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Diffusion-coupled cohesive interface simulations of stress corrosion intergranular cracking in polycrystalline materials

Journal Article · · Acta Materialia

To study the stress corrosion intergranular cracking mechanism, a diffusion-coupled cohesive zone model (CZM) is proposed for the simulation of the stress-assisted diffusional process along grain boundaries and the mechanical response of grain boundary sliding and separation. This simulation methodology considers the synergistic effects of impurity diffusion driven by pressure gradient and degradation of grain boundary strength by impurity concentration. The diffusion-coupled CZM is combined with crystal plasticity finite element model (CPFEM) to simulate intergranular fracture of polycrystalline material under corrosive environment. Significant heterogeneity of the stress field and extensive impurity accumulation is observed at grain boundaries and junction points. Deformation mechanism maps are constructed with respect to the grain boundary degradation factor and applied strain rate, which dictate the transition from internal to near-surface intergranular fracture modes under various strain amplitudes and grain sizes.

Research Organization:
Argonne National Laboratory (ANL)
Sponsoring Organization:
USDOE Office of Nuclear Energy (NE); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
DOE Contract Number:
AC02-06CH11357
OSTI ID:
1389308
Journal Information:
Acta Materialia, Journal Name: Acta Materialia Journal Issue: C Vol. 136; ISSN 1359-6454
Publisher:
Elsevier
Country of Publication:
United States
Language:
English

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