Vapor phase hydrodeoxygenation of furfural to 2-methylfuran on molybdenum carbide catalysts

Lee, Wen-Sheng; Wang, Zhenshu; Zheng, Weiqing; Vlachos, Dionisios G.; Bhan, Aditya

doi:10.1039/c4cy00286e

Vapor phase hydrodeoxygenation of furfural to 2-methylfuran on molybdenum carbide catalysts

Journal Article · Tue Dec 31 23:00:00 EST 2013 · Catalysis Science and Technology

DOI:https://doi.org/10.1039/c4cy00286e· OSTI ID:1386926

Lee, Wen-Sheng; Wang, Zhenshu; Zheng, Weiqing; Vlachos, Dionisios G.; Bhan, Aditya

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Catalysis Center for Energy Innovation (CCEI)

Sponsoring Organization:: USDOE SC Office of Basic Energy Sciences (SC-22)

DOE Contract Number:: SC0001004

OSTI ID:: 1386926

Journal Information:: Catalysis Science and Technology, Journal Name: Catalysis Science and Technology Journal Issue: 8 Vol. 4; ISSN CSTAGD; ISSN 2044-4753

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

References (41)

Elementary steps of syngas reactions on Mo2C(001): Adsorption thermochemistry and bond dissociation Medford, Andrew J.; Vojvodic, Aleksandra; Studt, Felix Journal of Catalysis, Vol. 290 https://doi.org/10.1016/j.jcat.2012.03.007	journal	June 2012
Effects of adsorbed carbon and oxygen on the chemisorption of H2 and Co on Mo(100) Ko, E. I.; Madix, R. J. Surface Science, Vol. 109, Issue 1 https://doi.org/10.1016/0039-6028(81)90521-5	journal	August 1981
Comparison of Reaction Pathways of Ethylene Glycol, Acetaldehyde, and Acetic Acid on Tungsten Carbide and Ni-Modified Tungsten Carbide Surfaces Yu, Weiting; Mellinger, Zachary J.; Barteau, Mark A. The Journal of Physical Chemistry C, Vol. 116, Issue 9 https://doi.org/10.1021/jp210756f	journal	February 2012
Deactivation mechanistic studies of copper chromite catalyst for selective hydrogenation of 2-furfuraldehyde Liu, Dongxia; Zemlyanov, Dmitry; Wu, Tianpin Journal of Catalysis, Vol. 299 https://doi.org/10.1016/j.jcat.2012.10.026	journal	March 2013
Carbon and oxygen atom mobility during activation of Mo2C catalysts Leary, K. Journal of Catalysis, Vol. 101, Issue 2 https://doi.org/10.1016/0021-9517(86)90257-5	journal	October 1986
Synthesis of High-Quality Diesel with Furfural and 2-Methylfuran from Hemicellulose Li, Guangyi; Li, Ning; Wang, Zhiqiang ChemSusChem, Vol. 5, Issue 10 https://doi.org/10.1002/cssc.201200228	journal	August 2012
Acid and base characteristics of molybdenum carbide catalysts Bej, Shyamal K.; Bennett, Christopher A.; Thompson, Levi T. Applied Catalysis A: General, Vol. 250, Issue 2 https://doi.org/10.1016/S0926-860X(02)00664-6	journal	September 2003
Conversion of furfural and 2-methylpentanal on Pd/SiO2 and Pd–Cu/SiO2 catalysts Sitthisa, Surapas; Pham, Trung; Prasomsri, Teerawit Journal of Catalysis, Vol. 280, Issue 1 https://doi.org/10.1016/j.jcat.2011.02.006	journal	May 2011
Synergies between Bio- and Oil Refineries for the Production of Fuels from Biomass Huber, George W.; Corma, Avelino Angewandte Chemie International Edition, Vol. 46, Issue 38, p. 7184-7201 https://doi.org/10.1002/anie.200604504	journal	September 2007
A study of furfural decarbonylation on K-doped Pd/Al2O3 catalysts Zhang, Wei; Zhu, Yulei; Niu, Shasha Journal of Molecular Catalysis A: Chemical, Vol. 335, Issue 1-2 https://doi.org/10.1016/j.molcata.2010.11.016	journal	February 2011
Hydrocracking of organocell lignin for phenol production Meier, D.; Berns, J.; Faix, O. Biomass and Bioenergy, Vol. 7, Issue 1-6 https://doi.org/10.1016/0961-9534(95)92632-I	journal	January 1994
Production of dimethylfuran for liquid fuels from biomass-derived carbohydrates Román-Leshkov, Yuriy; Barrett, Christopher J.; Liu, Zhen Y. Nature, Vol. 447, Issue 7147, p. 982-985 https://doi.org/10.1038/nature05923	journal	June 2007
Molybdenum carbide catalysts for water–gas shift Patt, Jeremy; Moon, Dong Ju; Phillips, Cory Catalysis Letters, Vol. 65, Issue 4, p. 193-195 https://doi.org/10.1023/A:1019098112056	journal	April 2000
CC Bond Formation Reactions for Biomass-Derived Molecules Subrahmanyam, Ayyagari V.; Thayumanavan, Sankaran; Huber, George W. ChemSusChem, Vol. 3, Issue 10 https://doi.org/10.1002/cssc.201000136	journal	August 2010
Kinetics and mechanism of hydrogenation of furfural on Cu/SiO2 catalysts Sitthisa, Surapas; Sooknoi, Tawan; Ma, Yuguang Journal of Catalysis, Vol. 277, Issue 1 https://doi.org/10.1016/j.jcat.2010.10.005	journal	January 2011
Historical Developments in Hydroprocessing Bio-oils Elliott, Douglas C. Energy & Fuels, Vol. 21, Issue 3, p. 1792-1815 https://doi.org/10.1021/ef070044u	journal	May 2007
DFT Study of Furfural Conversion to Furan, Furfuryl Alcohol, and 2-Methylfuran on Pd(111) Vorotnikov, Vassili; Mpourmpakis, Giannis; Vlachos, Dionisios G. ACS Catalysis, Vol. 2, Issue 12 https://doi.org/10.1021/cs300395a	journal	October 2012
Recent Advances in Hydrotreating of Pyrolysis Bio-Oil and Its Oxygen-Containing Model Compounds Wang, Huamin; Male, Jonathan; Wang, Yong ACS Catalysis, Vol. 3, Issue 5 https://doi.org/10.1021/cs400069z	journal	April 2013
Kinetics and mechanism of deactivation of Pd$z.sbnd;Al2O3 catalyst in the gaseous phase decarbonylation of furfural Srivastava, R. Journal of Catalysis, Vol. 91, Issue 2 https://doi.org/10.1016/0021-9517(85)90339-2	journal	February 1985
Influence of the Degree of Carburization on the Density of Sites and Hydrogenating Activity of Molybdenum Carbides Choi, Jae-Soon; Bugli, Guy; Djéga-Mariadassou, Gérald Journal of Catalysis, Vol. 193, Issue 2 https://doi.org/10.1006/jcat.2000.2894	journal	July 2000
Carbon-Supported Molybdenum Carbide Catalysts for the Conversion of Vegetable Oils Han, Junxing; Duan, Jinzhao; Chen, Ping ChemSusChem, Vol. 5, Issue 4, p. 727-733 https://doi.org/10.1002/cssc.201100476	journal	February 2012
202. The hydrogenation of furfuraldehyde to furfuryl alcohol and sylvan (2-methylfuran) Bremner, John G. M.; Keeys, Richard K. F. Journal of the Chemical Society (Resumed) https://doi.org/10.1039/jr9470001068	journal	January 1947
Furfural-A Promising Platform for Lignocellulosic Biofuels Lange, Jean-Paul; van der Heide, Evert; van Buijtenen, Jeroen ChemSusChem, Vol. 5, Issue 1 https://doi.org/10.1002/cssc.201100648	journal	December 2011
Water-Gas-Shift Reaction on Molybdenum Carbide Surfaces: Essential Role of the Oxycarbide Liu, Ping; Rodriguez, José A. The Journal of Physical Chemistry B, Vol. 110, Issue 39 https://doi.org/10.1021/jp0621629	journal	October 2006
Preparation and surface composition of tungsten carbide powders with high specific surface area Ribeiro, F. H.; Dalla Betta, R. A.; Guskey, G. J. Chemistry of Materials, Vol. 3, Issue 5 https://doi.org/10.1021/cm00017a015	journal	September 1991
Acid-Catalyzed Polycondensation of Furfuryl Alcohol: Mechanisms of Chromophore Formation and Cross-Linking Choura, Mekki; Belgacem, Naceur M.; Gandini, Alessandro Macromolecules, Vol. 29, Issue 11 https://doi.org/10.1021/ma951522f	journal	January 1996
Properties of Copper Chromite Catalysts in Hydrogenation Reactions Rao, R.; Dandekar, A.; Baker, R. T. K. Journal of Catalysis, Vol. 171, Issue 2 https://doi.org/10.1006/jcat.1997.1832	journal	October 1997
Selective conversion of furfural to methylfuran over silica-supported NiFe bimetallic catalysts Sitthisa, Surapas; An, Wei; Resasco, Daniel E. Journal of Catalysis, Vol. 284, Issue 1 https://doi.org/10.1016/j.jcat.2011.09.005	journal	November 2011
Study on Cu–Mn–Si catalysts for synthesis of cyclohexanone and 2-methylfuran through the coupling process Zheng, Hong-Yan; Zhu, Yu-Lei; Huang, Long Catalysis Communications, Vol. 9, Issue 3 https://doi.org/10.1016/j.catcom.2007.06.026	journal	March 2008
Tungsten-Based Catalysts for Selective Deoxygenation Gosselink, Robert W.; Stellwagen, Daniel R.; Bitter, Johannes H. Angewandte Chemie International Edition, Vol. 52, Issue 19 https://doi.org/10.1002/anie.201209809	journal	April 2013
Hydrodeoxygenation of Furfural Over Supported Metal Catalysts: A Comparative Study of Cu, Pd and Ni Sitthisa, Surapas; Resasco, Daniel E. Catalysis Letters, Vol. 141, Issue 6 https://doi.org/10.1007/s10562-011-0581-7	journal	March 2011
Carbon Nanofiber Supported Transition-Metal Carbide Catalysts for the Hydrodeoxygenation of Guaiacol Jongerius, Anna L.; Gosselink, Robert W.; Dijkstra, Jelmer ChemCatChem, Vol. 5, Issue 10 https://doi.org/10.1002/cctc.201300280	journal	July 2013
Molybdenum Carbide as a Highly Selective Deoxygenation Catalyst for Converting Furfural to 2-Methylfuran Xiong, Ke; Lee, Wen-Sheng; Bhan, Aditya ChemSusChem, Vol. 7, Issue 8 https://doi.org/10.1002/cssc.201402033	journal	April 2014
Selective Hydrodeoxygenation of Biomass-Derived Oxygenates to Unsaturated Hydrocarbons using Molybdenum Carbide Catalysts Ren, Hui; Yu, Weiting; Salciccioli, Michael ChemSusChem, Vol. 6, Issue 5 https://doi.org/10.1002/cssc.201200991	journal	April 2013
Experimental criterion for the absence of artifacts in the measurement of rates of heterogeneous catalytic reactions Madon, Rostam J.; Boudart, Michel Industrial & Engineering Chemistry Fundamentals, Vol. 21, Issue 4, p. 438-447 https://doi.org/10.1021/i100008a022	journal	November 1982
Catalysis over molybdenum carbides and nitrides I. Catalyst characterization Ranhotra, G. Journal of Catalysis, Vol. 108, Issue 1 https://doi.org/10.1016/0021-9517(87)90152-7	journal	November 1987
High Structure Sensitivity of Vapor-Phase Furfural Decarbonylation/Hydrogenation Reaction Network as a Function of Size and Shape of Pt Nanoparticles Pushkarev, Vladimir V.; Musselwhite, Nathan; An, Kwangjin Nano Letters, Vol. 12, Issue 10 https://doi.org/10.1021/nl3023127	journal	September 2012
Hydroprocessing of Bio-Oils and Oxygenates to Hydrocarbons. Understanding the Reaction Routes Donnis, Bjørn; Egeberg, Rasmus Gottschalck; Blom, Peder Topics in Catalysis, Vol. 52, Issue 3 https://doi.org/10.1007/s11244-008-9159-z	journal	January 2009
Advances in conversion of hemicellulosic biomass to furfural and upgrading to biofuels Dutta, Saikat; De, Sudipta; Saha, Basudeb Catalysis Science & Technology, Vol. 2, Issue 10 https://doi.org/10.1039/c2cy20235b	journal	January 2012
Molybdenum carbide catalysts I. Synthesis of unsupported powders Lee, J. Journal of Catalysis, Vol. 106, Issue 1 https://doi.org/10.1016/0021-9517(87)90218-1	journal	July 1987
Catalytic Reduction of Biomass-Derived Furanic Compounds with Hydrogen Nakagawa, Yoshinao; Tamura, Masazumi; Tomishige, Keiichi ACS Catalysis, Vol. 3, Issue 12 https://doi.org/10.1021/cs400616p	journal	October 2013

Similar Records

Vapor phase hydrodeoxygenation of furfural to 2-methylfuran on molybdenum carbide catalysts

Journal Article · Tue Dec 31 23:00:00 EST 2013 · Catal. Sci. Technol. · OSTI ID:1168312

Molybdenum Carbide as a Highly Selective Deoxygenation Catalyst for Converting Furfural to 2-Methylfuran

Journal Article · Tue Apr 22 00:00:00 EDT 2014 · ChemSusChem · OSTI ID:1168307

Molybdenum Carbide as a Highly Selective Deoxygenation Catalyst for Converting Furfural to 2-Methylfuran

Journal Article · Tue Apr 22 00:00:00 EDT 2014 · ChemSusChem · OSTI ID:1386916

Related Subjects

bio-inspired
biofuels (including algae and biomass)
catalysis (heterogeneous)
catalysis (homogeneous)
hydrogen and fuel cells
materials and chemistry by design
synthesis (novel materials)
synthesis (scalable processing)
synthesis (self-assembly)

Vapor phase hydrodeoxygenation of furfural to 2-methylfuran on molybdenum carbide catalysts

Citation Formats

References (41)

Similar Records

Related Subjects