Progress towards high-power Li/CFx batteries: electrode architectures using carbon nanotubes with CFx

Zhang, Qing; Takeuchi, Kenneth J.; Takeuchi, Esther S.; Marschilok, Amy C.

doi:10.1039/C5CP03217B

Progress towards high-power Li/CF_x batteries: electrode architectures using carbon nanotubes with CF_x

Journal Article · Mon Aug 03 00:00:00 EDT 2015 · Physical Chemistry Chemical Physics. PCCP

DOI:https://doi.org/10.1039/C5CP03217B· OSTI ID:1387334

Zhang, Qing ^[1]; Takeuchi, Kenneth J. ^[1]; Takeuchi, Esther S. ^[2]; Marschilok, Amy C. ^[1]

Stony Brook Univ., NY (United States)
Stony Brook Univ., NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)

Carbon monofluoride (CF_x) has a high energy density, exceeding 2000 W h kg^–1, however its application in primary lithium batteries is limited by its power capability. Multi-walled carbon nanotubes (CNTs) are appealing additives for high-power batteries, due to their outstanding electronic transport properties, high aspect ratio necessitating low volume fraction for percolation, and high tensile strength. This perspective describes the current state of the art in lithium–carbon monofluoride (Li/CF_x) batteries and highlights the opportunities for the development of high-power Li/CF_x batteries via utilization of carbon nanotubes. In this report, we generated several electrode architectures using CF_x/CNT combinations, and demonstrated the effectiveness of CNTs in enhancing the rate capability and energy density of Li/CF_x batteries. First, we investigated the resistivity of CF_x combined with CNTs and compared the CF_x/CNT composites with conventional carbon additives. Second, we built CF_x–CNT electrodes without metallic current collectors using CNTs as substrates, and compared their electrochemical performance with conventional CF_x electrodes using aluminum foil as a current collector. Furthermore, we fabricated multi-layered CNT–CF_x–CNT composite electrodes (sandwich electrodes) and studied the impact of the structure on the performance of the electrode. Our work demonstrates some of the opportunities for utilization of CNTs in CF_x electrodes and the resultant implementation of CF_x as a battery cathode in next-generation high-power batteries.

View Accepted Manuscript (DOE)

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2M); Energy Frontier Research Centers (EFRC) (United States). The NorthEast Center for Chemical Energy Storage (NECCES)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012673; SC0001294

OSTI ID:: 1387334

Journal Information:: Physical Chemistry Chemical Physics. PCCP, Journal Name: Physical Chemistry Chemical Physics. PCCP Journal Issue: 35 Vol. 17; ISSN 1463-9076; ISSN PPCPFQ

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Fluorinated Nanographite as a Cathode Material for Lithium Primary Batteries Wang, Li; Li, Yanyan; Wang, Shuo ChemElectroChem, Vol. 6, Issue 8 https://doi.org/10.1002/celc.201900194	journal	March 2019
Facile Carbon Fluoride/Sulfur Hybrid Cathode for High‐Rate Lithium Batteries Peng, Sikan; Wang, Chen; Yan, Shaojiu ChemElectroChem, Vol. 6, Issue 13 https://doi.org/10.1002/celc.201900619	journal	July 2019
Use of inorganic fluorinated materials in lithium batteries and in energy conversion systems Groult, Henri; Tressaud, Alain Chemical Communications, Vol. 54, Issue 81 https://doi.org/10.1039/c8cc05549a	journal	January 2018
Reductive defluorination of graphite monofluoride by weak, non-nucleophilic reductants reveals low-lying electron-accepting sites Liu, Yijun; Noffke, Benjamin W.; Gao, Xinfeng Physical Chemistry Chemical Physics, Vol. 20, Issue 21 https://doi.org/10.1039/c8cp00384j	journal	January 2018
Fluorinated graphene/sulfur hybrid cathode for high energy and high power density lithium primary batteries Peng, Sikan; Yan, Shaojiu; Wang, Nan RSC Advances, Vol. 8, Issue 23 https://doi.org/10.1039/c8ra00226f	journal	January 2018
Insights into the lithiation mechanism of CF _x by a joint high-resolution ¹⁹ F NMR, in situ TEM and ⁷ Li NMR approach Zhong, Guiming; Chen, Huixin; Cheng, Yong Journal of Materials Chemistry A, Vol. 7, Issue 34 https://doi.org/10.1039/c9ta06800g	journal	January 2019
Tomographic 3D Analysis of Reduction Displacement Reaction with Associated Formation of a Conductive Network in High Energy Primary Batteries Bruck, Andrea M.; Li, Yue Ru; Brady, Alexander B. Journal of The Electrochemical Society, Vol. 166, Issue 14 https://doi.org/10.1149/2.0411914jes	journal	January 2019

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
charge transport
energy storage (including batteries and capacitors)
mesostructured materials