skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Electron Transfer and Multi-Electron Accumulation in ExBox 4+

Authors:
; ; ; ; ; ;
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Argonne-Northwestern Solar Energy Research Center (ANSER)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1386311
DOE Contract Number:  
SC0001059
Resource Type:
Journal Article
Journal Name:
Angewandte Chemie (International Edition)
Additional Journal Information:
Journal Volume: 53; Journal Issue: 21; Related Information: ANSER partners with Northwestern University (lead); Argonne National Laboratory; University of Chicago; University of Illinois, Urbana-Champaign; Yale University; Journal ID: ISSN 1433-7851
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
catalysis (homogeneous), catalysis (heterogeneous), solar (photovoltaic), solar (fuels), photosynthesis (natural and artificial), bio-inspired, hydrogen and fuel cells, electrodes - solar, defects, charge transport, spin dynamics, membrane, materials and chemistry by design, optics, synthesis (novel materials), synthesis (self-assembly)

Citation Formats

Dyar, Scott M., Barnes, Jonathan C., Juríček, Michal, Stoddart, J. Fraser, Co, Dick T., Young, Ryan M., and Wasielewski, Michael R. Electron Transfer and Multi-Electron Accumulation in ExBox 4+. United States: N. p., 2014. Web. doi:10.1002/anie.201402444.
Dyar, Scott M., Barnes, Jonathan C., Juríček, Michal, Stoddart, J. Fraser, Co, Dick T., Young, Ryan M., & Wasielewski, Michael R. Electron Transfer and Multi-Electron Accumulation in ExBox 4+. United States. doi:10.1002/anie.201402444.
Dyar, Scott M., Barnes, Jonathan C., Juríček, Michal, Stoddart, J. Fraser, Co, Dick T., Young, Ryan M., and Wasielewski, Michael R. Wed . "Electron Transfer and Multi-Electron Accumulation in ExBox 4+". United States. doi:10.1002/anie.201402444.
@article{osti_1386311,
title = {Electron Transfer and Multi-Electron Accumulation in ExBox 4+},
author = {Dyar, Scott M. and Barnes, Jonathan C. and Juríček, Michal and Stoddart, J. Fraser and Co, Dick T. and Young, Ryan M. and Wasielewski, Michael R.},
abstractNote = {},
doi = {10.1002/anie.201402444},
journal = {Angewandte Chemie (International Edition)},
issn = {1433-7851},
number = 21,
volume = 53,
place = {United States},
year = {2014},
month = {5}
}

Works referenced in this record:

Photoinduced electron transfer in supramolecular systems for artificial photosynthesis
journal, May 1992

  • Wasielewski, Michael R.
  • Chemical Reviews, Vol. 92, Issue 3, p. 435-461
  • DOI: 10.1021/cr00011a005

Enabling tetracationic cyclophane production by trading templates
journal, January 2010

  • Sue, Chi-Hau; Basu, Subhadeep; Fahrenbach, Albert C.
  • Chemical Science, Vol. 1, Issue 1
  • DOI: 10.1039/c0sc00176g

Ruthenium Photocatalysts Capable of Reversibly Storing up to Four Electrons in a Single Acceptor Ligand: A Step Closer to Artificial Photosynthesis
journal, September 2002


Synthesis and characterization of new conjugation-extended viologens involving a central aromatic linking group
journal, January 1992

  • Takahashi, Kazuko; Nihira, Takayasu; Akiyama, Kimio
  • Journal of the Chemical Society, Chemical Communications, Issue 8
  • DOI: 10.1039/c39920000620

Synthesis and Characterization of a Highly Reducing Neutral “Extended Viologen” and the Isostructural Hydrocarbon 4,4‘ ‘‘ ‘-Di- n -octyl- p -quaterphenyl
journal, November 2005

  • Porter, William W.; Vaid, Thomas P.; Rheingold, Arnold L.
  • Journal of the American Chemical Society, Vol. 127, Issue 47
  • DOI: 10.1021/ja053084q

Intrazeolitic Photochemical Charge Separation for Ru(bpy) 3 2+ −Bipyridinium System:  Role of the Zeolite Structure
journal, April 1999

  • Vitale, Marcello; Castagnola, Norma B.; Ortins, Nancy J.
  • The Journal of Physical Chemistry B, Vol. 103, Issue 13
  • DOI: 10.1021/jp983579k

Switching Surface Chemistry with Supramolecular Machines
journal, January 2007

  • Bunker, Bruce C.; Huber, Dale L.; Kushmerick, James G.
  • Langmuir, Vol. 23, Issue 1
  • DOI: 10.1021/la0615793

Molecular mimicry of photosynthetic energy and electron transfer
journal, April 1993

  • Gust, Devens; Moore, Thomas A.; Moore, Ana L.
  • Accounts of Chemical Research, Vol. 26, Issue 4
  • DOI: 10.1021/ar00028a010

Intersystem Crossing Involving Strongly Spin Exchange-Coupled Radical Ion Pairs in Donor–bridge–Acceptor Molecules
journal, February 2012

  • Colvin, Michael T.; Ricks, Annie Butler; Scott, Amy M.
  • The Journal of Physical Chemistry A, Vol. 116, Issue 8
  • DOI: 10.1021/jp212546w

Improved Template-Directed Synthesis of Cyclobis(paraquat- p -phenylene)
journal, January 1996

  • Asakawa, Masumi; Dehaen, Wim; L'abbé, Gerrit
  • The Journal of Organic Chemistry, Vol. 61, Issue 26
  • DOI: 10.1021/jo961488i

Photoelectrochemical cell based on the ion pair 1,1'-dimethyl-4,4'-bipyridinium bis(tetraphenylborate). Photocurrents from the direct irradiation of a donor-acceptor complex
journal, April 1982

  • Sullivan, B. Patrick; Dressick, Walter J.; Meyer, Thomas J.
  • The Journal of Physical Chemistry, Vol. 86, Issue 8
  • DOI: 10.1021/j100397a053

Intrazeolite Photochemistry. 16. Fluorescence of Methylviologen Adsorbed within Medium- and Large-Pore Zeolites
journal, January 1996

  • Alvaro, Mercedes; Facey, Glenn A.; García, Hermenegildo
  • The Journal of Physical Chemistry, Vol. 100, Issue 46
  • DOI: 10.1021/jp960733z

Intrazeolite Photochemistry. 17. Zeolites as Electron Donors:  Photolysis of Methylviologen Incorporated within Zeolites
journal, April 1997

  • Alvaro, Mercedes; García, Hermenegildo; García, Sara
  • The Journal of Physical Chemistry B, Vol. 101, Issue 16
  • DOI: 10.1021/jp9628850

A Radically Configurable Six-State Compound
journal, January 2013


Photoinitiated multi-step charge separation and ultrafast charge transfer induced dissociation in a pyridyl-linked photosensitizer–cobaloxime assembly
journal, January 2013

  • Veldkamp, Brad S.; Han, Won-Sik; Dyar, Scott M.
  • Energy & Environmental Science, Vol. 6, Issue 6
  • DOI: 10.1039/c3ee40378e

Excited State Dynamics of Methyl Viologen. Ultrafast Photoreduction in Methanol and Fluorescence in Acetonitrile
journal, June 2001

  • Peon, Jorge; Tan, Xin; Hoerner, J. David
  • The Journal of Physical Chemistry A, Vol. 105, Issue 24
  • DOI: 10.1021/jp010084d

Intrazeolitic Photoreactions of Ru(bpy) 3 3+ with Methyl Viologen
journal, September 1998


A Novel Type of Cationic Host Molecules withπ-Acceptor Properties
journal, November 1988

  • Bühner, Manfred; Geuder, Wolfram; Gries, Willi-Kurt
  • Angewandte Chemie International Edition in English, Vol. 27, Issue 11
  • DOI: 10.1002/anie.198815531

ExBox: A Polycyclic Aromatic Hydrocarbon Scavenger
journal, October 2012

  • Barnes, Jonathan C.; Juríček, Michal; Strutt, Nathan L.
  • Journal of the American Chemical Society, Vol. 135, Issue 1
  • DOI: 10.1021/ja307360n

Solar Fuels via Artificial Photosynthesis
journal, December 2009

  • Gust, Devens; Moore, Thomas A.; Moore, Ana L.
  • Accounts of Chemical Research, Vol. 42, Issue 12
  • DOI: 10.1021/ar900209b

The photoexcited triplet state and photosynthesis
journal, June 1978


Self-Assembly Strategies for Integrating Light Harvesting and Charge Separation in Artificial Photosynthetic Systems
journal, December 2009

  • Wasielewski, Michael R.
  • Accounts of Chemical Research, Vol. 42, Issue 12
  • DOI: 10.1021/ar9001735

Accumulative Charge Separation Inspired by Photosynthesis
journal, December 2010

  • Karlsson, Susanne; Boixel, Julien; Pellegrin, Yann
  • Journal of the American Chemical Society, Vol. 132, Issue 51
  • DOI: 10.1021/ja104809x

A porphyrin–polyoxometallate bio-inspired mimic for artificial photosynthesis
journal, January 2009

  • Elliott, Kristopher J.; Harriman, Anthony; Le Pleux, Loïc
  • Physical Chemistry Chemical Physics, Vol. 11, Issue 39
  • DOI: 10.1039/b905548g

Synthesis and Photophysical Properties of Light-Harvesting Arrays Comprised of a Porphyrin Bearing Multiple Perylene-Monoimide Accessory Pigments
journal, September 2002

  • Tomizaki, Kin-ya; Loewe, Robert S.; Kirmaier, Christine
  • The Journal of Organic Chemistry, Vol. 67, Issue 18
  • DOI: 10.1021/jo0258002

Mechanically induced intramolecular electron transfer in a mixed-valence molecular shuttle
journal, June 2012

  • Barnes, J. C.; Fahrenbach, A. C.; Dyar, S. M.
  • Proceedings of the National Academy of Sciences, Vol. 109, Issue 29
  • DOI: 10.1073/pnas.1201561109

Einschlußkomplexe aus einem makrocyclischen Wirtmolekül und aromatischen Kohlenwasserstoffen in wäßriger Lösung
journal, September 1983


A ‘Texas-sized’ molecular box that forms an anion-induced supramolecular necklace
journal, March 2010

  • Gong, Han-Yuan; Rambo, Brett M.; Karnas, Elizabeth
  • Nature Chemistry, Vol. 2, Issue 5
  • DOI: 10.1038/nchem.597

Picosecond Optical Switching Based on Biphotonic Excitation of an Electron Donor-Acceptor-Donor Molecule
journal, July 1992


Biomimetic and Microbial Approaches to Solar Fuel Generation
journal, December 2009

  • Magnuson, Ann; Anderlund, Magnus; Johansson, Olof
  • Accounts of Chemical Research, Vol. 42, Issue 12
  • DOI: 10.1021/ar900127h

A rigid donor–acceptor daisy chain dimer
journal, January 2012

  • Cao, Dennis; Wang, Cheng; Giesener, Marc A.
  • Chemical Communications, Vol. 48, Issue 54
  • DOI: 10.1039/c2cc32499g

Measurement of the extinction coefficient of the methyl viologen cation radical and the efficiency of its formation by semiconductor photocatalysis
journal, July 1982

  • Watanabe, Tadashi; Honda, Kenichi
  • The Journal of Physical Chemistry, Vol. 86, Issue 14
  • DOI: 10.1021/j100211a014

Cyclobis(paraquat-p-phenylen), ein tetrakationischer Mehrzweckrezeptor
journal, November 1988

  • Odell, Barbara; Reddington, Mark V.; Slawin, Alexandra M. Z.
  • Angewandte Chemie, Vol. 100, Issue 11
  • DOI: 10.1002/ange.19881001132

Storage of light energy by photoelectron transfer across a sensitized zeolite–solution interface
journal, March 1993

  • Borja, Marlon; Dutta, Prabir K.
  • Nature, Vol. 362, Issue 6415
  • DOI: 10.1038/362043a0

Electron dopable molecular wires based on the extended viologens
journal, January 2011

  • Kolivoška, Viliam; Gál, Miroslav; Pospíšil, Lubomír
  • Physical Chemistry Chemical Physics, Vol. 13, Issue 23
  • DOI: 10.1039/c1cp20652d

Ein neuer Typ kationischer Wirtmoleküle mit π-Acceptor-Eigenschaften
journal, November 1988

  • Bühner, Manfred; Geuder, Wolfram; Gries, Willi-Kurt
  • Angewandte Chemie, Vol. 100, Issue 11
  • DOI: 10.1002/ange.19881001134

A [2]Catenane-Based Solid State Electronically Reconfigurable Switch
journal, August 2000


Cyclobis(paraquat-p-phenylene). A Tetracationic Multipurpose Receptor
journal, November 1988

  • Odell, Barbara; Reddington, Mark V.; Slawin, Alexandra M. Z.
  • Angewandte Chemie International Edition in English, Vol. 27, Issue 11, p. 1547-1550
  • DOI: 10.1002/anie.198815471

A chemically and electrochemically switchable molecular shuttle
journal, May 1994

  • Bissell, Richard A.; Córdova, Emilio; Kaifer, Angel E.
  • Nature, Vol. 369, Issue 6476
  • DOI: 10.1038/369133a0

The “Texas-Sized” Molecular Box: A Versatile Building Block for the Construction of Anion-Directed Mechanically Interlocked Structures
journal, May 2012

  • Rambo, Brett M.; Gong, Han-Yuan; Oh, Moonhyun
  • Accounts of Chemical Research, Vol. 45, Issue 8
  • DOI: 10.1021/ar300076b

Ultrafast Conformational Dynamics of Electron Transfer in ExBox 4+ ⊂Perylene
journal, November 2013

  • Young, Ryan M.; Dyar, Scott M.; Barnes, Jonathan C.
  • The Journal of Physical Chemistry A, Vol. 117, Issue 47
  • DOI: 10.1021/jp409883a

Photoinduced electron transfer in DNA matrix from intercalated ethidium to condensed methylviologen
journal, August 1986

  • Fromherz, Peter.; Rieger, Bernhard.
  • Journal of the American Chemical Society, Vol. 108, Issue 17
  • DOI: 10.1021/ja00277a060

Chemical Approaches to Artificial Photosynthesis. 2
journal, October 2005

  • Alstrum-Acevedo, James H.; Brennaman, M. Kyle; Meyer, Thomas J.
  • Inorganic Chemistry, Vol. 44, Issue 20
  • DOI: 10.1021/ic050904r

Photochemical Conversion of Solar Energy
journal, February 2008

  • Balzani, Vincenzo; Credi, Alberto; Venturi, Margherita
  • ChemSusChem, Vol. 1, Issue 1-2
  • DOI: 10.1002/cssc.200700087

A 160-kilobit molecular electronic memory patterned at 1011 bits per square centimetre
journal, January 2007

  • Green, Jonathan E.; Wook Choi, Jang; Boukai, Akram
  • Nature, Vol. 445, Issue 7126, p. 414-417
  • DOI: 10.1038/nature05462

Inclusion Complexes between a Macrocyclic Host Molecule and Aromatic Hydrocarbons in Aqueous Solution
journal, January 1983

  • Diederich, François; Dick, Klaus
  • Angewandte Chemie International Edition in English, Vol. 22, Issue 9
  • DOI: 10.1002/anie.198307151

Donor–acceptor molecular figures-of-eight
journal, January 2011

  • Boyle, Megan M.; Forgan, Ross S.; Friedman, Douglas C.
  • Chemical Communications, Vol. 47, Issue 43
  • DOI: 10.1039/c1cc15333a