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A full set of iridium( iv ) pyridine-alkoxide stereoisomers: highly geometry-dependent redox properties

Journal Article · · Chemical Science
DOI:https://doi.org/10.1039/c6sc03758e· OSTI ID:1388146
 [1];  [2];  [3];  [4];  [2];  [2];  [2]
  1. Yale Univ., New Haven, CT (United States)
  2. Yale Univ., New Haven, CT (United States); Yale Univ., West Haven, CT (United States). Energy Sciences Inst.
  3. Yale Univ., New Haven, CT (United States); Consejo Superior de Investigaciones Cientificas (CSIC), Sevilla (Spain)
  4. Yale Univ., New Haven, CT (United States); Louisiana State Univ., Baton Rouge, LA (United States)
+ Show Author Affiliations

A complete series of Ir(iv) diastereomers coordinated with chlorides and bidentate pyridine-alkoxide ligands was prepared, revealing a number of significant unusual properties.

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Argonne-Northwestern Solar Energy Research Center (ANSER); Northwestern Univ., Evanston, IL (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Grant/Contract Number:
SC0001059
OSTI ID:
1388146
Journal Information:
Chemical Science, Journal Name: Chemical Science Journal Issue: 2 Vol. 8; ISSN 2041-6520; ISSN CSHCBM
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United States
Language:
English

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Cited By (10)

Synthesis and Characterization of Iridium(V) Coordination Complexes With an N,O-Donor Organic Ligand journal September 2017
Metalloradicals Supported by a meta ‐Carborane Ligand journal May 2019
Synthesis and Characterization of Iridium(V) Coordination Complexes With an N,O-Donor Organic Ligand journal September 2017
Metalloradicals Supported by a meta -Carborane Ligand journal May 2019
Electrochemical and Kinetic Insights into Molecular Water Oxidation Catalysts Derived from Cp*Ir(pyridine‐alkoxide) Complexes journal August 2018
N,N,O Pincer Ligand with a Deprotonatable Site That Promotes Redox-Leveling, High Mn Oxidation States, and a Mn 2 O 2 Dimer Competent for Catalytic Oxygen Evolution : N,N,O Pincer Ligand with a Deprotonatable Site That Promotes Redox-Leveling, High Mn Oxidation States, and a Mn2O2 Dimer Competent for Catalytic Oxyge journal January 2019
Synthesis of pyridine-alkoxide ligands for formation of polynuclear complexes journal January 2017
Stable iridium( iv ) complexes supported by tetradentate salen ligands. Synthesis, structures and reactivity journal January 2019
Synthesis and structural characterisation of unprecedented primary N -nitrosamines coordinated to iridium( iv ) journal January 2018
Novel iridium complexes with N-heterocyclic dicarbene ligands in light-driven water oxidation catalysis: photon management, ligand effect and catalyst evolution journal January 2020

Figures / Tables (13)

Scheme 1(p. 1)figure Scheme 1
Scheme 2(p. 2)figure Scheme 2
Fig. 1(p. 3)figure Fig. 1
Scheme 3(p. 4)figure Scheme 3
Table 1(p. 4)table Table 1
Fig. 2(p. 5)figure Fig. 2
Fig. 3(p. 6)figure Fig. 3
Table 2(p. 7)table Table 2
Table 3(p. 7)table Table 3
Fig. 4(p. 8)figure Fig. 4
Table 4(p. 8)table Table 4
Table 5(p. 8)table Table 5
Fig. 5(p. 9)figure Fig. 5

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