In Situ Synthesis of Highly Dispersed and Ultrafine Metal Nanoparticles from Chalcogels

Liu, Jian; He, Kai; Wu, Weiqiang; Song, Tze-Bin; Kanatzidis, Mercouri G.

doi:10.1021/jacs.6b13279

Title: In Situ Synthesis of Highly Dispersed and Ultrafine Metal Nanoparticles from Chalcogels

Journal Article · Wed Feb 15 00:00:00 EST 2017 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.6b13279· OSTI ID:1388134

^[1]; He, Kai ^[2]; Wu, Weiqiang ^[3]; Song, Tze-Bin ^[3];

^[4]

Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry, and Argonne-Northwestern Solar Energy Research Center
Northwestern Univ., Evanston, IL (United States). Dept. of Materials Science and Engineering
Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry
Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry, and Argonne-Northwestern Solar Energy Research Center, and Dept. of Materials Science and Engineering

We report a unique reaction type for facile synthesis of ultrafine and well-dispersed Pt nanoparticles supported on chalcogel surfaces. The nanoparticles are obtained by in-situ Pt²⁺ reduction of a chalcogel network formed by the metathesis reaction between K₂PtCl₄ and Na₄SnS₄. The rapid catalytic ability of the chalcogelsupported Pt nanoparticles is demonstrated in a recyclable manner by using 4-nitrophenol reduction as a probe reaction.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Argonne-Northwestern Solar Energy Research Center (ANSER)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0001059

OSTI ID:: 1388134

Journal Information:: Journal of the American Chemical Society, Vol. 139, Issue 8; Related Information: ANSER partners with Northwestern University (lead); Argonne National Laboratory; University of Chicago; University of Illinois, Urbana-Champaign; Yale University; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 61 works

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Title: In Situ Synthesis of Highly Dispersed and Ultrafine Metal Nanoparticles from Chalcogels

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