Molecular composition and volatility of isoprene photochemical oxidation secondary organic aerosol under low- and high-NOx conditions

D'Ambro, Emma L.; Lee, Ben H.; Liu, Jiumeng; Shilling, John E.; Gaston, Cassandra J.; Lopez-Hilfiker, Felipe D.; Schobesberger, Siegfried; Zaveri, Rahul A.; Mohr, Claudia; Lutz, Anna; Zhang, Zhenfa; Gold, Avram; Surratt, Jason D.; Rivera-Rios, Jean C.; Keutsch, Frank N.; Thornton, Joel A.

doi:10.5194/acp-17-159-2017

Title: Molecular composition and volatility of isoprene photochemical oxidation secondary organic aerosol under low- and high-NOx conditions

Journal Article · Wed Jan 04 00:00:00 EST 2017 · Atmospheric Chemistry and Physics (Online)

DOI:https://doi.org/10.5194/acp-17-159-2017· OSTI ID:1338140

; Lee, Ben H.;

;

; Gaston, Cassandra J.; Lopez-Hilfiker, Felipe D.;

;

; Lutz, Anna; Zhang, Zhenfa; Gold, Avram;

; Rivera-Rios, Jean C.; Keutsch, Frank N.; Thornton, Joel A.

We present measurements of secondary organic aerosol (SOA) formation from isoprene photochemical oxidation in an environmental simulation chamber at a variety of oxidant conditions and using dry neutral seed particles to suppress acid-catalyzed multiphase chemistry. A high-resolution time-of-flight chemical ionization mass spectrometer (HR-ToF-CIMS) utilizing iodide-adduct ionization coupled to the Filter Inlet for Gases and Aerosols (FIGAERO) allowed for simultaneous online sampling of the gas and particle composition. Under high-HO₂ and low-NO conditions, highly oxygenated (O : C ≥ 1) C₅ compounds were major components (~50 %) of SOA. The SOA composition and effective volatility evolved both as a function of time and as a function of input NO concentrations. Organic nitrates increased in both the gas and particle phases as input NO increased, but the dominant non-nitrate particle-phase components monotonically decreased. We use comparisons of measured and predicted gas-particle partitioning of individual components to assess the validity of literature-based group-contribution methods for estimating saturation vapor concentrations. While there is evidence for equilibrium partitioning being achieved on the chamber residence timescale (5.2 h) for some individual components, significant errors in group-contribution methods are revealed. In addition, > 30 % of the SOA mass, detected as low-molecular-weight semivolatile compounds, cannot be reconciled with equilibrium partitioning. These compounds desorb from the FIGAERO at unexpectedly high temperatures given their molecular composition, which is indicative of thermal decomposition of effectively lower-volatility components such as larger molecular weight oligomers.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-76RL01830; SC0011791

OSTI ID:: 1338140

Alternate ID(s):: OSTI ID: 1339791; OSTI ID: 1390603

Report Number(s):: PNNL-SA-119934

Journal Information:: Atmospheric Chemistry and Physics (Online), Journal Name: Atmospheric Chemistry and Physics (Online) Vol. 17 Journal Issue: 1; ISSN 1680-7324

Publisher:: Copernicus Publications, EGUCopyright Statement

Country of Publication:: Germany

Language:: English

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Cited by: 57 works

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References (70)

Organic aerosol formation from the reactive uptake of isoprene epoxydiols (IEPOX) onto non-acidified inorganic seeds Nguyen, T. B.; Coggon, M. M.; Bates, K. H. Atmospheric Chemistry and Physics, Vol. 14, Issue 7 https://doi.org/10.5194/acp-14-3497-2014	journal	January 2014
Effect of Acidity on Secondary Organic Aerosol Formation from Isoprene Surratt, Jason D.; Lewandowski, Michael; Offenberg, John H. Environmental Science & Technology, Vol. 41, Issue 15 https://doi.org/10.1021/es0704176	journal	August 2007
Formation of 2-methyl tetrols and 2-methylglyceric acid in secondary organic aerosol from laboratory irradiated isoprene/NOX/SO2/air mixtures and their detection in ambient PM2.5 samples collected in the eastern United States Edney, E. O.; Kleindienst, T. E.; Jaoui, M. Atmospheric Environment, Vol. 39, Issue 29 https://doi.org/10.1016/j.atmosenv.2005.05.031	journal	September 2005
SIMPOL.1: a simple group contribution method for predicting vapor pressures and enthalpies of vaporization of multifunctional organic compounds Pankow, J. F.; Asher, W. E. Atmospheric Chemistry and Physics, Vol. 8, Issue 10 https://doi.org/10.5194/acp-8-2773-2008	journal	January 2008
Spatial and Seasonal Trends in Biogenic Secondary Organic Aerosol Tracers and Water-Soluble Organic Carbon in the Southeastern United States Ding, Xiang; Zheng, Mei; Yu, Liping Environmental Science & Technology, Vol. 42, Issue 14 https://doi.org/10.1021/es7032636	journal	July 2008
Formation of Low Volatility Organic Compounds and Secondary Organic Aerosol from Isoprene Hydroxyhydroperoxide Low-NO Oxidation Krechmer, Jordan E.; Coggon, Matthew M.; Massoli, Paola Environmental Science & Technology, Vol. 49, Issue 17 https://doi.org/10.1021/acs.est.5b02031	journal	July 2015
Seasonal Variation of 2-Methyltetrols in Ambient Air Samples Xia, Xiaoyan; Hopke, Philip K. Environmental Science & Technology, Vol. 40, Issue 22 https://doi.org/10.1021/es060988i	journal	November 2006
A study of secondary organic aerosol formation in the anthropogenic-influenced southeastern United States: SOA FORMATION IN THE POLLUTED SOUTHEAST Weber, Rodney J.; Sullivan, Amy P.; Peltier, Richard E. Journal of Geophysical Research: Atmospheres, Vol. 112, Issue D13 https://doi.org/10.1029/2007JD008408	journal	July 2007
Organic condensation: a vital link connecting aerosol formation to cloud condensation nuclei (CCN) concentrations Riipinen, I.; Pierce, J. R.; Yli-Juuti, T. Atmospheric Chemistry and Physics, Vol. 11, Issue 8 https://doi.org/10.5194/acp-11-3865-2011	journal	January 2011
Enhanced SOA formation from mixed anthropogenic and biogenic emissions during the CARES campaign Shilling, J. E.; Zaveri, R. A.; Fast, J. D. Atmospheric Chemistry and Physics, Vol. 13, Issue 4 https://doi.org/10.5194/acp-13-2091-2013	journal	January 2013
The formation of secondary organic aerosol from the isoprene + OH reaction in the absence of NO _x Kleindienst, T. E.; Lewandowski, M.; Offenberg, J. H. Atmospheric Chemistry and Physics, Vol. 9, Issue 17 https://doi.org/10.5194/acp-9-6541-2009	journal	January 2009
The Model of Emissions of Gases and Aerosols from Nature version 2.1 (MEGAN2.1): an extended and updated framework for modeling biogenic emissions Guenther, A. B.; Jiang, X.; Heald, C. L. Geoscientific Model Development, Vol. 5, Issue 6 https://doi.org/10.5194/gmd-5-1471-2012	journal	January 2012
Online molecular characterization of fine particulate matter in Port Angeles, WA: Evidence for a major impact from residential wood smoke Gaston, Cassandra J.; Lopez-Hilfiker, Felipe D.; Whybrew, Lauren E. Atmospheric Environment, Vol. 138 https://doi.org/10.1016/j.atmosenv.2016.05.013	journal	August 2016
Efficient Isoprene Secondary Organic Aerosol Formation from a Non-IEPOX Pathway Liu, Jiumeng; D’Ambro, Emma L.; Lee, Ben H. Environmental Science & Technology, Vol. 50, Issue 18 https://doi.org/10.1021/acs.est.6b01872	journal	September 2016
Phase partitioning and volatility of secondary organic aerosol components formed from α-pinene ozonolysis and OH oxidation: the importance of accretion products and other low volatility compounds Lopez-Hilfiker, F. D.; Mohr, C.; Ehn, M. Atmospheric Chemistry and Physics, Vol. 15, Issue 14 https://doi.org/10.5194/acp-15-7765-2015	journal	January 2015
Influence of vapor wall loss in laboratory chambers on yields of secondary organic aerosol Zhang, X.; Cappa, C. D.; Jathar, S. H. Proceedings of the National Academy of Sciences, Vol. 111, Issue 16 https://doi.org/10.1073/pnas.1404727111	journal	April 2014
Atmospheric Aerosols: Composition, Transformation, Climate and Health Effects Pöschl, Ulrich Angewandte Chemie International Edition, Vol. 44, Issue 46 https://doi.org/10.1002/anie.200501122	journal	November 2005
Effects of anthropogenic emissions on aerosol formation from isoprene and monoterpenes in the southeastern United States Xu, Lu; Guo, Hongyu; Boyd, Christopher M. Proceedings of the National Academy of Sciences, Vol. 112, Issue 1 https://doi.org/10.1073/pnas.1417609112	journal	December 2014
Epoxide as a precursor to secondary organic aerosol formation from isoprene photooxidation in the presence of nitrogen oxides Lin, Y. -H.; Zhang, H.; Pye, H. O. T. Proceedings of the National Academy of Sciences, Vol. 110, Issue 17 https://doi.org/10.1073/pnas.1221150110	journal	April 2013
Estimation of pure component properties Nannoolal, Yash; Rarey, Jürgen; Ramjugernath, Deresh Fluid Phase Equilibria, Vol. 269, Issue 1-2 https://doi.org/10.1016/j.fluid.2008.04.020	journal	July 2008
Cloud droplet activation of mixed organic-sulfate particles produced by the photooxidation of isoprene King, S. M.; Rosenoern, T.; Shilling, J. E. Atmospheric Chemistry and Physics, Vol. 10, Issue 8 https://doi.org/10.5194/acp-10-3953-2010	journal	January 2010
Contributions of Organic Peroxides to Secondary Aerosol Formed from Reactions of Monoterpenes with O ₃ Docherty, Kenneth S.; Wu, Wilbur; Lim, Yong Bin Environmental Science & Technology, Vol. 39, Issue 11 https://doi.org/10.1021/es050228s	journal	June 2005
Molecular Composition and Volatility of Organic Aerosol in the Southeastern U.S.: Implications for IEPOX Derived SOA Lopez-Hilfiker, F. D.; Mohr, C.; D’Ambro, E. L. Environmental Science & Technology, Vol. 50, Issue 5 https://doi.org/10.1021/acs.est.5b04769	journal	February 2016
Particle mass yield in secondary organic aerosol formed by the dark ozonolysis of α-pinene Shilling, J. E.; Chen, Q.; King, S. M. Atmospheric Chemistry and Physics, Vol. 8, Issue 7 https://doi.org/10.5194/acp-8-2073-2008	journal	January 2008
Laboratory observation of oligomers in the aerosol from isoprene/NO _x photooxidation Dommen, J.; Metzger, A.; Duplissy, J. Geophysical Research Letters, Vol. 33, Issue 13 https://doi.org/10.1029/2006GL026523	journal	January 2006
(CH3)3COOH (tert-butyl hydroperoxide): OH reaction rate coefficients between 206 and 375 K and the OH photolysis quantum yield at 248 nm Baasandorj, Munkhbayar; Papanastasiou, Dimitrios K.; Talukdar, Ranajit K. Physical Chemistry Chemical Physics, Vol. 12, Issue 38 https://doi.org/10.1039/c0cp00463d	journal	January 2010
Uptake of Epoxydiol Isomers Accounts for Half of the Particle-Phase Material Produced from Isoprene Photooxidation via the HO ₂ Pathway Liu, Yingjun; Kuwata, Mikinori; Strick, Benjamin F. Environmental Science & Technology, Vol. 49, Issue 1 https://doi.org/10.1021/es5034298	journal	December 2014
An absorption model of gas/particle partitioning of organic compounds in the atmosphere Pankow, James F. Atmospheric Environment, Vol. 28, Issue 2 https://doi.org/10.1016/1352-2310(94)90093-0	journal	January 1994
Ubiquity and dominance of oxygenated species in organic aerosols in anthropogenically-influenced Northern Hemisphere midlatitudes: UBIQUITY AND DOMINANCE OF OXYGENATED OA Zhang, Q.; Jimenez, J. L.; Canagaratna, M. R. Geophysical Research Letters, Vol. 34, Issue 13 https://doi.org/10.1029/2007GL029979	journal	July 2007
Kinetics and Products of the Reaction of the First-Generation Isoprene Hydroxy Hydroperoxide (ISOPOOH) with OH St. Clair, Jason M.; Rivera-Rios, Jean C.; Crounse, John D. The Journal of Physical Chemistry A, Vol. 120, Issue 9 https://doi.org/10.1021/acs.jpca.5b06532	journal	September 2015
Trends in organic hydroperoxide photodissociation and absorption cross sections between 266 and 377 nm Hsieh, Shizuka; Vushe, Rumbidzai; Tun, Yamin T. Chemical Physics Letters, Vol. 591 https://doi.org/10.1016/j.cplett.2013.11.008	journal	January 2014
Reactive intermediates revealed in secondary organic aerosol formation from isoprene Surratt, J. D.; Chan, A. W. H.; Eddingsaas, N. C. Proceedings of the National Academy of Sciences, Vol. 107, Issue 15 https://doi.org/10.1073/pnas.0911114107	journal	December 2009
Observation of 2-methyltetrols and related photo-oxidation products of isoprene in boreal forest aerosols from Hyytiälä, Finland Kourtchev, I.; Ruuskanen, T.; Maenhaut, W. Atmospheric Chemistry and Physics, Vol. 5, Issue 10 https://doi.org/10.5194/acp-5-2761-2005	journal	January 2005
Explicit modelling of SOA formation from α-pinene photooxidation: sensitivity to vapour pressure estimation Valorso, R.; Aumont, B.; Camredon, M. Atmospheric Chemistry and Physics, Vol. 11, Issue 14 https://doi.org/10.5194/acp-11-6895-2011	journal	January 2011
Sources and formation pathways of organic aerosol in a subtropical metropolis during summer Tsai, I-Chun; Chen, Jen-Ping; Lung, Candice Shi-Chun Atmospheric Environment, Vol. 117 https://doi.org/10.1016/j.atmosenv.2015.07.005	journal	September 2015
Evolution of Organic Aerosols in the Atmosphere Jimenez, J. L.; Canagaratna, M. R.; Donahue, N. M. Science, Vol. 326, Issue 5959 https://doi.org/10.1126/science.1180353	journal	December 2009
Secondary organic aerosol formation from isoprene photooxidation under high-NO _x conditions : SOA FORMATION FROM ISOPRENE OXIDATION Kroll, Jesse H.; Ng, Nga L.; Murphy, Shane M. Geophysical Research Letters, Vol. 32, Issue 18 https://doi.org/10.1029/2005GL023637	journal	September 2005
Heterogeneous Atmospheric Aerosol Production by Acid-Catalyzed Particle-Phase Reactions Jang, M. Science, Vol. 298, Issue 5594 https://doi.org/10.1126/science.1075798	journal	October 2002
Aerosol formation in the photooxidation of isoprene and β-pinene Pandis, Spyros N.; Paulson, Suzanne E.; Seinfeld, John H. Atmospheric Environment. Part A. General Topics, Vol. 25, Issue 5-6 https://doi.org/10.1016/0960-1686(91)90141-S	journal	January 1991
EVAPORATION: a new vapour pressure estimation methodfor organic molecules including non-additivity and intramolecular interactions Compernolle, S.; Ceulemans, K.; Müller, J. -F. Atmospheric Chemistry and Physics, Vol. 11, Issue 18 https://doi.org/10.5194/acp-11-9431-2011	journal	January 2011
Effect of relative humidity on SOA formation from isoprene/NO photooxidation: enhancement of 2-methylglyceric acid and its corresponding oligoesters under dry conditions Zhang, H.; Surratt, J. D.; Lin, Y. H. Atmospheric Chemistry and Physics, Vol. 11, Issue 13 https://doi.org/10.5194/acp-11-6411-2011	journal	January 2011
Secondary Organic Aerosol Formation from Isoprene Photooxidation Kroll, Jesse H.; Ng, Nga L.; Murphy, Shane M. Environmental Science & Technology, Vol. 40, Issue 6 https://doi.org/10.1021/es0524301	journal	March 2006
A group contribution method for estimating the vapour pressures of α-pinene oxidation products Capouet, M.; Müller, J. -F. Atmospheric Chemistry and Physics, Vol. 6, Issue 6 https://doi.org/10.5194/acp-6-1455-2006	journal	January 2006
Formation of Secondary Organic Aerosols Through Photooxidation of Isoprene Claeys, M. Science, Vol. 303, Issue 5661 https://doi.org/10.1126/science.1092805	journal	February 2004
α-Pinene Autoxidation Products May Not Have Extremely Low Saturation Vapor Pressures Despite High O:C Ratios Kurtén, Theo; Tiusanen, Kirsi; Roldin, Pontus The Journal of Physical Chemistry A, Vol. 120, Issue 16 https://doi.org/10.1021/acs.jpca.6b02196	journal	April 2016
Reactive Uptake of an Isoprene-Derived Epoxydiol to Submicron Aerosol Particles Gaston, Cassandra J.; Riedel, Theran P.; Zhang, Zhenfa Environmental Science & Technology, Vol. 48, Issue 19 https://doi.org/10.1021/es5034266	journal	September 2014
On Rates and Mechanisms of OH and O ₃ Reactions with Isoprene-Derived Hydroxy Nitrates Lee, Lance; Teng, Alex P.; Wennberg, Paul O. The Journal of Physical Chemistry A, Vol. 118, Issue 9 https://doi.org/10.1021/jp4107603	journal	February 2014
Isoprene photooxidation: new insights into the production of acids and organic nitrates Paulot, F.; Crounse, J. D.; Kjaergaard, H. G. Atmospheric Chemistry and Physics, Vol. 9, Issue 4 https://doi.org/10.5194/acp-9-1479-2009	journal	January 2009
Chemical Composition of Secondary Organic Aerosol Formed from the Photooxidation of Isoprene Surratt, Jason D.; Murphy, Shane M.; Kroll, Jesse H. The Journal of Physical Chemistry A, Vol. 110, Issue 31 https://doi.org/10.1021/jp061734m	journal	August 2006
Kinetics of the reactions of isoprene-derived hydroxynitrates: gas phase epoxide formation and solution phase hydrolysis Jacobs, M. I.; Burke, W. J.; Elrod, M. J. Atmospheric Chemistry and Physics, Vol. 14, Issue 17 https://doi.org/10.5194/acp-14-8933-2014	journal	January 2014
Highly functionalized organic nitrates in the southeast United States: Contribution to secondary organic aerosol and reactive nitrogen budgets Lee, Ben H.; Mohr, Claudia; Lopez-Hilfiker, Felipe D. Proceedings of the National Academy of Sciences, Vol. 113, Issue 6 https://doi.org/10.1073/pnas.1508108113	journal	January 2016
Mechanism of the hydroxyl radical oxidation of methacryloyl peroxynitrate (MPAN) and its pathway toward secondary organic aerosol formation in the atmosphere Nguyen, Tran B.; Bates, Kelvin H.; Crounse, John D. Physical Chemistry Chemical Physics, Vol. 17, Issue 27 https://doi.org/10.1039/C5CP02001H	journal	January 2015
Theoretical constraints on pure vapor-pressure driven condensation of organics to ultrafine particles: ORGANIC CONDENSATION Donahue, N. M.; Trump, E. R.; Pierce, J. R. Geophysical Research Letters, Vol. 38, Issue 16 https://doi.org/10.1029/2011GL048115	journal	August 2011
Hydrolysis of Organonitrate Functional Groups in Aerosol Particles Liu, Shang; Shilling, John E.; Song, Chen Aerosol Science and Technology, Vol. 46, Issue 12 https://doi.org/10.1080/02786826.2012.716175	journal	December 2012
Heterogeneous Reactions of Isoprene-Derived Epoxides: Reaction Probabilities and Molar Secondary Organic Aerosol Yield Estimates Riedel, Theran P.; Lin, Ying-Hsuan; Budisulistiorini, Sri Hapsari Environmental Science & Technology Letters, Vol. 2, Issue 2 https://doi.org/10.1021/ez500406f	journal	January 2015
Effect of NO _x on Secondary Organic Aerosol Concentrations Lane, Timothy E.; Donahue, Neil M.; Pandis, Spyros N. Environmental Science & Technology, Vol. 42, Issue 16 https://doi.org/10.1021/es703225a	journal	August 2008
A novel method for online analysis of gas and particle composition: description and evaluation of a Filter Inlet for Gases and AEROsols (FIGAERO) Lopez-Hilfiker, F. D.; Mohr, C.; Ehn, M. Atmospheric Measurement Techniques, Vol. 7, Issue 4 https://doi.org/10.5194/amt-7-983-2014	journal	January 2014
Investigating the influences of SO ₂ and NH ₃ levels on isoprene-derived secondary organic aerosol formation using conditional sampling approaches Lin, Y. -H.; Knipping, E. M.; Edgerton, E. S. Atmospheric Chemistry and Physics, Vol. 13, Issue 16 https://doi.org/10.5194/acp-13-8457-2013	journal	January 2013
Isoprene Epoxydiols as Precursors to Secondary Organic Aerosol Formation: Acid-Catalyzed Reactive Uptake Studies with Authentic Compounds Lin, Ying-Hsuan; Zhang, Zhenfa; Docherty, Kenneth S. Environmental Science & Technology, Vol. 46, Issue 1 https://doi.org/10.1021/es202554c	journal	November 2011
Effects of NO _x on the Volatility of Secondary Organic Aerosol from Isoprene Photooxidation Xu, Lu; Kollman, Matthew S.; Song, Chen Environmental Science & Technology, Vol. 48, Issue 4 https://doi.org/10.1021/es404842g	journal	February 2014
Constraining the sensitivity of iodide adduct chemical ionization mass spectrometry to multifunctional organic molecules using the collision limit and thermodynamic stability of iodide ion adducts Lopez-Hilfiker, Felipe D.; Iyer, Siddarth; Mohr, Claudia Atmospheric Measurement Techniques, Vol. 9, Issue 4 https://doi.org/10.5194/amt-9-1505-2016	journal	January 2016
Near-UV photolysis cross sections of CH<sub>3</sub>OOH and HOCH<sub>2</sub>OOH determined via action spectroscopy Roehl, C. M.; Marka, Z.; Fry, J. L. Atmospheric Chemistry and Physics, Vol. 7, Issue 3 https://doi.org/10.5194/acp-7-713-2007	journal	January 2007
Simulating secondary organic aerosol in a regional air quality model using the statistical oxidation model – Part 1: Assessing the influence of constrained multi-generational ageing Jathar, S. H.; Cappa, C. D.; Wexler, A. S. Atmospheric Chemistry and Physics, Vol. 16, Issue 4 https://doi.org/10.5194/acp-16-2309-2016	journal	January 2016
Light-Absorbing Oligomer Formation in Secondary Organic Aerosol from Reactive Uptake of Isoprene Epoxydiols Lin, Ying-Hsuan; Budisulistiorini, Sri Hapsari; Chu, Kevin Environmental Science & Technology, Vol. 48, Issue 20 https://doi.org/10.1021/es503142b	journal	October 2014
Ion-induced nucleation of pure biogenic particles Kirkby, Jasper; Duplissy, Jonathan; Sengupta, Kamalika Nature, Vol. 533, Issue 7604 https://doi.org/10.1038/nature17953	journal	May 2016
Secondary organic aerosol formation from the photooxidation of isoprene, 1,3-butadiene, and 2,3-dimethyl-1,3-butadiene under high NO _x conditions Sato, K.; Nakao, S.; Clark, C. H. Atmospheric Chemistry and Physics, Vol. 11, Issue 14 https://doi.org/10.5194/acp-11-7301-2011	journal	January 2011
Chemical Characterization of Secondary Organic Aerosol from Oxidation of Isoprene Hydroxyhydroperoxides Riva, Matthieu; Budisulistiorini, Sri H.; Chen, Yuzhi Environmental Science & Technology, Vol. 50, Issue 18 https://doi.org/10.1021/acs.est.6b02511	journal	September 2016
An Iodide-Adduct High-Resolution Time-of-Flight Chemical-Ionization Mass Spectrometer: Application to Atmospheric Inorganic and Organic Compounds Lee, Ben H.; Lopez-Hilfiker, Felipe D.; Mohr, Claudia Environmental Science & Technology, Vol. 48, Issue 11 https://doi.org/10.1021/es500362a	journal	May 2014
Coupled Partitioning, Dilution, and Chemical Aging of Semivolatile Organics Donahue, N. M.; Robinson, A. L.; Stanier, C. O. Environmental Science & Technology, Vol. 40, Issue 8 https://doi.org/10.1021/es052297c	journal	April 2006
Unexpected Epoxide Formation in the Gas-Phase Photooxidation of Isoprene Paulot, F.; Crounse, J. D.; Kjaergaard, H. G. Science, Vol. 325, Issue 5941 https://doi.org/10.1126/science.1172910	journal	August 2009

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secondary organic aerosol

Title: Molecular composition and volatility of isoprene photochemical oxidation secondary organic aerosol under low- and high-NO<sub><i>x</i></sub> conditions

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