Branched isomeric 1,2,3-triazolium-based ionic liquids: new insight into structure–property relationships

Lartey, M.; Meyer-Ilse, J.; Watkins, J. D.; Roth, E. A.; Bowser, S.; Kusuma, V. A.; Damodaran, K.; Zhou, X.; Haranczyk, M.; Albenze, E.; Luebke, D. R.; Hopkinson, D.; Kortright, J. B.; Nulwala, H. B.

doi:10.1039/C5CP04756K

Title: Branched isomeric 1,2,3-triazolium-based ionic liquids: new insight into structure–property relationships

Journal Article · Tue Oct 06 00:00:00 EDT 2015 · Physical Chemistry Chemical Physics. PCCP

DOI:https://doi.org/10.1039/C5CP04756K· OSTI ID:1386959

Lartey, M. ^[1]; Meyer-Ilse, J. ^[2]; Watkins, J. D. ^[1]; Roth, E. A. ^[1]; Bowser, S. ^[3]; Kusuma, V. A. ^[1]; Damodaran, K. ^[3]; Zhou, X. ^[4]; Haranczyk, M. ^[5]; Albenze, E. ^[1]; Luebke, D. R. ^[1]; Hopkinson, D. ^[1]; Kortright, J. B. ^[5];

^[6]

National Energy Technology Lab. (NETL), Pittsburgh, PA (United States)
Materials Science Division; Lawrence Berkeley National Laboratory; Berkeley; USA
Univ. of Pittsburgh, PA (United States)
National Energy Technology Lab. (NETL), Pittsburgh, PA (United States); Liquid Ion Solutions, LLC, Pittsburgh, PA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
National Energy Technology Lab. (NETL), Pittsburgh, PA (United States); Liquid Ion Solutions, LLC, Pittsburgh, PA (United States); Carnegie Mellon Univ., Pittsburgh, PA (United States)

A series of four isomeric 1,2,3-triazolium-based ionic liquids (ILs) with vary degree of branching were synthesized and characterized to investigate the effect of ion branching on thermal and physical properties of the resulting IL. Here, it was found that increased branching led to a higher ionicity and higher viscosity. The thermal properties were also altered significantly and spectral changes in the near edge X-ray absorption fine structure (NEXAFS) spectra show that branching affects intermolecular interaction. While the ionicity and viscosity varying linearly with branching, the MDSC and NEXAFS measurements show that the cation shape has a stronger influence on the melting temperature and absorptive properties than the number of branched alkyl substituents.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Fossil Energy (FE)

Grant/Contract Number:: SC0001015; FE0004000; AC02-05CH11231

OSTI ID:: 1386959

Journal Information:: Physical Chemistry Chemical Physics. PCCP, Vol. 17, Issue 44; Related Information: CGS partners with University of California, Berkeley; University of California, Davis; Lawrence Berkeley National Laboratory; University of Minnesota; National Energy Technology Laboratory; Texas A&M University; ISSN 1463-9076

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 15 works

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