Cerium(IV) Tellurite Halides [Ce 2 Te 7 O 17 ]X 2 (X = Cl – or Br – ): The First Cerium-Containing Cationic Frameworks
- Department of Civil &, Environmental Engineering &, Earth Sciences and Department of Chemistry and Biochemistry, University of Notre Dame, 156 Fitzpatrick Hall, Notre Dame, Indiana 46556, United States
- Department of Chemistry and Biochemistry, Florida State University, Tallahassee, Florida 32306, United States
Two isotypic cerium tellurite halides with the formulas [Ce2Te7O17]Cl2 and [Ce2Te7O17]Br2 have been synthesized hydrothermally via the reactions of CeCl3 and CeBr3 with TeO2. The structures of these compounds feature a cationic inorganic framework. The CeIV dimers are bound by a novel 3D Te7O176– building unit, forming an unusual hexagonal-bipyramidal environment around CeIV.
- Research Organization:
- Energy Frontier Research Centers (EFRC) (United States). Materials Science of Actinides (MSA)
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- DOE Contract Number:
- SC0001089
- OSTI ID:
- 1386694
- Journal Information:
- Inorganic Chemistry, Vol. 51, Issue 19; Related Information: MSA partners with University of Notre Dame (lead); University of California, Davis; Florida State University; George Washington University; University of Michigan; University of Minnesota; Oak Ridge National Laboratory; Oregon state University; Rensselaer Polytechnic Institute; Savannah River National Laboratory; ISSN 0020-1669
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
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