Low-Symmetry Uranyl Pyrophosphate Cage Clusters

Ling, Jie; Qiu, Jie; Szymanowski, Jennifer E.  S.; Burns, Peter C.

doi:10.1002/chem.201003481

Low-Symmetry Uranyl Pyrophosphate Cage Clusters

Journal Article · Sun Jan 30 04:00:00 EST 2011 · Chemistry - A European Journal

DOI:https://doi.org/10.1002/chem.201003481· OSTI ID:1386650

Ling, Jie; Qiu, Jie; Szymanowski, Jennifer E. S.; Burns, Peter C.

Is cluster symmetry so important? The combination of uranyl, peroxide, and pyrophosphate in aqueous solution results in the self-assembly of highly complex clusters (see figure) containing 45 uranyl bipyramids and 23 pyrophosphate groups. These clusters are built from three basic structural units, and are highly unusual because they completely lack symmetry. They provide a window into the complex chemistry of evolving cluster topologies under the conditions of their formation.

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Materials Science of Actinides (MSA)

Sponsoring Organization:: USDOE SC Office of Basic Energy Sciences (SC-22)

DOE Contract Number:: SC0001089

OSTI ID:: 1386650

Journal Information:: Chemistry - A European Journal, Journal Name: Chemistry - A European Journal Journal Issue: 9 Vol. 17; ISSN 0947-6539

Publisher:: ChemPubSoc Europe

Country of Publication:: United States

Language:: English

References (29)

Epoxidation of olefins with hydrogen peroxide catalyzed by polyoxometalates Mizuno, N.; Yamaguchi, K.; Kamata, K. Coordination Chemistry Reviews, Vol. 249, Issue 17-18 https://doi.org/10.1016/j.ccr.2004.11.019	journal	September 2005
En route from the mystery of molybdenum blue via related manipulatable building blocks to aspects of materials science Müller, A.; Roy, S. Coordination Chemistry Reviews, Vol. 245, Issue 1-2 https://doi.org/10.1016/S0010-8545(03)00110-3	journal	October 2003
High-Symmetry Coordination Cages via Self-Assembly Seidel, S. Russell; Stang, Peter J. Accounts of Chemical Research, Vol. 35, Issue 11 https://doi.org/10.1021/ar010142d	journal	November 2002
C60: Buckminsterfullerene Kroto, H. W.; Heath, J. R.; O'Brien, S. C. Nature, Vol. 318, Issue 6042 https://doi.org/10.1038/318162a0	journal	November 1985
Actinyl Peroxide Nanospheres Burns, Peter C.; Kubatko, Karrie-Ann; Sigmon, Ginger Angewandte Chemie International Edition, Vol. 44, Issue 14 https://doi.org/10.1002/anie.200462445	journal	March 2005
Uranium Pyrophosphate/Methylenediphosphonate Polyoxometalate Cage Clusters Ling, Jie; Qiu, Jie; Sigmon, Ginger E. Journal of the American Chemical Society, Vol. 132, Issue 38 https://doi.org/10.1021/ja1048219	journal	September 2010
Hybrid Uranium-Oxalate Fullerene Topology Cage Clusters Ling, Jie; Wallace, Christine M.; Szymanowski, Jennifer E. S. Angewandte Chemie, Vol. 122, Issue 40 https://doi.org/10.1002/ange.201003197	journal	August 2010
Hybrid Uranium-Oxalate Fullerene Topology Cage Clusters Ling, Jie; Wallace, Christine M.; Szymanowski, Jennifer E. S. Angewandte Chemie International Edition, Vol. 49, Issue 40 https://doi.org/10.1002/anie.201003197	journal	August 2010
Metal–Oxygen Isopolyhedra Assembled into Fullerene Topologies Forbes, Tori Z.; McAlpin, J. Gregory; Murphy, Rachel Angewandte Chemie, Vol. 120, Issue 15 https://doi.org/10.1002/ange.200705563	journal	March 2008
Uranyl peroxide closed clusters containing topological squares Unruh, Daniel K.; Burtner, Alicia; Pressprich, Laura Dalton Transactions, Vol. 39, Issue 25 https://doi.org/10.1039/c0dt00074d	journal	January 2010
Polyoxometallate als Bausteine für funktionelle Nanosysteme Long, De-Liang; Tsunashima, Ryo; Cronin, Leroy Angewandte Chemie, Vol. 122, Issue 10 https://doi.org/10.1002/ange.200902483	journal	March 2010
Polyoxometalates: Building Blocks for Functional Nanoscale Systems Long, De-Liang; Tsunashima, Ryo; Cronin, Leroy Angewandte Chemie International Edition, Vol. 49, Issue 10, p. 1736-1758 https://doi.org/10.1002/anie.200902483	journal	March 2010
[Mo154(NO)14O420(OH)28(H2O)70](25± 5)−: A Water-Soluble Big Wheel with More than 700 Atoms and a Relative Molecular Mass of About 24000 Müller, Achim; Krickemeyer, Erich; Meyer, Jochen Angewandte Chemie International Edition in English, Vol. 34, Issue 19 https://doi.org/10.1002/anie.199521221	journal	October 1995
Progress and challenges in polyoxometalate-based catalysis and catalytic materials chemistry Hill, Craig L. Journal of Molecular Catalysis A: Chemical, Vol. 262, Issue 1-2 https://doi.org/10.1016/j.molcata.2006.08.042	journal	February 2007
Self-assembly in aqueous solution of wheel-shaped Mo154 oxide clusters into vesicles Liu, Tianbo; Diemann, Ekkehard; Li, Huilin Nature, Vol. 426, Issue 6962 https://doi.org/10.1038/nature02036	journal	November 2003
Uranyl−Peroxide Interactions Favor Nanocluster Self-Assembly Sigmon, Ginger E.; Ling, Jie; Unruh, Daniel K. Journal of the American Chemical Society, Vol. 131, Issue 46 https://doi.org/10.1021/ja907837u	journal	November 2009
Actinyl Peroxide Nanospheres Burns, Peter C.; Kubatko, Karrie-Ann; Sigmon, Ginger Angewandte Chemie, Vol. 117, Issue 14 https://doi.org/10.1002/ange.200462445	journal	March 2005
Symmetry versus Minimal Pentagonal Adjacencies in Uranium-Based Polyoxometalate Fullerene Topologies Sigmon, Ginger E.; Unruh, Daniel K.; Ling, Jie Angewandte Chemie International Edition, Vol. 48, Issue 15 https://doi.org/10.1002/anie.200805870	journal	March 2009
Understanding the Structure and Formation of Uranyl Peroxide Nanoclusters by Quantum Chemical Calculations Vlaisavljevich, Bess; Gagliardi, Laura; Burns, Peter C. Journal of the American Chemical Society, Vol. 132, Issue 41 https://doi.org/10.1021/ja104964x	journal	October 2010
Actinide Polyoxometalates: Incorporation of Uranyl-Peroxo in U-Shaped 36-Tungsto-8-Phosphate Mal, Sib Sankar; Dickman, Michael H.; Kortz, Ulrich Chemistry - A European Journal, Vol. 14, Issue 32 https://doi.org/10.1002/chem.200801583	journal	November 2008
Single-crystal structure validation with the program PLATON Spek, A. L. Journal of Applied Crystallography, Vol. 36, Issue 1, p. 7-13 https://doi.org/10.1107/S0021889802022112	journal	January 2003
Polyoxometalate clusters, nanostructures and materials: From self assembly to designer materials and devices Long, De-Liang; Burkholder, Eric; Cronin, Leroy Chem. Soc. Rev., Vol. 36, Issue 1 https://doi.org/10.1039/B502666K	journal	January 2007
Symmetry versus Minimal Pentagonal Adjacencies in Uranium-Based Polyoxometalate Fullerene Topologies Sigmon, Ginger E.; Unruh, Daniel K.; Ling, Jie Angewandte Chemie, Vol. 121, Issue 15 https://doi.org/10.1002/ange.200805870	journal	March 2009
Formation of a “less stable” polyanion directed and protected by electrophilic internal surface functionalities of a capsule in growth: [{Mo ₆ O ₁₉ } ²⁻ ⊂{Mo ^vi ₇₂ Fe ⁱⁱⁱ ₃₀ O ₂₅₂ (ac) ₂₀ (H ₂ O) ₉₂ }] ⁴⁻ Müller, Achim; Todea, Ana Maria; Bögge, Hartmut Chem. Commun., Issue 29 https://doi.org/10.1039/B604977J	journal	January 2006
Crown and Bowl-Shaped Clusters of Uranyl Polyhedra Sigmon, Ginger E.; Weaver, Brittany; Kubatko, Karrie-Ann Inorganic Chemistry, Vol. 48, Issue 23 https://doi.org/10.1021/ic9020355	journal	December 2009
Metal–Oxygen Isopolyhedra Assembled into Fullerene Topologies Forbes, Tori Z.; McAlpin, J. Gregory; Murphy, Rachel Angewandte Chemie International Edition, Vol. 47, Issue 15 https://doi.org/10.1002/anie.200705563	journal	March 2008
Synthesis and Structural Characterization of the First Uranium Cluster Containing an Isopolyoxometalate Core Duval, Paul B.; Burns, Carol J.; Clark, David L. Angewandte Chemie International Edition, Vol. 40, Issue 18 https://doi.org/10.1002/1521-3773(20010917)40:18<3357::AID-ANIE3357>3.0.CO;2-C	journal	September 2001
Soluble Molybdenum Blues“des Pudels Kern” ^† Müller, Achim; Serain, Claire Accounts of Chemical Research, Vol. 33, Issue 1 https://doi.org/10.1021/ar9601510	journal	January 2000
[Mo154(NO)14O420(OH)28(H2O)70](25 ± 5)−: ein wasserlösliches Riesenrad mit mehr als 700 Atomen und einer relativen Molekülmasse von ca. 24000 Müller, Achim; Krickemeyer, Erich; Meyer, Jochen Angewandte Chemie, Vol. 107, Issue 19 https://doi.org/10.1002/ange.19951071911	journal	October 1995

Similar Records

Pyrophosphate and Methylenediphosphonate Incorporated Uranyl Peroxide Cage Clusters

Journal Article · Tue Nov 06 23:00:00 EST 2018 · Crystal Growth and Design · OSTI ID:1566486

Nanoscale uranium-based cage clusters inspired by uranium mineralogy

Journal Article · Mon Jan 31 23:00:00 EST 2011 · Mineralogical Magazine · OSTI ID:1386723

Sulfate-Centered Sodium-Icosahedron-Templated Uranyl Peroxide Phosphate Cages with Uranyl Bridged by μ–η¹:η² Peroxide

Journal Article · Sun Jan 29 19:00:00 EST 2017 · Inorganic Chemistry · OSTI ID:1388536

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
nuclear (including radiation effects)
materials and chemistry by design
synthesis (novel materials)
synthesis (self-assembly)

Low-Symmetry Uranyl Pyrophosphate Cage Clusters

Citation Formats

References (29)

Similar Records

Related Subjects