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Title: Heterolytic cleavage of H 2 by bifunctional manganese( i ) complexes: impact of ligand dynamics, electrophilicity, and base positioning

Journal Article · · Chemical Science
DOI:https://doi.org/10.1039/C4SC01801J· OSTI ID:1386166
 [1];  [1];  [1]
  1. Center for Molecular Electrocatalysis; Physical Sciences Division; Pacific Northwest National Laboratory; Richland, USA
+ Show Author Affiliations

A balance of metal electrophilicity and ligand steric influences is required for facile, reversible H–H heterolytic cleavage in Mn complexes with pendant amines.

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Center for Molecular Electrocatalysis (CME)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
DOE Contract Number:
AC05-76RL01830
OSTI ID:
1386166
Journal Information:
Chemical Science, Vol. 5, Issue 12; Related Information: CME partners with Pacific Northwest National Laboratory (lead); University of Illinois, Urbana-Champaign; Pennsylvania State University; University of Washington; University of Wyoming; ISSN 2041-6520
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

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