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Title: Emergence of room-temperature ferroelectricity at reduced dimensions

Authors:
; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ;
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Center for the Computational Design of Functional Layered Materials (CCDM)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1387363
DOE Contract Number:  
SC0012575
Resource Type:
Journal Article
Journal Name:
Science
Additional Journal Information:
Journal Volume: 349; Journal Issue: 6254; Related Information: CCDM partners with Temple University (lead); Brookhaven National Laboratory; Drexel University; Duke University; North Carolina State University; Northeastern University; Princeton University; Rice University; University of Pennsylvania; Journal ID: ISSN 0036-8075
Publisher:
AAAS
Country of Publication:
United States
Language:
English
Subject:
catalysis (heterogeneous), solar (photovoltaic), energy storage (including batteries and capacitors), hydrogen and fuel cells, defects, mechanical behavior, materials and chemistry by design, synthesis (novel materials)

Citation Formats

Lee, D., Lu, H., Gu, Y., Choi, S. -. Y., Li, S. -. D., Ryu, S., Paudel, T. R., Song, K., Mikheev, E., Lee, S., Stemmer, S., Tenne, D. A., Oh, S. H., Tsymbal, E. Y., Wu, X., Chen, L. -. Q., Gruverman, A., and Eom, C. B. Emergence of room-temperature ferroelectricity at reduced dimensions. United States: N. p., 2015. Web. doi:10.1126/science.aaa6442.
Lee, D., Lu, H., Gu, Y., Choi, S. -. Y., Li, S. -. D., Ryu, S., Paudel, T. R., Song, K., Mikheev, E., Lee, S., Stemmer, S., Tenne, D. A., Oh, S. H., Tsymbal, E. Y., Wu, X., Chen, L. -. Q., Gruverman, A., & Eom, C. B. Emergence of room-temperature ferroelectricity at reduced dimensions. United States. doi:10.1126/science.aaa6442.
Lee, D., Lu, H., Gu, Y., Choi, S. -. Y., Li, S. -. D., Ryu, S., Paudel, T. R., Song, K., Mikheev, E., Lee, S., Stemmer, S., Tenne, D. A., Oh, S. H., Tsymbal, E. Y., Wu, X., Chen, L. -. Q., Gruverman, A., and Eom, C. B. Thu . "Emergence of room-temperature ferroelectricity at reduced dimensions". United States. doi:10.1126/science.aaa6442.
@article{osti_1387363,
title = {Emergence of room-temperature ferroelectricity at reduced dimensions},
author = {Lee, D. and Lu, H. and Gu, Y. and Choi, S. -. Y. and Li, S. -. D. and Ryu, S. and Paudel, T. R. and Song, K. and Mikheev, E. and Lee, S. and Stemmer, S. and Tenne, D. A. and Oh, S. H. and Tsymbal, E. Y. and Wu, X. and Chen, L. -. Q. and Gruverman, A. and Eom, C. B.},
abstractNote = {},
doi = {10.1126/science.aaa6442},
journal = {Science},
issn = {0036-8075},
number = 6254,
volume = 349,
place = {United States},
year = {2015},
month = {9}
}

Works referenced in this record:

Generalized Gradient Approximation Made Simple
journal, October 1996

  • Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
  • Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
  • DOI: 10.1103/PhysRevLett.77.3865

Composition dependent intrinsic defect structures in SrTiO 3
journal, January 2014

  • Liu, Bin; Cooper, Valentino R.; Xu, Haixuan
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 29
  • DOI: 10.1039/C4CP01510J

Oxide Interfaces--An Opportunity for Electronics
journal, March 2010


Switching kinetics of lead zirconate titanate submicron thin‐film memories
journal, July 1988

  • Scott, J. F.; Kammerdiner, L.; Parris, M.
  • Journal of Applied Physics, Vol. 64, Issue 2
  • DOI: 10.1063/1.341925

Cluster and domain-state dynamics of ferroelectric Sr 1 x Ca x TiO 3 ( x =0.007)
journal, April 1995


Probing Nanoscale Ferroelectricity by Ultraviolet Raman Spectroscopy
journal, September 2006

  • Tenne, D. A.; Bruchhausen, A.; Lanzillotti-Kimura, N. D.
  • Science, Vol. 313, Issue 5793
  • DOI: 10.1126/science.1130306

Tunneling Electroresistance Effect in Ferroelectric Tunnel Junctions at the Nanoscale
journal, October 2009

  • Gruverman, A.; Wu, D.; Lu, H.
  • Nano Letters, Vol. 9, Issue 10
  • DOI: 10.1021/nl901754t

Crystalline ferroelectrics with glassy polarization behavior
journal, September 1983


Superconductor–insulator transition in La2 − xSr x CuO4 at the pair quantum resistance
journal, April 2011


Ferroelectric Control of Spin Polarization
journal, January 2010


Ferroelectricity in Strain-Free SrTiO 3 Thin Films
journal, May 2010


Epitaxial SrTiO3 films with electron mobilities exceeding 30,000 cm2 V-1 s-1
journal, April 2010

  • Son, Junwoo; Moetakef, Pouya; Jalan, Bharat
  • Nature Materials, Vol. 9, Issue 6, p. 482-484
  • DOI: 10.1038/nmat2750

Origin of ferroelectricity in perovskite oxides
journal, July 1992


Ferroelectricity in nonstoichiometric SrTiO3 films studied by ultraviolet Raman spectroscopy
journal, October 2010

  • Tenne, D. A.; Farrar, A. K.; Brooks, C. M.
  • Applied Physics Letters, Vol. 97, Issue 14
  • DOI: 10.1063/1.3499273

Phenomenological study of the size effect on phase transitions in ferroelectric particles
journal, July 1994


Enhancement of Ferroelectric Polarization Stability by Interface Engineering
journal, January 2012


Direct imaging of hydrogen-atom columns in a crystal by annular bright-field electron microscopy
journal, February 2011

  • Ishikawa, Ryo; Okunishi, Eiji; Sawada, Hidetaka
  • Nature Materials, Vol. 10, Issue 4
  • DOI: 10.1038/nmat2957

Ferroelectricity and Tetragonality in Ultrathin P b T i O 3 Films
journal, February 2005


Applications of semi-implicit Fourier-spectral method to phase field equations
journal, February 1998


Enhancement of Ferroelectricity in Strained BaTiO3 Thin Films
journal, November 2004


Single-Crystal Epitaxial Thin Films of the Isotropic Metallic Oxides Sr1-xCaxRuO3 (0 le x le 1)
journal, December 1992


Theory of polarization of crystalline solids
journal, January 1993


Defects and transport in complex oxide thin films
journal, May 2008

  • Ohnishi, Tsuyoshi; Shibuya, Keisuke; Yamamoto, Takahisa
  • Journal of Applied Physics, Vol. 103, Issue 10
  • DOI: 10.1063/1.2921972

First-principles calculations of atomic and electronic structure of SrTiO 3 (001) and (011) surfaces
journal, May 2008


Macroscopic polarization in crystalline dielectrics: the geometric phase approach
journal, July 1994


Effect of substrate constraint on the stability and evolution of ferroelectric domain structures in thin films
journal, January 2002


Reversible electrical switching of spin polarization in multiferroic tunnel junctions
journal, February 2012

  • Pantel, D.; Goetze, S.; Hesse, D.
  • Nature Materials, Vol. 11, Issue 4
  • DOI: 10.1038/nmat3254

Room-temperature ferroelectricity in strained SrTiO3
journal, August 2004

  • Haeni, J. H.; Irvin, P.; Chang, W.
  • Nature, Vol. 430, Issue 7001, p. 758-761
  • DOI: 10.1038/nature02773

Effect of electrical boundary conditions on ferroelectric domain structures in thin films
journal, July 2002

  • Li, Y. L.; Hu, S. Y.; Liu, Z. K.
  • Applied Physics Letters, Vol. 81, Issue 3
  • DOI: 10.1063/1.1492025

Magnetic effects at the interface between non-magnetic oxides
journal, June 2007

  • Brinkman, A.; Huijben, M.; van Zalk, M.
  • Nature Materials, Vol. 6, Issue 7, p. 493-496
  • DOI: 10.1038/nmat1931

A Ferroelectric Oxide Made Directly on Silicon
journal, April 2009


Mechanical Writing of Ferroelectric Polarization
journal, April 2012


Enhancement of ferroelectricity at metal–oxide interfaces
journal, April 2009

  • Stengel, Massimiliano; Vanderbilt, David; Spaldin, Nicola A.
  • Nature Materials, Vol. 8, Issue 5
  • DOI: 10.1038/nmat2429

Ferroelectric Memories
journal, December 1989


Phase transitions and domain structures in strained pseudocubic (100) Sr Ti O 3 thin films
journal, May 2006


Giant tunnel electroresistance for non-destructive readout of ferroelectric states
journal, May 2009

  • Garcia, V.; Fusil, S.; Bouzehouane, K.
  • Nature, Vol. 460, Issue 7251, p. 81-84
  • DOI: 10.1038/nature08128

Restoring the Density-Gradient Expansion for Exchange in Solids and Surfaces
journal, April 2008


Giant Electroresistance in Ferroelectric Tunnel Junctions
journal, June 2005


Relaxor ferroelectrics
journal, December 1987


A high-mobility electron gas at the LaAlO3/SrTiO3 heterointerface
journal, January 2004


Polarization Vortices in Germanium Telluride Nanoplatelets: A Theoretical Study
journal, December 2009


Superconducting Interfaces Between Insulating Oxides
journal, August 2007


Studying Atomic Structures by Aberration-Corrected Transmission Electron Microscopy
journal, July 2008


SrTi O 3 : An intrinsic quantum paraelectric below 4 K
journal, April 1979


Unit-cell scale mapping of ferroelectricity and tetragonality in epitaxial ultrathin ferroelectric films
journal, December 2006

  • Jia, Chun-Lin; Nagarajan, Valanoor; He, Jia-Qing
  • Nature Materials, Vol. 6, Issue 1
  • DOI: 10.1038/nmat1808

Role of Ti Antisitelike Defects in SrTiO 3
journal, October 2009


Critical thickness for ferroelectricity in perovskite ultrathin films
journal, April 2003

  • Junquera, Javier; Ghosez, Philippe
  • Nature, Vol. 422, Issue 6931, p. 506-509
  • DOI: 10.1038/nature01501

Inverse design approach to hole doping in ternary oxides: Enhancing p -type conductivity in cobalt oxide spinels
journal, November 2011


Non-stoichiometry in alkaline earth excess alkaline earth titanates
journal, January 1989