Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Origin of Pressure-induced Superconducting Phase in KxFe2-ySe2 studied by Synchrotron X-ray Diffraction and Spectroscopy

Journal Article · · Scientific Reports
DOI:https://doi.org/10.1038/srep30946· OSTI ID:1388077
 [1];  [2];  [3];  [4];  [5];  [3];  [6];  [7];  [7];  [7];  [8];  [8];  [8];  [8];  [1]
  1. Kwansei Gukuin Univ., Hyogo (Japan)
  2. RIKEN SPring-8 Center, Hyogo (Japan)
  3. National Institute for Materials Science, Ibaraki (Japan)
  4. National Institute for Materials Science, Ibaraki (Japan); Tohoku Univ., Miyagi (Japan)
  5. Kwansei Gukuin Univ., Hyogo (Japan); National Institute for Materials Science, Ibaraki (Japan)
  6. The Univ. of Texas at Austin, Austin, TX (United States); Center for High Pressure Science and Technology Advanced Research (HPSTAR), Shanghai (China)
  7. Osaka Univ., Osaka (Japan)
  8. National Synchrotron Radiation Research Center, Hsinchu (Taiwan)
Pressure dependence of the electronic and crystal structures of KxFe2–ySe2, which has pressure-induced two superconducting domes of SC I and SC II, was investigated by x-ray emission spectroscopy and diffraction. X-ray diffraction data show that compressibility along the c-axis changes around 12 GPa, where a new superconducting phase of SC II appears. This suggests a possible tetragonal to collapsed tetragonal phase transition. X-ray emission spectroscopy data also shows the change in the electronic structure around 12 GPa. These results can be explained by the scenario that the two SC domes under pressure originate from the change of Fermi surface topology. Lastly, our results here show the pronounced increase of the density of states near the Fermi surface under pressure with a structural phase transition, which can help address our fundamental understanding for the appearance of the SC II phase.
Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Energy Frontier Research in Extreme Environments (EFree)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Grant/Contract Number:
SC0001057
OSTI ID:
1388077
Journal Information:
Scientific Reports, Journal Name: Scientific Reports Journal Issue: 1 Vol. 6; ISSN 2045-2322
Publisher:
Nature Publishing GroupCopyright Statement
Country of Publication:
United States
Language:
English

References (49)

Iron-Based Layered Superconductor La[O 1- x F x ]FeAs ( x = 0.05−0.12) with T c = 26 K journal March 2008
Nodeless superconducting gap in AxFe2Se2 (A=K,Cs) revealed by angle-resolved photoemission spectroscopy journal February 2011
Observation of superconductivity at 30∼46K in AxFe2Se2(A = Li, Na, Ba, Sr, Ca, Yb and Eu) journal May 2012
Superconductivity in the PbO-type structure  -FeSe journal September 2008
Origin of pressure induced second superconducting dome in A y  Fe 2− x Se 2 [A = K, (Tl,Rb)] journal September 2013
Pressure dependence of superconductive transition temperature on K x Fe 2-y Se 2 journal March 2015
Elimination of the inner-shell lifetime broadening in x-ray-absorption spectroscopy journal November 1991
New Spectroscopy Solves an Old Puzzle: The Kondo Scale in Heavy Fermions journal April 2002
Colloquium : The unexpected properties of alkali metal iron selenide superconductors journal May 2013
High-Pressure Physics: The 1-Megabar Mark on the Ruby R1 Static Pressure Scale journal February 1976
The X-ray Non-diagram Lines K β' of Some Compounds of the Iron Group journal December 1959
Coexistence of superconductivity and antiferromagnetism in single crystals $A_{0.8}Fe_{2-y}Se_2$ (A= K, Rb, Cs, Tl/K and Tl/Rb): evidence from magnetization and resistivity text January 2011
Reemerging superconductivity at 48 K across quantum criticality in iron chalcogenides text January 2011
Phase Diagram and High Temperature Superconductivity at 65 K in Tuning Carrier Concentration of Single-Layer FeSe Films text January 2012
Spin-state transition in the Fe-pnictides text January 2012
Three dimensional spider-web-like superconducting filamentary paths in $K_xFe_{2-y}Se_2$ single crystals text January 2013
Probing the 3d Spin Momentum with X-ray Emission Spectroscopy:  The Case of Molecular-Spin Transitions journal June 2006
Re-emerging superconductivity at 48 kelvin in iron chalcogenides journal February 2012
Influence of microstructure on superconductivity in KxFe2−ySe2 and evidence for a new parent phase K2Fe7Se8 journal May 2013
Phase diagram and electronic indication of high-temperature superconductivity at 65 K in single-layer FeSe films journal May 2013
Superconductivity above 100 K in single-layer FeSe films on doped SrTiO3 journal November 2014
Phase separation and magnetic order in K-doped iron selenide superconductor journal November 2011
Spectromicroscopy of electronic phase separation in KxFe2−ySe2 superconductor journal July 2014
Conventional empirical law reverses in the phase transitions of 122-type iron-based superconductors journal November 2014
Two-dimensional detector software: From real detector to idealised image or two-theta scan journal January 1996
A Novel Large Moment Antiferromagnetic Order in K 0.8 Fe 1.6 Se 2 Superconductor journal August 2011
Evolution of superconductivity in isovalent Te-substituted K x Fe 2− y Se 2 crystals journal March 2013
The 1s x-ray absorption pre-edge structures in transition metal oxides journal February 2009
Superconductivity in the iron selenide K x Fe 2 Se 2 ( 0 ≤ x ≤ 1.0 ) journal November 2010
Revealing the dual nature of magnetism in iron pnictides and iron chalcogenides using x-ray emission spectroscopy journal September 2011
Pressure dependence of the electronic structure and spin state in Fe 1.01 Se superconductors probed by x-ray absorption and x-ray emission spectroscopy journal September 2011
Coexistence of different electronic phases in the K 0.8 Fe 1.6 Se 2 superconductor: A bulk-sensitive hard x-ray spectroscopy study journal June 2012
Interplay of electronic and lattice degrees of freedom in A 1 − x Fe 2 − y Se 2 superconductors under pressure journal November 2013
Role of the 245 phase in alkaline iron selenide superconductors revealed by high-pressure studies journal March 2014
X-ray absorption and photoemission spectroscopy of electronic phase separation in K x Fe 2 − y Se 2 journal November 2014
Direct observation of nanoscale interface phase in the superconducting chalcogenide K x Fe 2 − y Se 2 with intrinsic phase separation journal January 2015
High-temperature superconductivity stabilized by electron-hole interband coupling in collapsed tetragonal phase of KFe 2 As 2 under high pressure journal February 2015
Origin of the superconducting state in the collapsed tetragonal phase of KFe 2 As 2 journal April 2015
Common Crystalline and Magnetic Structure of Superconducting A 2 Fe 4 Se 5 ( A = K , Rb , Cs , Tl ) Single Crystals Measured Using Neutron Diffraction journal September 2011
Pressure-Driven Quantum Criticality in Iron-Selenide Superconductors journal May 2012
Spin-State Transition in the Fe Pnictides journal January 2013
Role of Valence Fluctuations in the Superconductivity of Ce122 Compounds journal August 2014
Elimination of the inner-shell lifetime broadening in x-ray-absorption spectroscopy journal November 1991
New Spectroscopy Solves an Old Puzzle: The Kondo Scale in Heavy Fermions journal April 2002
Electronic Identification of the Parental Phases and Mesoscopic Phase Separation of K x Fe 2 − y Se 2 Superconductors journal December 2011
Colloquium : The unexpected properties of alkali metal iron selenide superconductors journal May 2013
The X-ray Non-diagram Lines K β' of Some Compounds of the Iron Group journal December 1959
Coexistence of superconductivity and antiferromagnetism in single crystals A 0.8 Fe 2−y Se 2 (A=K, Rb, Cs, Tl/K and Tl/Rb): Evidence from magnetization and resistivity journal April 2011
Origin of the Higher- T c Phase in the K x Fe 2− y Se 2 System journal April 2016

Cited By (1)

Reciprocity between local moments and collective magnetic excitations in the phase diagram of BaFe2(As1−xPx)2 journal November 2019