Fast-responding bio-based shape memory thermoplastic polyurethanes

Petrovic, Zoran S.; Milic, Jelena; Zhang, Fan; Ilavsky, Jan

doi:10.1016/j.polymer.2017.05.072

Fast-responding bio-based shape memory thermoplastic polyurethanes

Journal Article · Wed May 31 00:00:00 EDT 2017 · Polymer

DOI:https://doi.org/10.1016/j.polymer.2017.05.072· OSTI ID:1389618

Petrovic, Zoran S. ^[1]; Milic, Jelena ^[1]; Zhang, Fan ^[2]; Ilavsky, Jan ^[3]

Pittsburg State Univ. Pittsburg, KS (United States)
National Inst. of Standards and Technology, Gaithersburg, MD (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)

Fast response shape-memory polyurethanes were prepared from bio-based polyols, diphenyl methane diisocyanate and butane diol. The bio-based polyester polyols were synthesized from 9-hydroxynonanoic acid, a product obtained by ozonolysis of fatty acids extracted from soy oil and castor oil. The morphology of polyurethanes was investigated by synchrotron ultra-small angle X-ray scattering, which revealed the inter-domain spacing between the hard and soft phases, the degree of phase separation, and the level of intermixing between the hard and soft phases. We also conducted thorough investigations of the thermal, mechanical, and dielectric properties of the polyurethanes, and found that high crystallization rate of the soft segment gives these polyurethanes unique properties suitable for shapememory applications, such as adjustable transition temperatures, high degree of elastic elongations, and good mechanical strength. In conclusion, these materials are also potentially biodegradable and biocompatible, therefore suitable for biomedical and environmental applications.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: Directorate for Mathematical and Physical Sciences Division of Chemistry (MPS/CHE); National Science Foundation (NSF), Directorate for Mathematical and Physical Sciences Division of Materials Research (MPS-DMR); U.S. Department of Agriculture (USDA); USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1389618

Alternate ID(s):: OSTI ID: 1550091

Journal Information:: Polymer, Journal Name: Polymer Journal Issue: C Vol. 121; ISSN 0032-3861

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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