Uranyl triazolate formation via an in situ Huisgen 1,3-dipolar cycloaddition reaction

Knope, Karah E.; Cahill, Christopher L.

doi:10.1039/c0ce00231c

Uranyl triazolate formation via an in situ Huisgen 1,3-dipolar cycloaddition reaction

Journal Article · Fri Dec 31 23:00:00 EST 2010 · CrystEngComm

DOI:https://doi.org/10.1039/c0ce00231c· OSTI ID:1386708

Knope, Karah E.; Cahill, Christopher L.

A two dimensional UO22+ coordination polymer, (UO2)3(C10H5N3O4)2(OH)2(H2O)2, has been synthesized under solvothermal conditions. The triazolate ligand, 1-(4-carboxyphenyl)-1H-1,2,3-triazole-4-carboxylic acid (CPTAZ) has been generated via a 1,3-dipolar cycloaddition of 4-azidobenzoic acid and propiolic acid. Reactions of the UO22+ cation with both the in situ generated triazolate ligand and the presynthesized ligand have been explored. The structure, fluorescent and thermal behaviour of this material are presented, as is a discussion of the utility of in situ ligand formation versus direct assembly.

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Materials Science of Actinides (MSA)

Sponsoring Organization:: USDOE SC Office of Basic Energy Sciences (SC-22)

DOE Contract Number:: SC0001089

OSTI ID:: 1386708

Journal Information:: CrystEngComm, Journal Name: CrystEngComm Journal Issue: 1 Vol. 13; ISSN CRECF4; ISSN 1466-8033

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

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