Toward Inexpensive Photocatalytic Hydrogen Evolution: A Nickel Sulfide Catalyst Supported on a High-Stability Metal–Organic Framework

Peters, Aaron W.; Li, Zhanyong; Farha, Omar K.; Hupp, Joseph T.

doi:10.1021/acsami.6b04729

Title: Toward Inexpensive Photocatalytic Hydrogen Evolution: A Nickel Sulfide Catalyst Supported on a High-Stability Metal–Organic Framework

Journal Article · Wed Aug 03 00:00:00 EDT 2016 · ACS Applied Materials and Interfaces

DOI:https://doi.org/10.1021/acsami.6b04729· OSTI ID:1388232

Peters, Aaron W. ^[1]; Li, Zhanyong ^[1]; Farha, Omar K. ^[2]; Hupp, Joseph T. ^[1]

Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry
Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry; King Abdulaziz Univ., Jeddah (Saudi Arabia). Dept. of Chemistry

Few-atom clusters composed of nickel and sulfur have been successfully installed into the Zr(IV)-based metal–organic framework (MOF) NU-1000 via ALD-like chemistry (ALD = atomic layer deposition). Here, X-ray photoelectron spectroscopy and Raman spectroscopy are used to determine that primarily Ni²⁺ and S^2– sites are deposited within the MOF. In a pH 7 buffered aqueous solution, the porous catalyst is able to produce H₂ gas at a rate of 3.1 mmol g^–1 h^–1 upon UV irradiation, whereas no H₂ is generated by irradiating bare NU-1000. Upon visible light irradiation, little H₂ generation was observed; however, with the addition of an organic dye, rose bengal, NiS-AIM can catalyze the production of H₂ at an enhanced rate of 4.8 mmol g^–1 h^–1. These results indicate that ALD in MOFs (AIM) can engender reactivity within high surface area supports for applications in the solar fuels field.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Energy Frontier Research Center for Inorganometallic Catalyst Design (ICDC)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOD; National Science Foundation (NSF)

Grant/Contract Number:: SC0012702; DMR-1121262

OSTI ID:: 1388232

Journal Information:: ACS Applied Materials and Interfaces, Vol. 8, Issue 32; Related Information: ICDC partners with University of Minnesota(lead); Argonne National Laboratory; Clemson University; Dow Chemical Company; Northwestern University; Pacific Northwest National Laboratory; University of California Davis; University of Washington; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
catalysis (heterogeneous)
materials and chemistry by design
synthesis (novel materials)
metal−organic framework
nickel sulfide
hydrogen evolution
atomic layer deposition
photocatalysis

Title: Toward Inexpensive Photocatalytic Hydrogen Evolution: A Nickel Sulfide Catalyst Supported on a High-Stability Metal–Organic Framework

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