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Title: Adsorption-enhanced hydrolysis of glucan oligomers into glucose over sulfonated three-dimensionally ordered mesoporous carbon catalysts

Journal Article · · Green Chemistry
DOI:https://doi.org/10.1039/c6gc02221a· OSTI ID:1388591
 [1];  [1];  [2];  [2];  [3];  [1]
  1. Department of Chemical Engineering; University of Massachusetts; Amherst; USA
  2. Department of Food Science; University of Massachusetts; Amherst; USA
  3. Department of Chemical Engineering and Materials Science; University of Minnesota; Minneapolis; USA

The hydrolysis of cellulose and β(1 → 4) oligosaccharides on carbon catalysts is a promising approach for the selective production of glucose from cellulose and its derivatives.

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Catalysis Center for Energy Innovation (CCEI)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
DOE Contract Number:
SC0001004
OSTI ID:
1388591
Journal Information:
Green Chemistry, Vol. 18, Issue 24; Related Information: CCEI partners with the University of Delaware (lead); Brookhaven National Laboratory; California Institute of Technology; Columbia University; University of Delaware; Lehigh University; University of Massachusetts, Amherst; Massachusetts Institute of Technology; University of Minnesota; Pacific Northwest National Laboratory; University of Pennsylvania; Princeton University; Rutgers University; ISSN 1463-9262
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

References (40)

Hierarchical nanofabrication of microporous crystals with ordered mesoporosity journal October 2008
Development of a single aptamer-based surface enhanced Raman scattering method for rapid detection of multiple pesticides journal January 2014
Production of dimethylfuran for liquid fuels from biomass-derived carbohydrates journal June 2007
Converting carbohydrates to bulk chemicals and fine chemicals over heterogeneous catalysts journal January 2011
Adsorption-Enhanced Hydrolysis of β-1,4-Glucan on Graphene-Based Amorphous Carbon Bearing SO 3 H, COOH, and OH Groups journal May 2009
Adsorption of the Compounds Encountered in Monosaccharide Dehydration in Zeolite Beta journal May 2013
Apparent molar volumes of aqueous cellobiose solutions
  • Herrington, Thelma M.; Pethybridge, Alan D.; Parkin, Brian A.
  • Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 79, Issue 4 https://doi.org/10.1039/f19837900845
journal January 1983
Amorphous Carbon with SO 3 H Groups as a Solid Brønsted Acid Catalyst journal May 2012
Direct Syntheses of Ordered SBA-15 Mesoporous Silica Containing Sulfonic Acid Groups journal August 2000
Catalytic Hydrolysis of Cellulose to Glucose Using Weak-Acid Surface Sites on Postsynthetically Modified Carbon journal November 2014
Glucan Adsorption on Mesoporous Carbon Nanoparticles: Effect of Chain Length and Internal Surface journal October 2012
Synthesis of Transportation Fuels from Biomass: Chemistry, Catalysts, and Engineering journal September 2006
Challenges of and Insights into Acid-Catalyzed Transformations of Sugars journal August 2014
Long-Chain Glucan Adsorption and Depolymerization in Zeolite-Templated Carbon Catalysts journal September 2015
Mechanocatalytic depolymerization of cellulose combined with hydrogenolysis as a highly efficient pathway to sugar alcohols journal January 2013
Sulfonated Ordered Mesoporous Carbon as a Stable and Highly Active Protonic Acid Catalyst journal May 2007
Solvent-Free Catalytic Depolymerization of Cellulose to Water-Soluble Oligosaccharides journal April 2012
Raman microspectroscopy of soot and related carbonaceous materials: Spectral analysis and structural information journal July 2005
Entropically Favored Adsorption of Cellulosic Molecules onto Carbon Materials through Hydrophobic Functionalities journal March 2014
Solid-fluid equilibrium in molecular models of n -alkanes journal January 1999
Raman spectroscopic characterization of carbonaceous aerosols journal January 2001
A reconsideration of the relationship between the crystallite size La of carbons determined by X-ray diffraction and Raman spectroscopy journal December 2006
Biomass Ethanol: Technical Progress, Opportunities, and Commercial Challenges journal November 1999
Adsorption of Glycols, Sugars, and Related Multiple −OH Compounds onto Activated Carbons. 2. Solvent Regeneration journal October 1999
Conversion of glucose into levulinic acid with solid metal(IV) phosphate catalysts journal August 2013
Significance of microporosity on the interaction of phenol with porous graphitic carbon journal June 2015
Some aspects of the surface chemistry of carbon blacks and other carbons journal January 1994
Hydrolysis Catalysis of Miscanthus Xylan to Xylose Using Weak-Acid Surface Sites journal December 2013
Acid Hydrolysis of Cellulose as the Entry Point into Biorefinery Schemes journal December 2009
Position-dependent diffusion coefficients and free energies from Bayesian analysis of equilibrium and replica molecular dynamics simulations journal January 2005
Phase Modifiers Promote Efficient Production of Hydroxymethylfurfural from Fructose journal June 2006
Effect of Temperature on Hydrophobic Interaction between Proteins and Hydrophobic Adsorbents: Studies by Isothermal Titration Calorimetry and the van't Hoff Equation journal October 2003
Efficient mechano-catalytic depolymerization of crystalline cellulose by formation of branched glucan chains journal January 2015
Origin of dispersive effects of the Raman D band in carbon materials journal March 1999
Preparation of a Carbon-Based Solid Acid Catalyst by Sulfonating Activated Carbon in a Chemical Reduction Process journal October 2010
Thermodynamic Properties of Aqueous Carbohydrate Solutions journal January 1997
Characterization of the Pore Structure of Three-Dimensionally Ordered Mesoporous Carbons Using High Resolution Gas Sorption journal August 2012
Impact of Oxygen-Containing Surface Functional Groups on Activated Carbon Adsorption of Phenols journal July 1997
Dehydration of fructose into furans over zeolite catalyst using carbon black as adsorbent journal June 2014
Quenched solid density functional theory and pore size analysis of micro-mesoporous carbons journal June 2009

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