Ion-Exchange and Cation Solvation Reactions in Ti3C2 MXene

Ghidiu, Michael; Halim, Joseph; Kota, Sankalp; Bish, David; Gogotsi, Yury; Barsoum, Michel W.

doi:10.1021/acs.chemmater.6b01275

Title: Ion-Exchange and Cation Solvation Reactions in Ti₃C₂ MXene

Journal Article · Fri Apr 29 00:00:00 EDT 2016 · Chemistry of Materials

DOI:https://doi.org/10.1021/acs.chemmater.6b01275· OSTI ID:1388660

Ghidiu, Michael ^[1]; Halim, Joseph ^[2]; Kota, Sankalp ^[1]; Bish, David ^[3]; Gogotsi, Yury ^[1]; Barsoum, Michel W. ^[1]

Drexel Univ., Philadelphia, PA (United States)
Drexel Univ., Philadelphia, PA (United States); Linköping Univ. (Sweden)
Indiana Univ., Bloomington, IN (United States)

Ti₃C₂ and other two-dimensional transition metal carbides known as MXenes are currently being explored for many applications involving intercalated ions, from electrochemical energy storage, to contaminant sorption from water, to selected ion sieving. We report here a systematic investigation of ion exchange in Ti₃C₂ MXene and its hydration/dehydration behavior. We have investigated the effects of the presence of LiCl during the chemical etching of the MAX phase Ti₃AlC₂ into MXene Ti₃C₂T_x (T stands for surface termination) and found that the resulting MXene has Li⁺ cations in the interlayer space. We successfully exchanged the Li⁺ cations with K⁺, Na⁺, Rb⁺, Mg²⁺, and Ca²⁺ (supported by X-ray photoelectron and energy-dispersive spectroscopy) and found that the exchanged material expands on the unit-cell level in response to changes in humidity, with the nature of expansion dependent on the intercalated cation, similar to behavior of clay minerals; stepwise expansions of the basal spacing were observed, with changes consistent with the size of the H₂O molecule. Thermogravimetric analysis of the dehydration behavior of these materials shows that the amounts of H₂O contained at ambient humidity correlates simply with the hydration enthalpy of the intercalated cation, and that the diffusion of the exiting H₂O proceeds with kinetics similar to clays. Furthermore, these results have implications for understanding, controlling, and exploiting structural changes and H₂O sorption in MXene films and powders utilized in applications involving ions, such as electrochemical capacitors, sensors, reverse osmosis membranes, or contaminant sorbents.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: ERKCC61; DMR-1310245; 283036-3304; 621-2014-4890

OSTI ID:: 1388660

Journal Information:: Chemistry of Materials, Vol. 28, Issue 10; Related Information: FIRST partners with Oak Ridge National Laboratory (lead); Argonne National Laboratory; Drexel University; Georgia State University; Northwestern University; Pennsylvania State University; Suffolk University; Vanderbilt University; University of Virginia; ISSN 0897-4756

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 425 works

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References (34)

X-ray photoelectron spectroscopy of select multi-layered transition metal carbides (MXenes) Halim, Joseph; Cook, Kevin M.; Naguib, Michael Applied Surface Science, Vol. 362 https://doi.org/10.1016/j.apsusc.2015.11.089	journal	January 2016
Resolving the Structure of Ti ₃ C ₂ T _x MXenes through Multilevel Structural Modeling of the Atomic Pair Distribution Function Wang, Hsiu-Wen; Naguib, Michael; Page, Katharine Chemistry of Materials, Vol. 28, Issue 1 https://doi.org/10.1021/acs.chemmater.5b04250	journal	December 2015
Two-Dimensional Transition Metal Carbides Naguib, Michael; Mashtalir, Olha; Carle, Joshua ACS Nano, Vol. 6, Issue 2 https://doi.org/10.1021/nn204153h	journal	January 2012
25th Anniversary Article: MXenes: A New Family of Two-Dimensional Materials Naguib, Michael; Mochalin, Vadym N.; Barsoum, Michel W. Advanced Materials, Vol. 26, Issue 7, p. 992-1005 https://doi.org/10.1002/adma.201304138	journal	December 2013
Prediction and Characterization of MXene Nanosheet Anodes for Non-Lithium-Ion Batteries Xie, Yu; Dall’Agnese, Yohan; Naguib, Michael ACS Nano, Vol. 8, Issue 9 https://doi.org/10.1021/nn503921j	journal	August 2014
Charge- and Size-Selective Ion Sieving Through Ti ₃ C ₂ T _x MXene Membranes Ren, Chang E.; Hatzell, Kelsey B.; Alhabeb, Mohamed The Journal of Physical Chemistry Letters, Vol. 6, Issue 20 https://doi.org/10.1021/acs.jpclett.5b01895	journal	September 2015
Transparent Conductive Two-Dimensional Titanium Carbide Epitaxial Thin Films Halim, Joseph; Lukatskaya, Maria R.; Cook, Kevin M. Chemistry of Materials, Vol. 26, Issue 7 https://doi.org/10.1021/cm500641a	journal	March 2014
Prediction of Mobility, Enhanced Storage Capacity, and Volume Change during Sodiation on Interlayer-Expanded Functionalized Ti ₃ C ₂ MXene Anode Materials for Sodium-Ion Batteries Yu, Yang-Xin The Journal of Physical Chemistry C, Vol. 120, Issue 10 https://doi.org/10.1021/acs.jpcc.5b10366	journal	January 2016
Intercalation and delamination of layered carbides and carbonitrides Mashtalir, Olha; Naguib, Michael; Mochalin, Vadym N. Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms2664	journal	April 2013
Cation Intercalation and High Volumetric Capacitance of Two-Dimensional Titanium Carbide Lukatskaya, M. R.; Mashtalir, O.; Ren, C. E. Science, Vol. 341, Issue 6153 https://doi.org/10.1126/science.1241488	journal	September 2013
Solving the Capacitive Paradox of 2D MXene using Electrochemical Quartz-Crystal Admittance and In Situ Electronic Conductance Measurements Levi, Mikhael D.; Lukatskaya, Maria R.; Sigalov, Sergey Advanced Energy Materials, Vol. 5, Issue 1 https://doi.org/10.1002/aenm.201400815	journal	August 2014
Conductive two-dimensional titanium carbide ‘clay’ with high volumetric capacitance Ghidiu, Michael; Lukatskaya, Maria R.; Zhao, Meng-Qiang Nature, Vol. 516, Issue 7529 https://doi.org/10.1038/nature13970	journal	November 2014
Pseudocapacitance of MXene nanosheets for high-power sodium-ion hybrid capacitors Wang, Xianfen; Kajiyama, Satoshi; Iinuma, Hiroki Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7544	journal	April 2015
Two-Dimensional Titanium Carbide for Efficiently Reductive Removal of Highly Toxic Chromium(VI) from Water Ying, Yulong; Liu, Yu; Wang, Xinyu ACS Applied Materials & Interfaces, Vol. 7, Issue 3 https://doi.org/10.1021/am5074722	journal	January 2015
Unique Lead Adsorption Behavior of Activated Hydroxyl Group in Two-Dimensional Titanium Carbide Peng, Qiuming; Guo, Jianxin; Zhang, Qingrui Journal of the American Chemical Society, Vol. 136, Issue 11 https://doi.org/10.1021/ja500506k	journal	March 2014
High capacitance of surface-modified 2D titanium carbide in acidic electrolyte Dall'Agnese, Yohan; Lukatskaya, Maria R.; Cook, Kevin M. Electrochemistry Communications, Vol. 48 https://doi.org/10.1016/j.elecom.2014.09.002	journal	November 2014
Two-Dimensional Nanocrystals Produced by Exfoliation of Ti₃AlC₂ Naguib, Michael; Kurtoglu, Murat; Presser, Volker Advanced Materials, Vol. 23, Issue 37, p. 4248-4253 https://doi.org/10.1002/adma.201102306	journal	August 2011
Preparation of MXene-Cu2O nanocomposite and effect on thermal decomposition of ammonium perchlorate Gao, Yupeng; Wang, Libo; Li, Zhengyang Solid State Sciences, Vol. 35 https://doi.org/10.1016/j.solidstatesciences.2014.06.014	journal	September 2014
Porous Two-Dimensional Transition Metal Carbide (MXene) Flakes for High-Performance Li-Ion Storage Ren, Chang E.; Zhao, Meng-Qiang; Makaryan, Taron ChemElectroChem, Vol. 3, Issue 5 https://doi.org/10.1002/celc.201600059	journal	February 2016
High-Resolution X-Ray Photoemission from Sodium Metal and Its Hydroxide Citrin, P. H. Physical Review B, Vol. 8, Issue 12 https://doi.org/10.1103/PhysRevB.8.5545	journal	December 1973
A comparison of different spectrometers and charge corrections used in X-ray photoelectron spectroscopy Nefedov, V. I.; Salyn, Ya. V.; Leonhardt, G. Journal of Electron Spectroscopy and Related Phenomena, Vol. 10, Issue 2 https://doi.org/10.1016/0368-2048(77)85010-X	journal	January 1977
An Auger and X-ray photoelectron spectroscopic study of sodium metal and sodium oxide Barrie, A.; Street, F. J. Journal of Electron Spectroscopy and Related Phenomena, Vol. 7, Issue 1 https://doi.org/10.1016/0368-2048(75)80052-1	journal	January 1975
Near-infrared absorption properties of RbxWO3 nanoparticles Guo, Chongshen; Yin, Shu; Dong, Qiang CrystEngComm, Vol. 14, Issue 22 https://doi.org/10.1039/c2ce25460c	journal	January 2012
The swelling of montmorillonite Norrish, K. Discussions of the Faraday Society, Vol. 18 https://doi.org/10.1039/df9541800120	journal	January 1954
Hydration, expansion, structure, and dynamics of layered double hydroxides Hou, Xiaoqiang; Bish, David L.; Wang, Shan-Li American Mineralogist, Vol. 88, Issue 1 https://doi.org/10.2138/am-2003-0120	journal	January 2003
Synthesis and characterization of two-dimensional Nb ₄ C ₃ (MXene) Ghidiu, M.; Naguib, M.; Shi, C. Chem. Commun., Vol. 50, Issue 67 https://doi.org/10.1039/C4CC03366C	journal	January 2014
Solvation reactions of layered ternary sulfides AxTiS2, AxNbS2, and AxTaS2 Lerf, A.; Schoellhorn, R. Inorganic Chemistry, Vol. 16, Issue 11 https://doi.org/10.1021/ic50177a057	journal	November 1977
Hydration phase diagram for sodium cobalt oxide Na0.3CoO2·yH2O Foo, M. L.; Klimczuk, T.; Cava, R. J. Materials Research Bulletin, Vol. 40, Issue 4 https://doi.org/10.1016/j.materresbull.2005.01.001	journal	April 2005
Protonated pentatitanate: preparation, characterizations and cation intercalation Sasaki, Takayoshi; Komatsu, Yu; Fujiki, Yoshinori Chemistry of Materials, Vol. 4, Issue 4 https://doi.org/10.1021/cm00022a027	journal	July 1992
Controlled-Humidity Xrd Analyses: Application to the Study of Smectite Expansion/Contraction Chipera, Steve J.; William Carey, J.; Bish, David. L. Advances in X-Ray Analysis https://doi.org/10.1007/978-1-4615-5377-9_79	book	January 1997
A calorimetric study of mesoscopic swelling and hydration sequence in solid Na-montmorillonite Salles, Fabrice; Beurroies, Isabelle; Bildstein, Olivier Applied Clay Science, Vol. 39, Issue 3-4 https://doi.org/10.1016/j.clay.2007.06.001	journal	May 2008
Ambient temperature phase relations in the system if Johnston, David C. Materials Research Bulletin, Vol. 17, Issue 1 https://doi.org/10.1016/0025-5408(82)90177-5	journal	January 1982
Kinetics of dehydration of Ca-montmorillonite Bray, H. J.; Redfern, S. A. T. Physics and Chemistry of Minerals, Vol. 26, Issue 7 https://doi.org/10.1007/s002690050223	journal	August 1999
The hydrated intercalation complexes of the layered disulfides Whittingham, M. Stanley Materials Research Bulletin, Vol. 9, Issue 12 https://doi.org/10.1016/0025-5408(74)90162-7	journal	December 1974

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Title: Ion-Exchange and Cation Solvation Reactions in Ti3C2 MXene

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Title: Ion-Exchange and Cation Solvation Reactions in Ti₃C₂ MXene