, Elvezio; Chmaissem, Omar; Chan, Ting-Shan; Chen, Jin-Ming; Hsu, Ying-Ya; Yamauchi, Hisao; Karppinen, Maarit

In this work we examine the low-temperature magnetic properties of the two double-perovskite compounds Sr2CuWO6 and Sr2CuMoO6 using magnetic susceptibility, muon spin rotation and relaxation, and neutron powder diffraction measurements. Additionally, the most relevant spin exchange interaction constants are derived from ab initio electronic structure calculations, aided by x-ray absorption spectroscopy. The compounds exhibit quasi-two-dimensional magnetic properties, with broad maxima at T-max = 83 and 95 K for Sr2CuWO6 and Sr2CuMoO6, respectively. However, three-dimensional long-range order takes place below T-N = 24(1) and 28(2) K for Sr2CuWO6 and Sr2CuMoO6, respectively. Our results show that the low-dimensional magnetic correlations are mainly due to the significant next-nearest-neighbor interactions in the ab plane of the double-perovskite structure, whereas three-dimensional long-range magnetic order is caused by weaker next-nearest-neighbor interactions along the c axis. Next-nearest-neighbor interactions are also slightly frustrated by weaker nearest-neighbor interactions within the ab plane. Based on these results we predict the low-temperature magnetic structure in these compounds to be type-II antiferromagnetic order of the double-perovskite lattice.

Research Organization:: Argonne National Laboratory (ANL)

Sponsoring Organization:: USDOE Office of Science - Office of Basic Energy Sciences

DOE Contract Number:: AC02-06CH11357

OSTI ID:: 1392128

Journal Information:: Physical Review. B, Condensed Matter and Materials Physics, Journal Name: Physical Review. B, Condensed Matter and Materials Physics Journal Issue: 13 Vol. 89; ISSN 1098-0121; ISSN PRBMDO

Publisher:: American Physical Society (APS)

Country of Publication:: United States

Language:: English

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