Crystal engineering on superpolyhedral building blocks in metal–organic frameworks applied in gas adsorption

Chen, Ying-Pin; Liu, Tian-Fu; Fordham, Stephen; Zhou, Hong-Cai

doi:10.1107/S205252061501584X

Crystal engineering on superpolyhedral building blocks in metal–organic frameworks applied in gas adsorption

Journal Article · Sat Nov 07 04:00:00 EST 2015 · Acta Crystallographica. Section B, Structural Science, Crystal Engineering and Materials (Online)

DOI:https://doi.org/10.1107/S205252061501584X· OSTI ID:1387386

Chen, Ying-Pin; Liu, Tian-Fu; Fordham, Stephen; Zhou, Hong-Cai

Two metal–organic frameworks [PCN-426(Ni) and PCN-427(Cu)] have been designed and synthesized to investigate the structure predictability using a SBB (supermolecular building blocks) approach. Tetratopic ligands featuring 120° angular carboxylate moieties were coordinated with a [Ni₃(μ₃-O)] cluster and a [Cu₂O₂] unit, respectively. As topologically predicted, 4-connected networks with square coordination adopted thenbonet for the Ni-MOF andssbnet for the Cu-MOF. PCN-426(Ni) was augmented with 12-connected octahedral SBBs, while PCN-427(Cu) was constructed with tetragonal open channels. After a CO₂supercritical drying procedure, the PCN-426(Ni) possessed a Brunauer–Emmett–Teller (BET) surface area as high as 3935 m²g^-1and impressively high N₂ uptake of 1500 cm³ g^-1. This work demonstrates the generalization of the SBB strategy, finding an alternative to inconvenient synthetic processes to achieve the desired structural features.

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS)

Sponsoring Organization:: USDOE SC Office of Basic Energy Sciences (SC-22)

DOE Contract Number:: SC0001015

OSTI ID:: 1387386

Journal Information:: Acta Crystallographica. Section B, Structural Science, Crystal Engineering and Materials (Online), Journal Name: Acta Crystallographica. Section B, Structural Science, Crystal Engineering and Materials (Online) Journal Issue: 6 Vol. 71; ISSN ACSBDA; ISSN 2052-5206

Publisher:: International Union of Crystallography

Country of Publication:: United States

Language:: English

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Crystal engineering on superpolyhedral building blocks in metal–organic frameworks applied in gas adsorption

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References (19)

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