Electrochemical oxidation of H 2 catalyzed by ruthenium hydride complexes bearing P 2 N 2 ligands with pendant amines as proton relays

Liu, Tianbiao; DuBois, Mary Rakowski; DuBois, Daniel L.; Bullock, R. Morris

doi:10.1039/C4EE01262C

Electrochemical oxidation of H ₂ catalyzed by ruthenium hydride complexes bearing P ₂ N ₂ ligands with pendant amines as proton relays

Journal Article · Wed Jan 01 04:00:00 EST 2014 · Energy & Environmental Science

DOI:https://doi.org/10.1039/C4EE01262C· OSTI ID:1386175

Liu, Tianbiao ^[1]; DuBois, Mary Rakowski ^[1]; DuBois, Daniel L. ^[1]; Bullock, R. Morris ^[1]

Center for Molecular Electrocatalysis; Physical Sciences Division; Pacific Northwest National Laboratory; Richland, USA

A new class of Ru electrocatalysts containing P₂N₂diphosphine ligands with pendant amines converts the chemical bond energy of H₂to electricity.

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Molecular Electrocatalysis (CME)

Sponsoring Organization:: USDOE SC Office of Basic Energy Sciences (SC-22)

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1386175

Journal Information:: Energy & Environmental Science, Journal Name: Energy & Environmental Science Journal Issue: 11 Vol. 7; ISSN EESNBY; ISSN 1754-5692

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

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Electrochemical oxidation of H 2 catalyzed by ruthenium hydride complexes bearing P 2 N 2 ligands with pendant amines as proton relays

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Electrochemical oxidation of H ₂ catalyzed by ruthenium hydride complexes bearing P ₂ N ₂ ligands with pendant amines as proton relays