Comparison of heterogenized molecular and heterogeneous oxide catalysts for photoelectrochemical water oxidation †

Li, Wei; He, Da; Sheehan, Stafford W.; He, Yumin; Thorne, James E.; Yao, Xiahui; Brudvig, Gary W.; Wang, Dunwei

doi:10.1039/C5EE03871E

Title: Comparison of heterogenized molecular and heterogeneous oxide catalysts for photoelectrochemical water oxidation †

Journal Article · Fri Jan 01 00:00:00 EST 2016 · Energy & Environmental Science

DOI:https://doi.org/10.1039/C5EE03871E· OSTI ID:1387675

Li, Wei ^[1]; He, Da ^[1]; Sheehan, Stafford W. ^[2]; He, Yumin ^[1]; Thorne, James E. ^[1]; Yao, Xiahui ^[1]; Brudvig, Gary W. ^[3]; Wang, Dunwei ^[1]

Department of Chemistry; Merkert Chemistry Center; Boston College; USA 02467
Catalytic Innovations LLC; Rhode Island; USA 02801
Department of Chemistry; Yale University; New Haven; USA 06520

Molecular and heterogeneous water oxidation catalysts improve the performance of hematite as a photoanodeviafundamentally different mechanisms.

Cite

Export

Save

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Argonne-Northwestern Solar Energy Research Center (ANSER)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: SC0001059

OSTI ID:: 1387675

Journal Information:: Energy & Environmental Science, Vol. 9, Issue 5; Related Information: ANSER partners with Northwestern University (lead); Argonne National Laboratory; University of Chicago; University of Illinois, Urbana-Champaign; Yale University; ISSN 1754-5692

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

References (70)

Light-driven water oxidation for solar fuels Young, Karin J.; Martini, Lauren A.; Milot, Rebecca L. Coordination Chemistry Reviews, Vol. 256, Issue 21-22 https://doi.org/10.1016/j.ccr.2012.03.031	journal	November 2012
Energetics at the Surface of Photoelectrodes and Its Influence on the Photoelectrochemical Properties Thorne, James E.; Li, Song; Du, Chun The Journal of Physical Chemistry Letters, Vol. 6, Issue 20 https://doi.org/10.1021/acs.jpclett.5b01372	journal	September 2015
Benchmarking Hydrogen Evolving Reaction and Oxygen Evolving Reaction Electrocatalysts for Solar Water Splitting Devices McCrory, Charles C. L.; Jung, Suho; Ferrer, Ivonne M. Journal of the American Chemical Society, Vol. 137, Issue 13 https://doi.org/10.1021/ja510442p	journal	March 2015
Photoelectrochemical cells Grätzel, Michael Nature, Vol. 414, Issue 6861 https://doi.org/10.1038/35104607	journal	November 2001
Design and development of photoanodes for water-splitting dye-sensitized photoelectrochemical cells Swierk, John R.; Mallouk, Thomas E. Chem. Soc. Rev., Vol. 42, Issue 6 https://doi.org/10.1039/C2CS35246J	journal	January 2013
Adaptive semiconductor/electrocatalyst junctions in water-splitting photoanodes Lin, Fuding; Boettcher, Shannon W. Nature Materials, Vol. 13, Issue 1 https://doi.org/10.1038/nmat3811	journal	December 2013
Electrochemical Photolysis of Water at a Semiconductor Electrode Fujishima, Akira; Honda, Kenichi Nature, Vol. 238, Issue 5358, p. 37-38 https://doi.org/10.1038/238037a0	journal	July 1972
Photooxidation of Water at α-Fe[sub 2]O[sub 3] Electrodes Kennedy, John H. Journal of The Electrochemical Society, Vol. 125, Issue 5 https://doi.org/10.1149/1.2131532	journal	January 1978
Light-Induced Water Splitting with Hematite: Improved Nanostructure and Iridium Oxide Catalysis Tilley, S. David; Cornuz, Maurin; Sivula, Kevin Angewandte Chemie International Edition, Vol. 49, Issue 36 https://doi.org/10.1002/anie.201003110	journal	July 2010
A monolithic device for CO ₂ photoreduction to generate liquid organic substances in a single-compartment reactor Arai, Takeo; Sato, Shunsuke; Morikawa, Takeshi Energy & Environmental Science, Vol. 8, Issue 7 https://doi.org/10.1039/C5EE01314C	journal	January 2015
Powering the planet: Chemical challenges in solar energy utilization Lewis, N. S.; Nocera, D. G. Proceedings of the National Academy of Sciences, Vol. 103, Issue 43, p. 15729-15735 https://doi.org/10.1073/pnas.0603395103	journal	October 2006
Water Oxidation on Hematite Photoelectrodes: Insight into the Nature of Surface States through In Situ Spectroelectrochemistry Klahr, Benjamin; Hamann, Thomas The Journal of Physical Chemistry C, Vol. 118, Issue 19 https://doi.org/10.1021/jp500543z	journal	May 2014
A Study of the Photoanodic Dissolution of CdS with Electrical and Opto-electrical Impedance Spectroscopy de Wit, A. R. Journal of The Electrochemical Society, Vol. 139, Issue 9 https://doi.org/10.1149/1.2221254	journal	January 1992
Toward Settling the Debate on the Role of Fe ₂ O ₃ Surface States for Water Splitting Yatom, Natav; Neufeld, Ofer; Caspary Toroker, Maytal The Journal of Physical Chemistry C, Vol. 119, Issue 44 https://doi.org/10.1021/acs.jpcc.5b06128	journal	October 2015
Equivalent Circuit of Electrons and Holes in Thin Semiconductor Films for Photoelectrochemical Water Splitting Applications Bertoluzzi, Luca; Bisquert, Juan The Journal of Physical Chemistry Letters, Vol. 3, Issue 17 https://doi.org/10.1021/jz3010909	journal	August 2012
Artificial Photosynthesis: Solar Splitting of Water to Hydrogen and Oxygen Bard, Allen J.; Fox, Marye Anne Accounts of Chemical Research, Vol. 28, Issue 3 https://doi.org/10.1021/ar00051a007	journal	March 1995
Probing the Viability of Oxo-Coupling Pathways in Iridium-Catalyzed Oxygen Evolution Graeupner, Jonathan; Hintermair, Ulrich; Huang, Daria L. Organometallics, Vol. 32, Issue 19 https://doi.org/10.1021/om400658a	journal	September 2013
Water Oxidation at Hematite Photoelectrodes with an Iridium-Based Catalyst Badia-Bou, Laura; Mas-Marza, Elena; Rodenas, Pau The Journal of Physical Chemistry C, Vol. 117, Issue 8 https://doi.org/10.1021/jp311983n	journal	February 2013
New iridium(III) organometallic complexes bearing strong electron donating bidentate ligands as catalysts for water oxidation Savini, Arianna; Bucci, Alberto; Bellachioma, Gianfranco Journal of Organometallic Chemistry, Vol. 771 https://doi.org/10.1016/j.jorganchem.2014.05.029	journal	November 2014
Recent advances in semiconductors for photocatalytic and photoelectrochemical water splitting Hisatomi, Takashi; Kubota, Jun; Domen, Kazunari Chem. Soc. Rev., Vol. 43, Issue 22 https://doi.org/10.1039/C3CS60378D	journal	January 2014
Competitive Photoelectrochemical Methanol and Water Oxidation with Hematite Electrodes Klahr, Benjamin; Gimenez, Sixto; Zandi, Omid ACS Applied Materials & Interfaces, Vol. 7, Issue 14 https://doi.org/10.1021/acsami.5b00440	journal	April 2015
Water Oxidation at Hematite Photoelectrodes: The Role of Surface States Klahr, Benjamin; Gimenez, Sixto; Fabregat-Santiago, Francisco Journal of the American Chemical Society, Vol. 134, Issue 9 https://doi.org/10.1021/ja210755h	journal	February 2012
Understanding the Role of Underlayers and Overlayers in Thin Film Hematite Photoanodes Steier, Ludmilla; Herraiz-Cardona, Isaac; Gimenez, Sixto Advanced Functional Materials, Vol. 24, Issue 48 https://doi.org/10.1002/adfm.201402742	journal	October 2014
Intensity-modulated photocurrent spectroscopy: reconciliation of phenomenological analysis with multistep electron transfer mechanisms Peter, L. M.; Ponomarev, E. A.; Fermín, D. J. Journal of Electroanalytical Chemistry, Vol. 427, Issue 1-2 https://doi.org/10.1016/S0022-0728(96)05033-4	journal	April 1997
Solar Water Splitting Cells Walter, Michael G.; Warren, Emily L.; McKone, James R. Chemical Reviews, Vol. 110, Issue 11, p. 6446-6473 https://doi.org/10.1021/cr1002326	journal	November 2010
Light-induced water oxidation at silicon electrodes functionalized with a cobalt oxygen-evolving catalyst Pijpers, J. J. H.; Winkler, M. T.; Surendranath, Y. Proceedings of the National Academy of Sciences, Vol. 108, Issue 25 https://doi.org/10.1073/pnas.1106545108	journal	June 2011
Tunable, light-assisted co-generation of CO and H ₂ from CO ₂ and H2O by Re(bipy-tbu)(CO) ₃ Cl and p-Si in non-aqueous medium Kumar, Bhupendra; Smieja, Jonathan M.; Sasayama, Alissa F. Chem. Commun., Vol. 48, Issue 2 https://doi.org/10.1039/C1CC16024A	journal	January 2012
New Insights into Water Splitting at Mesoporous α-Fe ₂ O ₃ Films: A Study by Modulated Transmittance and Impedance Spectroscopies Cummings, Charles Y.; Marken, Frank; Peter, Laurence M. Journal of the American Chemical Society, Vol. 134, Issue 2 https://doi.org/10.1021/ja209530s	journal	December 2011
Kinetic Isotope Effects in the Study of Organometallic Reaction Mechanisms Gómez-Gallego, Mar; Sierra, Miguel A. Chemical Reviews, Vol. 111, Issue 8 https://doi.org/10.1021/cr100436k	journal	August 2011
Molecular Chromophore–Catalyst Assemblies for Solar Fuel Applications Ashford, Dennis L.; Gish, Melissa K.; Vannucci, Aaron K. Chemical Reviews, Vol. 115, Issue 23 https://doi.org/10.1021/acs.chemrev.5b00229	journal	August 2015
A molecular catalyst for water oxidation that binds to metal oxide surfaces Sheehan, Stafford W.; Thomsen, Julianne M.; Hintermair, Ulrich Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7469	journal	March 2015
Photofunctional Construct That Interfaces Molecular Cobalt-Based Catalysts for H ₂ Production to a Visible-Light-Absorbing Semiconductor Krawicz, Alexandra; Yang, Jinhui; Anzenberg, Eitan Journal of the American Chemical Society, Vol. 135, Issue 32 https://doi.org/10.1021/ja404158r	journal	July 2013
A comparison of intensity modulated photocurrent spectroscopy and photoelectrochemical impedance spectroscopy in a study of photoelectrochemical hydrogen evolution at p-InP Ponomarev, E. A.; Peter, L. M. Journal of Electroanalytical Chemistry, Vol. 397, Issue 1-2 https://doi.org/10.1016/0022-0728(95)04148-9	journal	November 1995
Immobilization of a Molecular Ruthenium Catalyst on Hematite Nanorod Arrays for Water Oxidation with Stable Photocurrent Fan, Ke; Li, Fusheng; Wang, Lei ChemSusChem, Vol. 8, Issue 19 https://doi.org/10.1002/cssc.201500730	journal	August 2015
Kinetics of light-driven oxygen evolution at α-Fe ₂ O ₃ electrodes Peter, Laurence M.; Wijayantha, K. G. Upul; Tahir, Asif A. Faraday Discuss., Vol. 155 https://doi.org/10.1039/C1FD00079A	journal	January 2012
Kinetics of Electron Transfer and Oxygen Evolution in the Reaction of [Ru(bpy) ₃ ] ³⁺ with Colloidal Iridium Oxide Morris, Natalie D.; Suzuki, Masahiro; Mallouk, Thomas E. The Journal of Physical Chemistry A, Vol. 108, Issue 42 https://doi.org/10.1021/jp0480145	journal	October 2004
Hematite-Based Water Splitting with Low Turn-On Voltages Du, Chun; Yang, Xiaogang; Mayer, Matthew T. Angewandte Chemie International Edition, Vol. 52, Issue 48 https://doi.org/10.1002/anie.201306263	journal	October 2013
Kinetics of oxygen evolution at α-Fe2O3 photoanodes: a study by photoelectrochemical impedance spectroscopy Upul Wijayantha, K. G.; Saremi-Yarahmadi, Sina; Peter, Laurence M. Physical Chemistry Chemical Physics, Vol. 13, Issue 12 https://doi.org/10.1039/c0cp02408b	journal	January 2011
Activation Energies for the Rate-Limiting Step in Water Photooxidation by Nanostructured α-Fe ₂ O ₃ and TiO ₂ Cowan, Alexander J.; Barnett, Christopher J.; Pendlebury, Stephanie R. Journal of the American Chemical Society, Vol. 133, Issue 26 https://doi.org/10.1021/ja200800t	journal	July 2011
Mechanistic Aspects of Water Oxidation Catalyzed by Organometallic Iridium Complexes: Water Oxidation Catalyzed by Organometallic Ir Complexes Savini, Arianna; Bucci, Alberto; Bellachioma, Gianfranco European Journal of Inorganic Chemistry, Vol. 2014, Issue 4 https://doi.org/10.1002/ejic.201300530	journal	July 2013
Solar Water Splitting Combining a BiVO ₄ Light Absorber with a Ru-Based Molecular Cocatalyst de Respinis, Moreno; Joya, Khurram S.; De Groot, Huub J. M. The Journal of Physical Chemistry C, Vol. 119, Issue 13 https://doi.org/10.1021/acs.jpcc.5b00287	journal	March 2015
Photoassisted Overall Water Splitting in a Visible Light-Absorbing Dye-Sensitized Photoelectrochemical Cell Youngblood, W. Justin; Lee, Seung-Hyun Anna; Kobayashi, Yoji Journal of the American Chemical Society, Vol. 131, Issue 3, p. 926-927 https://doi.org/10.1021/ja809108y	journal	January 2009
A Noble-Metal-Free Hydrogen Evolution Catalyst Grafted to Visible Light-Absorbing Semiconductors Moore, Gary F.; Sharp, Ian D. The Journal of Physical Chemistry Letters, Vol. 4, Issue 4 https://doi.org/10.1021/jz400028z	journal	January 2013
Photoinduced Stepwise Oxidative Activation of a Chromophore–Catalyst Assembly on TiO ₂ Song, Wenjing; Glasson, Christopher R. K.; Luo, Hanlin The Journal of Physical Chemistry Letters, Vol. 2, Issue 14 https://doi.org/10.1021/jz200773r	journal	June 2011
Structural, Physicochemical, and Reactivity Properties of an All-Inorganic, Highly Active Tetraruthenium Homogeneous Catalyst for Water Oxidation Geletii, Yurii V.; Besson, Claire; Hou, Yu Journal of the American Chemical Society, Vol. 131, Issue 47 https://doi.org/10.1021/ja907277b	journal	December 2009
The Role of Cobalt Phosphate in Enhancing the Photocatalytic Activity of α-Fe ₂ O ₃ toward Water Oxidation Barroso, Monica; Cowan, Alexander J.; Pendlebury, Stephanie R. Journal of the American Chemical Society, Vol. 133, Issue 38 https://doi.org/10.1021/ja205325v	journal	September 2011
Photoelectrochemical CO ₂ reduction using a Ru( ii )–Re( i ) multinuclear metal complex on a p-type semiconducting NiO electrode Sahara, Go; Abe, Ryu; Higashi, Masanobu Chemical Communications, Vol. 51, Issue 53 https://doi.org/10.1039/C5CC02403J	journal	January 2015
Electrochemical Synthesis of Photoelectrodes and Catalysts for Use in Solar Water Splitting Kang, Donghyeon; Kim, Tae Woo; Kubota, Stephen R. Chemical Reviews, Vol. 115, Issue 23 https://doi.org/10.1021/acs.chemrev.5b00498	journal	August 2015
Rate Law Analysis of Water Oxidation on a Hematite Surface Le Formal, Florian; Pastor, Ernest; Tilley, S. David Journal of the American Chemical Society, Vol. 137, Issue 20 https://doi.org/10.1021/jacs.5b02576	journal	May 2015
Photoelectrochemical and Impedance Spectroscopic Investigation of Water Oxidation with “Co–Pi”-Coated Hematite Electrodes Klahr, Benjamin; Gimenez, Sixto; Fabregat-Santiago, Francisco Journal of the American Chemical Society, Vol. 134, Issue 40 https://doi.org/10.1021/ja306427f	journal	September 2012
Hematite-Based Solar Water Splitting in Acidic Solutions: Functionalization by Mono- and Multilayers of Iridium Oxygen-Evolution Catalysts Li, Wei; Sheehan, Stafford W.; He, Da Angewandte Chemie International Edition, Vol. 54, Issue 39 https://doi.org/10.1002/anie.201504427	journal	July 2015
Anchoring a Molecular Iron Catalyst to Solar-Responsive WO ₃ Improves the Rate and Selectivity of Photoelectrochemical Water Oxidation Klepser, Benjamin M.; Bartlett, Bart M. Journal of the American Chemical Society, Vol. 136, Issue 5 https://doi.org/10.1021/ja4086808	journal	January 2014
Photoelectrochemical operation of a surface-bound, nickel-phosphine H ₂ evolution catalyst on p-Si(111): a molecular semiconductor\|catalyst construct Seo, Junhyeok; Pekarek, Ryan T.; Rose, Michael J. Chemical Communications, Vol. 51, Issue 68 https://doi.org/10.1039/C5CC02802G	journal	January 2015
A generalized theory of intensity modulated photocurrent spectroscopy (IMPS) Ponomarev, E. A.; Peter, L. M. Journal of Electroanalytical Chemistry, Vol. 396, Issue 1-2 https://doi.org/10.1016/0022-0728(95)04115-5	journal	October 1995
Stable Iridium(IV) Complexes of an Oxidation-Resistant Pyridine-Alkoxide Ligand: Highly Divergent Redox Properties Depending on the Isomeric Form Adopted Shopov, Dimitar Y.; Rudshteyn, Benjamin; Campos, Jesús Journal of the American Chemical Society, Vol. 137, Issue 22 https://doi.org/10.1021/jacs.5b04185	journal	June 2015
Enabling unassisted solar water splitting by iron oxide and silicon Jang, Ji-Wook; Du, Chun; Ye, Yifan Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8447	journal	June 2015
A Monolithic Photovoltaic-Photoelectrochemical Device for Hydrogen Production via Water Splitting Khaselev, O. Science, Vol. 280, Issue 5362 https://doi.org/10.1126/science.280.5362.425	journal	April 1998
Photoelectrochemical Water Oxidation by Cobalt Catalyst (“Co−Pi”)/α-Fe ₂ O ₃ Composite Photoanodes: Oxygen Evolution and Resolution of a Kinetic Bottleneck Zhong, Diane K.; Gamelin, Daniel R. Journal of the American Chemical Society, Vol. 132, Issue 12 https://doi.org/10.1021/ja908730h	journal	March 2010
The Role of Surface States in the Oxygen Evolution Reaction on Hematite Iandolo, Beniamino; Hellman, Anders Angewandte Chemie, Vol. 126, Issue 49 https://doi.org/10.1002/ange.201406800	journal	October 2014
Development of Molecular Electrocatalysts for CO₂ Reduction and H₂ Production/Oxidation Rakowski Dubois, M.; Dubois, Daniel L. Accounts of Chemical Research, Vol. 42, Issue 12, p. 1974-1982 https://doi.org/10.1021/ar900110c	journal	December 2009
Comparison of Amorphous Iridium Water-Oxidation Electrocatalysts Prepared from Soluble Precursors Blakemore, James D.; Schley, Nathan D.; Kushner-Lenhoff, Maxwell N. Inorganic Chemistry, Vol. 51, Issue 14 https://doi.org/10.1021/ic300764f	journal	April 2012
Electrocatalytic and homogeneous approaches to conversion of CO ₂ to liquid fuels Benson, Eric E.; Kubiak, Clifford P.; Sathrum, Aaron J. Chem. Soc. Rev., Vol. 38, Issue 1 https://doi.org/10.1039/B804323J	journal	January 2009
Atomic Layer Deposition of a Submonolayer Catalyst for the Enhanced Photoelectrochemical Performance of Water Oxidation with Hematite Riha, Shannon C.; Klahr, Benjamin M.; Tyo, Eric C. ACS Nano, Vol. 7, Issue 3 https://doi.org/10.1021/nn305639z	journal	February 2013
Observation and Alteration of Surface States of Hematite Photoelectrodes Du, Chun; Zhang, Ming; Jang, Ji-Wook The Journal of Physical Chemistry C, Vol. 118, Issue 30 https://doi.org/10.1021/jp5006346	journal	April 2014
Dynamics of photogenerated holes in surface modified -Fe2O3 photoanodes for solar water splitting Barroso, M.; Mesa, C. A.; Pendlebury, S. R. Proceedings of the National Academy of Sciences, Vol. 109, Issue 39 https://doi.org/10.1073/pnas.1118326109	journal	July 2012
Kinetics and mechanism of light-driven oxygen evolution at thin film α-Fe2O3 electrodes Cummings, Charles Y.; Marken, Frank; Peter, Laurence M. Chemical Communications, Vol. 48, Issue 14 https://doi.org/10.1039/c2cc16382a	journal	January 2012
Anodic deposition of a robust iridium-based water-oxidation catalyst from organometallic precursors Blakemore, James D.; Schley, Nathan D.; Olack, Gerard W. Chem. Sci., Vol. 2, Issue 1 https://doi.org/10.1039/C0SC00418A	journal	January 2011
Molecular Approaches to the Photocatalytic Reduction of Carbon Dioxide for Solar Fuels Morris, Amanda J.; Meyer, Gerald J.; Fujita, Etsuko Accounts of Chemical Research, Vol. 42, Issue 12 https://doi.org/10.1021/ar9001679	journal	December 2009
Molecular Catalysts for Water Oxidation Blakemore, James D.; Crabtree, Robert H.; Brudvig, Gary W. Chemical Reviews, Vol. 115, Issue 23 https://doi.org/10.1021/acs.chemrev.5b00122	journal	July 2015
Dynamic aspects of semiconductor photoelectrochemistry Peter, Lawrence M. Chemical Reviews, Vol. 90, Issue 5 https://doi.org/10.1021/cr00103a005	journal	July 1990

Similar Records

A Molecular Silane-Derivatized Ru(II) Catalyst for Photoelectrochemical Water Oxidation

Journal Article · Tue Oct 16 00:00:00 EDT 2018 · Journal of the American Chemical Society · OSTI ID:1387675

Wu, Lei; Eberhart, Michael; Nayak, Animesh; +3 more

Modulating Charge Transfer Efficiency of Hematite Photoanode with Hybrid Dual‐Metal–Organic Frameworks for Boosting Photoelectrochemical Water Oxidation

Journal Article · Sun Oct 25 00:00:00 EDT 2020 · Advanced Science · OSTI ID:1387675

Wang, Keke; Liu, Yang; Kawashima, Kenta; +8 more

Optimization of Photoanodes for Photocatalytic Water Oxidation by Combining a Heterogenized Iridium Water‐Oxidation Catalyst with a High‐Potential Porphyrin Photosensitizer

Journal Article · Mon Oct 23 00:00:00 EDT 2017 · ChemSusChem · OSTI ID:1387675

Materna, Kelly L.; Jiang, Jianbing; Regan, Kevin P.; +3 more

Related Subjects

catalysis (homogeneous)
catalysis (heterogeneous)
solar (photovoltaic)
solar (fuels)
photosynthesis (natural and artificial)
bio-inspired
hydrogen and fuel cells
electrodes - solar
defects
charge transport
spin dynamics
membrane
materials and chemistry by design
optics
synthesis (novel materials)
synthesis (self-assembly)

Title: Comparison of heterogenized molecular and heterogeneous oxide catalysts for photoelectrochemical water oxidation †

Citation Formats

References (70)

Similar Records

Related Subjects