Electrochemical reduction of Ag 2 VP 2 O 8 composite electrodes visualized via in situ energy dispersive X-ray diffraction (EDXRD): unexpected conductive additive effects

Kirshenbaum, Kevin C.; Bock, David C.; Zhong, Zhong; Marschilok, Amy C.; Takeuchi, Kenneth J.; Takeuchi, Esther S.

doi:10.1039/C5TA04523A

Electrochemical reduction of Ag ₂ VP ₂ O ₈ composite electrodes visualized via in situ energy dispersive X-ray diffraction (EDXRD): unexpected conductive additive effects

Journal Article · Wed Dec 31 23:00:00 EST 2014 · Journal of Materials Chemistry. A

DOI:https://doi.org/10.1039/C5TA04523A· OSTI ID:1385996

Kirshenbaum, Kevin C. ^[1]; Bock, David C. ^[2]; Zhong, Zhong ^[1]; Marschilok, Amy C. ^[3]; Takeuchi, Kenneth J. ^[3]; Takeuchi, Esther S. ^[4]

Energy Sciences Directorate; Brookhaven National Laboratory; Upton; USA
Department of Chemistry; Stony Brook University; Stony Brook; USA
Department of Chemistry; Stony Brook University; Stony Brook; USA; Department of Materials Science and Engineering
Energy Sciences Directorate; Brookhaven National Laboratory; Upton; USA; Department of Chemistry

EDXRD of Li/C-Ag₂VP₂O₈revealed that higher-rate initial discharge (B) generated a more effective conductive matrixvia in situreduction-displacement-deposition of Ag⁰.

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2M)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

DOE Contract Number:: SC0012673

OSTI ID:: 1385996

Journal Information:: Journal of Materials Chemistry. A, Journal Name: Journal of Materials Chemistry. A Journal Issue: 35 Vol. 3; ISSN JMCAET; ISSN 2050-7488

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

References (29)

Energy Dispersive X-ray Diffraction Profiling of Prototype LiMn ₂ O ₄ -Based Coin Cells Liang, Gan; Croft, Mark C.; Zhong, Zhong Journal of The Electrochemical Society, Vol. 160, Issue 8 https://doi.org/10.1149/2.115308jes	journal	January 2013
Electrochemical properties of carbon-coated LiFePO4 cathode using graphite, carbon black, and acetylene black Shin, Ho Chul; Cho, Won Il; Jang, Ho Electrochimica Acta, Vol. 52, Issue 4 https://doi.org/10.1016/j.electacta.2006.01.078	journal	December 2006
Ohmic Drop in LiFePO ₄ Based Lithium Battery Cathodes Containing Agglomerates Cornut, R.; Lepage, D.; Schougaard, S. B. Journal of The Electrochemical Society, Vol. 159, Issue 6 https://doi.org/10.1149/2.081206jes	journal	January 2012
A kinetics and equilibrium study of vanadium dissolution from vanadium oxides and phosphates in battery electrolytes: Possible impacts on ICD battery performance Bock, David C.; Marschilok, Amy C.; Takeuchi, Kenneth J. Journal of Power Sources, Vol. 231 https://doi.org/10.1016/j.jpowsour.2013.01.012	journal	June 2013
Optimization of multicomponent aqueous suspensions of lithium iron phosphate (LiFePO₄) nanoparticles and carbon black for lithium-ion battery cathodes Li, Jianlin; Armstrong, Beth L.; Daniel, Claus Journal of Colloid and Interface Science, Vol. 405, p. 118-124 https://doi.org/10.1016/j.jcis.2013.05.030	journal	September 2013
Current issues in recrystallization: a review Doherty, R. D.; Hughes, D. A.; Humphreys, F. J. Materials Science and Engineering: A, Vol. 238, Issue 2 https://doi.org/10.1016/S0921-5093(97)00424-3	journal	November 1997
NIH Image to ImageJ: 25 years of image analysis Schneider, Caroline A.; Rasband, Wayne S.; Eliceiri, Kevin W. Nature Methods, Vol. 9, Issue 7 https://doi.org/10.1038/nmeth.2089	journal	June 2012
Hetaerolite Profiles in Alkaline Batteries Measured by High Energy EDXRD Gallaway, Joshua W.; Menard, Melissa; Hertzberg, Benjamin Journal of The Electrochemical Society, Vol. 162, Issue 1 https://doi.org/10.1149/2.0811501jes	journal	November 2014
In-situ electrochemical coating of Ag nanoparticles onto graphite electrode with enhanced performance for Li-ion batteries Yun, Jiaojiao; Wang, Yan; Gao, Tian Electrochimica Acta, Vol. 155 https://doi.org/10.1016/j.electacta.2014.12.129	journal	February 2015
An X-ray Absorption Spectroscopy Study of the Cathodic Discharge of Ag ₂ VO ₂ PO ₄ : Geometric and Electronic Structure Characterization of Intermediate phases and Mechanistic Insights Patridge, Christopher J.; Jaye, Cherno; Abtew, Tesfaye A. The Journal of Physical Chemistry C, Vol. 115, Issue 29 https://doi.org/10.1021/jp203924w	journal	July 2011
Effects of conducting carbon on the electrochemical performance of LiCoO2 and LiMn2O4 cathodes Liu, Zhaolin; Lee, Jim Y.; Lindner, H. J. Journal of Power Sources, Vol. 97-98 https://doi.org/10.1016/S0378-7753(01)00549-3	journal	July 2001
Effect of carbon additive on electrochemical performance of LiCoO2 composite cathodes Hong, Jin K.; Lee, Jong H.; Oh, Seung M. Journal of Power Sources, Vol. 111, Issue 1 https://doi.org/10.1016/S0378-7753(02)00264-1	journal	September 2002
Tracking inhomogeneity in high-capacity lithium iron phosphate batteries Paxton, William A.; Zhong, Zhong; Tsakalakos, Thomas Journal of Power Sources, Vol. 275 https://doi.org/10.1016/j.jpowsour.2014.11.035	journal	February 2015
Silver vanadium oxide and silver vanadium phosphorous oxide dissolution kinetics: a mechanistic study with possible impact on future ICD battery lifetimes Bock, David C.; Takeuchi, Kenneth J.; Marschilok, Amy C. Dalton Transactions, Vol. 42, Issue 38 https://doi.org/10.1039/c3dt51544c	journal	January 2013
Silver vanadium diphosphate Ag2VP2O8: Electrochemistry and characterization of reduced material providing mechanistic insights Takeuchi, Esther S.; Lee, Chia-Ying; Cheng, Po-Jen Journal of Solid State Chemistry, Vol. 200 https://doi.org/10.1016/j.jssc.2013.01.020	journal	April 2013
Experimental observation of nonuniversal behavior of the conductivity exponent for three-dimensional continuum percolation systems Lee, Sung-Ik; Song, Yi; Noh, Tae Won Physical Review B, Vol. 34, Issue 10 https://doi.org/10.1103/PhysRevB.34.6719	journal	November 1986
Mapping the Inhomogeneous Electrochemical Reaction Through Porous LiFePO ₄ -Electrodes in a Standard Coin Cell Battery Strobridge, Fiona C.; Orvananos, Bernardo; Croft, Mark Chemistry of Materials, Vol. 27, Issue 7 https://doi.org/10.1021/cm504317a	journal	March 2015
Recrystallization and texture Doherty, Roger D. Progress in Materials Science, Vol. 42, Issue 1-4 https://doi.org/10.1016/S0079-6425(97)00007-8	journal	January 1997
In situ X-ray diffraction of prototype sodium metal halide cells: Time and space electrochemical profiling Rijssenbeek, Job; Gao, Yan; Zhong, Zhong Journal of Power Sources, Vol. 196, Issue 4 https://doi.org/10.1016/j.jpowsour.2010.10.023	journal	February 2011
Structure Characterization and Ionic Conductivity of Ag2VP2O8 Daidouh, Abdelaali; Veiga, M. L.; Pico, C. Journal of Solid State Chemistry, Vol. 130, Issue 1 https://doi.org/10.1006/jssc.1996.7266	journal	April 1997
Energy dispersive X-ray diffraction of lithium–silver vanadium phosphorous oxide cells: in situ cathode depth profiling of an electrochemical reduction–displacement reaction Takeuchi, Esther S.; Marschilok, Amy C.; Takeuchi, Kenneth J. Energy & Environmental Science, Vol. 6, Issue 5 https://doi.org/10.1039/c3ee40152a	journal	January 2013
In situ visualization of Li/Ag2VP2O8 batteries revealing rate-dependent discharge mechanism Kirshenbaum, K.; Bock, D. C.; Lee, C. -Y. Science, Vol. 347, Issue 6218 https://doi.org/10.1126/science.1257289	journal	January 2015
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT Ravel, B.; Newville, M. Journal of Synchrotron Radiation, Vol. 12, Issue 4 https://doi.org/10.1107/S0909049505012719	journal	June 2005
Electrochemical Reduction of Silver Vanadium Phosphorus Oxide, Ag ₂ VO ₂ PO ₄ : The Formation of Electrically Conductive Metallic Silver Nanoparticles Takeuchi, Esther S.; Marschilok, Amy C.; Tanzil, Kevin Chemistry of Materials, Vol. 21, Issue 20 https://doi.org/10.1021/cm902102k	journal	October 2009
In situ profiling of lithium/Ag₂VP₂O₈ primary batteries using energy dispersive X-ray diffraction Kirshenbaum, Kevin C.; Bock, David C.; Zhong, Zhong Physical Chemistry Chemical Physics, Vol. 16, Issue 19, p. 9138-9147 https://doi.org/10.1039/C4CP01220H	journal	January 2014
Using all energy in a battery Dudney, N. J.; Li, J. Science, Vol. 347, Issue 6218 https://doi.org/10.1126/science.aaa2870	journal	January 2015
Energy-dispersive diffraction studies of inert anodes Scarlett, Nicola V. Y.; Madsen, Ian C.; Evans, John S. O. Journal of Applied Crystallography, Vol. 42, Issue 3 https://doi.org/10.1107/S0021889809008681	journal	May 2009
Percolation threshold of conducting polymer composites containing 3D randomly distributed graphite nanoplatelets Li, Jing; Kim, Jang-Kyo Composites Science and Technology, Vol. 67, Issue 10 https://doi.org/10.1016/j.compscitech.2006.11.010	journal	August 2007
Development of carbon conductive additives for advanced lithium ion batteries Spahr, Michael E.; Goers, Dietrich; Leone, Antonio Journal of Power Sources, Vol. 196, Issue 7 https://doi.org/10.1016/j.jpowsour.2010.07.002	journal	April 2011

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