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Title: Morphologically and size uniform monodisperse particles and their shape-directed self-assembly

Patent ·
OSTI ID:1390226

Monodisperse particles having: a single pure crystalline phase of a rare earth-containing lattice, a uniform three-dimensional size, and a uniform polyhedral morphology are disclosed. Due to their uniform size and shape, the monodisperse particles self assemble into superlattices. The particles may be luminescent particles such as down-converting phosphor particles and up-converting phosphors. The monodisperse particles of the invention have a rare earth-containing lattice which in one embodiment may be an yttrium-containing lattice or in another may be a lanthanide-containing lattice. The monodisperse particles may have different optical properties based on their composition, their size, and/or their morphology (or shape). Also disclosed is a combination of at least two types of monodisperse particles, where each type is a plurality of monodisperse particles having a single pure crystalline phase of a rare earth-containing lattice, a uniform three-dimensional size, and a uniform polyhedral morphology; and where the types of monodisperse particles differ from one another by composition, by size, or by morphology. In a preferred embodiment, the types of monodisperse particles have the same composition but different morphologies. Methods of making and methods of using the monodisperse particles are disclosed.

Research Organization:
INTELLIGENT MATERIAL SOLUTIONS, INC., Princeton, NJ (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
SC0002158
Assignee:
INTELLIGENT MATERIAL SOLUTIONS, INC.
Patent Number(s):
9,758,724
Application Number:
14/878,424
OSTI ID:
1390226
Resource Relation:
Patent File Date: 2015 Oct 08
Country of Publication:
United States
Language:
English

References (13)

Self-aligning QCA based nanomaterials patent February 2007
Lanthanide (III)—doped nanoparticles and their applications patent June 2009
Morphologically and size uniform monodisperse particles and their shape-directed self-assembly patent November 2015
Solvents and new method for the synthesis of cdse semiconductor nanocrystals patent-application September 2007
Lanthanide-Doped Nayf4 Nanocrystals, Method Of Preparing And Uses Thereof patent-application February 2009
Process For Producing Geometric Shaped Catalyst Bodies patent-application March 2010
Light Emitting Device Including Semiconductor Nanocrystals patent-application September 2010
Up And Down Conversion Systems For Production Of Emitted Light From Various Energy Sources patent-application October 2010
Ultrasmall Monodisperse NaYF4:Yb3+/Tm3+ Nanocrystals with Enhanced Near-Infrared to Near-Infrared Upconversion Photoluminescence journal May 2010
Comparative investigation on structure and luminescence properties of fluoride phosphors codoped with Er3+/Yb3+ journal October 2009
Optically active uniform potassium and lithium rare earth fluoride nanocrystals derived from metal trifluroacetate precursors journal January 2009
Controlled Synthesis and Luminescence of Lanthanide Doped NaYF4 Nanocrystals journal February 2007
Synthesis of Hexagonal-Phase NaYF4:Yb,Er and NaYF4:Yb,Tm Nanocrystals with Efficient Up-Conversion Fluorescence journal December 2006