Nickel(ii) and copper(i,ii)-based metal-organic frameworks incorporating an extended tris-pyrazolate linker

Tăbăcaru, Aurel; Galli, Simona; Pettinari, Claudio; Masciocchi, Norberto; McDonald, Thomas M.; Long, Jeffrey R.

doi:10.1039/c5ce00561b

Nickel(ii) and copper(i,ii)-based metal-organic frameworks incorporating an extended tris-pyrazolate linker

Journal Article · Wed May 20 04:00:00 EDT 2015 · CrystEngComm

DOI:https://doi.org/10.1039/c5ce00561b· OSTI ID:1385973

Tăbăcaru, Aurel ^[1]; Galli, Simona ^[2]; Pettinari, Claudio ^[1]; Masciocchi, Norberto ^[2]; McDonald, Thomas M. ^[3]; Long, Jeffrey R. ^[4]

Univ. of Camerino (Italy)
Univ. degli Studi di Insubria, Como (Italy)
Univ. of California, Berkeley, CA (United States)
Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Accelerator & Fusion Research Division

Solvothermal reactions between the tritopic pyrazole-based ligand 1,3,5-tris((1H-pyrazol-4-yl)phenyl)benzene (H₃BTPP) and nickel(II) perchlorate or copper(II) nitrate afforded two new metal-organic frameworks, Ni₃(BTPP)₂·solvent (Ni-BTPP) and Cu^I₄Cu^II₂(OH)₂(BTPP)₂·solvent (Cu-BTPP). Powder diffraction structure determination methods were employed to determine the crystal and molecular structure of the copper(I,II) derivative: triangular [Cu3N6(μ3-OH)] nodes are connected to six nearby ones by the pyrazolate ligands, thus constructing flat two-dimensional layers that stack to form slit-like one-dimensional channels. Thermogravimetric analyses highlighted both the thermal stability and the permanent porosity of these two materials. Porosity was confirmed by N₂ adsorption at 77 K, yielding Langmuir specific surface areas of 1923(3) m² g^-1 and 874(8) m² g^-1 for Ni-BTPP and Cu-BTPP, respectively. Additionally, Ni-BTPP adsorbed 1.73 mmol g^-1 (7.6 wt%) of CO₂ at the mild conditions of 298 K and 1 bar.

View Accepted Manuscript (DOE)

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0001015

OSTI ID:: 1385973

Journal Information:: CrystEngComm, Journal Name: CrystEngComm Journal Issue: 27 Vol. 17; ISSN CRECF4; ISSN 1466-8033

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (74)

Functional Porous Coordination Polymers Kitagawa, Susumu; Kitaura, Ryo; Noro, Shin-ichiro Angewandte Chemie International Edition, Vol. 43, Issue 18, p. 2334-2375 https://doi.org/10.1002/anie.200300610	journal	April 2004
Porous Coordination-Polymer Crystals with Gated Channels Specific for Supercritical Gases Kitaura, Ryo; Seki, Kenji; Akiyama, George Angewandte Chemie International Edition, Vol. 42, Issue 4 https://doi.org/10.1002/anie.200390130	journal	January 2003
Highly Selective CO ₂ Capture in Flexible 3D Coordination Polymer Networks Choi, Hye-Sun; Suh, Myunghyun Paik Angewandte Chemie International Edition, Vol. 48, Issue 37 https://doi.org/10.1002/anie.200902836	journal	September 2009
Self-Assembly and Anion-Exchange Properties of a Discrete Cage and 3D Coordination Networks Based on Cage Structures Wang, Ying; Cheng, Peng; Song, You Chemistry - A European Journal, Vol. 13, Issue 29 https://doi.org/10.1002/chem.200700431	journal	October 2007
Tuning the Functional Properties of Metal Complexes Containing Polytopic Heteroaromatic Nitrogen Ligands Pettinari, Claudio; Masciocchi, Norberto; Pandolfo, Luciano Chemistry - A European Journal, Vol. 16, Issue 4 https://doi.org/10.1002/chem.200901923	journal	January 2010
Functional Porous Coordination Polymers Kitagawa, Susumu; Kitaura, Ryo; Noro, Shin-ichiro ChemInform, Vol. 35, Issue 29 https://doi.org/10.1002/chin.200429230	journal	July 2004
Dynamic Porous Properties of Coordination Polymers Inspired by Hydrogen Bonds Kitagawa, Susumu; Uemura, Kazuhiro ChemInform, Vol. 36, Issue 17 https://doi.org/10.1002/chin.200517293	journal	April 2005
Structure and Magnetic Behavior of Cu ^II MOFs Supported by 1,2,4-Triazolyl-Bifunctionalized Adamantane Scaffold Senchyk, Ganna A.; Lysenko, Andrey B.; Rusanov, Eduard B. European Journal of Inorganic Chemistry, Vol. 2012, Issue 35 https://doi.org/10.1002/ejic.201200873	journal	October 2012
Anion Tuning of Cu(II)/4,4′-Bi-1,2,4-Triazole Coordination Polymers Govor, Evgen V.; Lysenko, Andrey B.; Rusanov, Eduard B. Zeitschrift für anorganische und allgemeine Chemie, Vol. 636, Issue 1 https://doi.org/10.1002/zaac.200900121	journal	January 2010
A series of POM-based hybrid materials with different copper/aminotriazole motifs Wu, Xiao-Yuan; Kuang, Xiao-Fei; Zhao, Zhen-Guo Inorganica Chimica Acta, Vol. 363, Issue 6 https://doi.org/10.1016/j.ica.2009.08.023	journal	April 2010
Hydrothermal syntheses of two novel coordination polymers based on tetranuclear metal cluster constructed by 1,3,5-Tris(2H-tetrazol-5-yl)benzene ligand Li, Mei-Na; Yang, Guang-Sheng; Li, Shun-Li Inorganic Chemistry Communications, Vol. 13, Issue 10 https://doi.org/10.1016/j.inoche.2010.06.050	journal	October 2010
Unusual coordination of a chloride ion to six copper ions: Synthesis and crystal structure of copper(II) complexes with 4-(4-hydroxyphenyl)-1,2,4-triazole Lider, Elisaveta V.; Peresypkina, Eugenia V.; Smolentsev, Anton I. Polyhedron, Vol. 26, Issue 8 https://doi.org/10.1016/j.poly.2006.11.051	journal	May 2007
Selective nitrosation of guanazine: preparation of azidoaminotriazole and nitrosoguanazine anion–Cu(II) complexes Bichay, Magdy; Fronabarger, John W.; Gilardi, Richard Tetrahedron Letters, Vol. 47, Issue 37 https://doi.org/10.1016/j.tetlet.2006.06.177	journal	September 2006
Equilibrium acidities in dimethyl sulfoxide solution Bordwell, Frederick G. Accounts of Chemical Research, Vol. 21, Issue 12 https://doi.org/10.1021/ar00156a004	journal	December 1988
Nanoscale Metal–Organic Frameworks for Biomedical Imaging and Drug Delivery Della Rocca, Joseph; Liu, Demin; Lin, Wenbin Accounts of Chemical Research, Vol. 44, Issue 10, p. 957-968 https://doi.org/10.1021/ar200028a	journal	October 2011
Porous and Nanorod-Like Coordination Polymers Assembled from a New V-Shaped Bis(1,2,4-triazolyl)tripyridine Ligand Yang, Peng; Li, Ming-Xing; Shao, Min Crystal Growth & Design, Vol. 13, Issue 10 https://doi.org/10.1021/cg400644k	journal	August 2013
Bis(pyrazolato)-Based Metal–Organic Frameworks Fabricated with 4,4′-Bis((3,5-dimethyl-1 H -pyrazol-4-yl)methyl)biphenyl and Late Transition Metals Tăbăcaru, Aurel; Pettinari, Claudio; Marchetti, Fabio Crystal Growth & Design, Vol. 14, Issue 6 https://doi.org/10.1021/cg500459v	journal	May 2014
Metal Azolate Frameworks: From Crystal Engineering to Functional Materials Zhang, Jie-Peng; Zhang, Yue-Biao; Lin, Jian-Bin Chemical Reviews, Vol. 112, Issue 2 https://doi.org/10.1021/cr200139g	journal	September 2011
Metal–Organic Frameworks for Separations Li, Jian-Rong; Sculley, Julian; Zhou, Hong-Cai Chemical Reviews, Vol. 112, Issue 2, p. 869-932 https://doi.org/10.1021/cr200190s	journal	September 2011
Commensurate Adsorption of Hydrocarbons and Alcohols in Microporous Metal Organic Frameworks Wu, Haohan; Gong, Qihan; Olson, David H. Chemical Reviews, Vol. 112, Issue 2 https://doi.org/10.1021/cr200216x	journal	September 2011
Metal–Organic Frameworks in Biomedicine Horcajada, Patricia; Gref, Ruxandra; Baati, Tarek Chemical Reviews, Vol. 112, Issue 2, p. 1232-1268 https://doi.org/10.1021/cr200256v	journal	September 2011
Hydrogen Storage in Metal–Organic Frameworks Suh, Myunghyun Paik; Park, Hye Jeong; Prasad, Thazhe Kootteri Chemical Reviews, Vol. 112, Issue 2, p. 782-835 https://doi.org/10.1021/cr200274s	journal	September 2011
Homochiral Metal–Organic Frameworks for Asymmetric Heterogeneous Catalysis Yoon, Minyoung; Srirambalaji, Renganathan; Kim, Kimoon Chemical Reviews, Vol. 112, Issue 2, p. 1196-1231 https://doi.org/10.1021/cr2003147	journal	September 2011
Carbon Dioxide Capture in Metal–Organic Frameworks Sumida, Kenji; Rogow, David L.; Mason, Jarad A. Chemical Reviews, Vol. 112, Issue 2, p. 724-781 https://doi.org/10.1021/cr2003272	journal	September 2011
Engineering Metal Organic Frameworks for Heterogeneous Catalysis Corma, A.; García, H.; Llabrés i Xamena, F. X. Chemical Reviews, Vol. 110, Issue 8, p. 4606-4655 https://doi.org/10.1021/cr9003924	journal	August 2010
Different Oxidation States of Copper(I, I/II, II) Thiocyanate Complexes Containing 1,2,4-Triazole as a Bridging Ligand: Syntheses, Crystal Structures, and Magnetic Properties of 2-D Polymer Cu ^I (admtrz)SCN, Linear Trinuclear [Cu ^I ₂ Cu ^II (admtrz) ₆ (SCN) ₂ ](ClO ₄ ) ₂ , and Triangular Trinuclear [Cu ^II ₃ (admtrz) ₄ (SCN) ₃ ( μ ₃ -OH)(H ₂ O)](ClO ₄ ) ₂ ·H ₂ O (admtrz = 4-Amino-3,5-dimethyl-1,2,4-triazole) Liu, Jia-Cheng; Huang, Jin-Shun Inorganic Chemistry, Vol. 42, Issue 1 https://doi.org/10.1021/ic0258173	journal	January 2003
Structural, Magnetic, and Electrical Characterization of New Polycrystalline Phases of Nickel- and Platinum-Doped [(DT-TTF) _n ][Au(mnt) ₂ ] ( n = 1, 2) Ribas, Xavi; Sironi, Angelo; Masciocchi, Norberto Inorganic Chemistry, Vol. 44, Issue 7 https://doi.org/10.1021/ic048484d	journal	April 2005
Spontaneous Self-Assembly of an Unsymmetric Trinuclear Triangular Copper(II) Pyrazolate Complex, [Cu ₃ (μ ₃ -OH)(μ-pz) ₃ (MeCOO) ₂ (Hpz)] (Hpz = Pyrazole). Synthesis, Experimental and Theoretical Characterization, Reactivity, and Catalytic Activity Casarin, Maurizio; Corvaja, Carlo; di Nicola, Corrado Inorganic Chemistry, Vol. 43, Issue 19 https://doi.org/10.1021/ic049260y	journal	September 2004
One-Dimensional and Two-Dimensional Coordination Polymers from Self-Assembling of Trinuclear Triangular Cu(II) Secondary Building Units Casarin, Maurizio; Corvaja, Carlo; Di Nicola, Corrado Inorganic Chemistry, Vol. 44, Issue 18 https://doi.org/10.1021/ic050678l	journal	September 2005
One-Dimensional Metal−Organic Framework with Unprecedented Heptanuclear Copper Units Ferrer, Sacramento; Aznar, Elena; Lloret, Francesc Inorganic Chemistry, Vol. 46, Issue 2 https://doi.org/10.1021/ic0619106	journal	January 2007
Novel Coordination Frameworks Incorporating the 4,4′-Bipyrazolyl Ditopic Ligand Pettinari, Claudio; Tăbăcaru, Aurel; Boldog, Ishtvan Inorganic Chemistry, Vol. 51, Issue 9 https://doi.org/10.1021/ic3001416	journal	April 2012
Highly Selective CO₂ Adsorption Accompanied with Low-Energy Regeneration in a Two-Dimensional Cu(II) Porous Coordination Polymer with Inorganic Fluorinated PF₆^– Anions Noro, Shin-ichiro; Hijikata, Yuh; Inukai, Munehiro Inorganic Chemistry, Vol. 52, Issue 1, p. 280-285 https://doi.org/10.1021/ic301823j	journal	December 2012
Pore Design of Two-Dimensional Coordination Polymers toward Selective Adsorption Hijikata, Yuh; Horike, Satoshi; Sugimoto, Masayuki Inorganic Chemistry, Vol. 52, Issue 7 https://doi.org/10.1021/ic302006x	journal	June 2012
Expanded Sodalite-Type Metal−Organic Frameworks: Increased Stability and H ₂ Adsorption through Ligand-Directed Catenation Dincǎ, Mircea; Dailly, Anne; Tsay, Charlene Inorganic Chemistry, Vol. 47, Issue 1 https://doi.org/10.1021/ic701917w	journal	January 2008
Synthesis, Crystal Structure, and Solution Properties of a Hexacopper(II) Complex with Bridging Hydroxides, Pyrazolates, and Nitrates Sakai, Ken; Yamada, Yasutaka; Tsubomura, Taro Inorganic Chemistry, Vol. 35, Issue 2 https://doi.org/10.1021/ic950181j	journal	January 1996
Hydrogen Storage in a Microporous Metal−Organic Framework with Exposed Mn ²⁺ Coordination Sites Dincǎ, Mircea; Dailly, Anne; Liu, Yun Journal of the American Chemical Society, Vol. 128, Issue 51 https://doi.org/10.1021/ja0656853	journal	December 2006
Supramolecular Isomerism, Framework Flexibility, Unsaturated Metal Center, and Porous Property of Ag(I)/Cu(I) 3,3‘,5,5‘-Tetrametyl-4,4‘-Bipyrazolate Zhang, Jie-Peng; Kitagawa, Susumu Journal of the American Chemical Society, Vol. 130, Issue 3 https://doi.org/10.1021/ja075408b	journal	January 2008
Single-Walled Polytetrazolate Metal–Organic Channels with High Density of Open Nitrogen-Donor Sites and Gas Uptake Lin, Qipu; Wu, Tao; Zheng, Shou-Tian Journal of the American Chemical Society, Vol. 134, Issue 2 https://doi.org/10.1021/ja2092882	journal	December 2011
Strong CO₂ Binding in a Water-Stable, Triazolate-Bridged Metal−Organic Framework Functionalized with Ethylenediamine Demessence, Aude; D’Alessandro, Deanna M.; Foo, Maw Lin Journal of the American Chemical Society, Vol. 131, Issue 25, p. 8784-8786 https://doi.org/10.1021/ja903411w	journal	July 2009
Mechanism for the Dynamic Adsorption of CO ₂ and CH ₄ in a Flexible Linear Chain Coordination Polymer as Determined from In Situ Infrared Spectroscopy Culp, Jeffrey T.; Goodman, A. L.; Chirdon, Danielle The Journal of Physical Chemistry C, Vol. 114, Issue 5 https://doi.org/10.1021/jp908202s	journal	January 2010
Novel Expansion/Shrinkage Modulation of 2D Layered MOF Triggered by Clathrate Formation with CO ₂ Molecules Kondo, Atsushi; Noguchi, Hiroshi; Ohnishi, Shunsuke Nano Letters, Vol. 6, Issue 11 https://doi.org/10.1021/nl062032b	journal	November 2006
Antisymmetric exchange in two tricopper( ii ) complexes containing a [Cu ₃ (μ ₃ -OMe)] ⁵⁺ core Liu, Xiaoming; de Miranda, Marcelo P.; McInnes, Eric J. L. Dalton Trans., Issue 1 https://doi.org/10.1039/B311980G	journal	January 2004
Metal–organic frameworks incorporating Cu ₃ (μ ₃ -OH) clusters Lysenko, Andrey B.; Govor, Evgen V.; Krautscheid, Harald Dalton Trans., Issue 31 https://doi.org/10.1039/B604804H	journal	January 2006
Hydrogenstorage in water-stable metal–organic frameworks incorporating 1,3- and 1,4-benzenedipyrazolate Choi, Hye Jin; Dincă, Mircea; Dailly, Anne Energy Environ. Sci., Vol. 3, Issue 1 https://doi.org/10.1039/B917512A	journal	January 2010
Structural diversity directed by switchable coordination of substitute groups in a ternary Cu ^II -triazole-sulfoisophthalate self-assembly system: synthesis, crystal structures and magnetic behavior Yang, En-Cui; Liu, Zhong-Yi; Zhang, Cui-Hua Dalton Trans., Vol. 42, Issue 5 https://doi.org/10.1039/C2DT31935G	journal	January 2013
A fluorite isoreticular series of porous framework complexes with tetrahedral ligands: new opportunities for azolate PCPs Boldog, Ishtvan; Domasevitch, Konstantin; Maclaren, Jana K. CrystEngComm, Vol. 16, Issue 2 https://doi.org/10.1039/C3CE42162G	journal	January 2014
Rational design of metal–organic frameworks with anticipated porosities and functionalities Zhang, Muwei; Bosch, Mathieu; Gentle III, Thomas CrystEngComm, Vol. 16, Issue 20 https://doi.org/10.1039/C4CE00321G	journal	January 2014
Adsorptive separation on metal–organic frameworks in the liquid phase Van de Voorde, Ben; Bueken, Bart; Denayer, Joeri Chem. Soc. Rev., Vol. 43, Issue 16 https://doi.org/10.1039/C4CS00006D	journal	January 2014
Methane storage in metal–organic frameworks He, Yabing; Zhou, Wei; Qian, Guodong Chem. Soc. Rev., Vol. 43, Issue 16 https://doi.org/10.1039/C4CS00032C	journal	January 2014
Water adsorption in MOFs: fundamentals and applications Canivet, Jérôme; Fateeva, Alexandra; Guo, Youmin Chem. Soc. Rev., Vol. 43, Issue 16 https://doi.org/10.1039/C4CS00078A	journal	January 2014
Applications of metal–organic frameworks in heterogeneous supramolecular catalysis Liu, Jiewei; Chen, Lianfen; Cui, Hao Chemical Society Reviews, Vol. 43, Issue 16, p. 6011-6061 https://doi.org/10.1039/C4CS00094C	journal	January 2014
Metal–organic framework membranes: from synthesis to separation application Qiu, Shilun; Xue, Ming; Zhu, Guangshan Chem. Soc. Rev., Vol. 43, Issue 16 https://doi.org/10.1039/C4CS00159A	journal	January 2014
When long bis(pyrazolates) meet late transition metals: structure, stability and adsorption of metal–organic frameworks featuring large parallel channels Galli, S.; Maspero, A.; Giacobbe, C. Journal of Materials Chemistry A, Vol. 2, Issue 31 https://doi.org/10.1039/C4TA01798F	journal	January 2014
Dynamic porous properties of coordination polymers inspired by hydrogen bonds Kitagawa, Susumu; Uemura, Kazuhiro Chemical Society Reviews, Vol. 34, Issue 2 https://doi.org/10.1039/b313997m	journal	January 2005
Luminescent metal–organic frameworks Allendorf, M. D.; Bauer, C. A.; Bhakta, R. K. Chemical Society Reviews, Vol. 38, Issue 5 https://doi.org/10.1039/b802352m	journal	January 2009
Adsorption properties and structure of CO2 adsorbed on open coordination sites of metal–organic framework Ni2(dhtp) from gas adsorption, IR spectroscopy and X-ray diffraction Dietzel, Pascal D. C.; Johnsen, Rune E.; Fjellvåg, Helmer Chemical Communications, Issue 41 https://doi.org/10.1039/b810574j	journal	January 2008
A novel metal–organic coordination polymer for selective adsorption of CO2 over CH4 Mu, Bin; Li, Feng; Walton, Krista S. Chemical Communications, Issue 18 https://doi.org/10.1039/b819828d	journal	January 2009
Framework-structured weak ferromagnets Weng, Dan-Feng; Wang, Zhe-Ming; Gao, Song Chemical Society Reviews, Vol. 40, Issue 6 https://doi.org/10.1039/c0cs00093k	journal	January 2011
Structure, adsorption and magnetic properties of chiral metal–organic frameworks bearing linear trinuclear secondary building blocks Chen, Zilu; Liu, Xianlin; Zhang, Chuanbing Dalton Transactions, Vol. 40, Issue 9 https://doi.org/10.1039/c0dt01278e	journal	January 2011
The coordination chemistry of Zn(ii), Cd(ii) and Hg(ii) complexes with 1,2,4-triazole derivatives Liu, Ke; Shi, Wei; Cheng, Peng Dalton Transactions, Vol. 40, Issue 34 https://doi.org/10.1039/c0dt01578d	journal	January 2011
High thermal and chemical stability in pyrazolate-bridged metal–organic frameworks with exposed metal sites Colombo, Valentina; Galli, Simona; Choi, Hye Jin Chemical Science, Vol. 2, Issue 7, p. 1311-1319 https://doi.org/10.1039/c1sc00136a	journal	January 2011
1,2,4-Triazole functionalized adamantanes: a new library of polydentate tectons for designing structures of coordination polymers Senchyk, Ganna A.; Lysenko, Andrey B.; Boldog, Ishtvan Dalton Transactions, Vol. 41, Issue 28 https://doi.org/10.1039/c2dt30362k	journal	January 2012
Theoretical and experimental characterization of pyrazolato-based Ni(ii) metal–organic frameworks Albanese, Elisa; Civalleri, Bartolomeo; Ferrabone, Matteo Journal of Materials Chemistry, Vol. 22, Issue 42 https://doi.org/10.1039/c2jm34079h	journal	January 2012
Engineering metal-based luminescence in coordination polymers and metal–organic frameworks Heine, Johanna; Müller-Buschbaum, Klaus Chemical Society Reviews, Vol. 42, Issue 24 https://doi.org/10.1039/c3cs60232j	journal	January 2013
Stability vs. reactivity: understanding the adsorption properties of Ni3(BTP)2 by experimental and computational methods Shearer, Greig C.; Colombo, Valentina; Chavan, Sachin Dalton Transactions, Vol. 42, Issue 18 https://doi.org/10.1039/c3dt32944e	journal	January 2013
Organosilicon linkers in metal organic frameworks: the tetrahedral tetrakis(4-tetrazolylphenyl)silane ligand Timokhin, Ivan; Baguña Torres, Júlia; White, Andrew J. P. Dalton Transactions, Vol. 42, Issue 38 https://doi.org/10.1039/c3dt51863a	journal	January 2013
Adsorption of Carbon Dioxide onto Activated Carbon and Nitrogen-Enriched Activated Carbon: Surface Changes, Equilibrium, and Modeling of Fixed-Bed Adsorption Dantas, Tirzhá L. P.; Amorim, Suélen M.; Luna, Francisco Murilo T. Separation Science and Technology, Vol. 45, Issue 1 https://doi.org/10.1080/01496390903401762	journal	December 2009
Indexing of powder diffraction patterns by iterative use of singular value decomposition Coelho, A. A. Journal of Applied Crystallography, Vol. 36, Issue 1 https://doi.org/10.1107/S0021889802019878	journal	January 2003
Single-crystal structure validation with the program PLATON Spek, A. L. Journal of Applied Crystallography, Vol. 36, Issue 1, p. 7-13 https://doi.org/10.1107/S0021889802022112	journal	January 2003
A fundamental parameters approach to X-ray line-profile fitting Cheary, R. W.; Coelho, A. Journal of Applied Crystallography, Vol. 25, Issue 2 https://doi.org/10.1107/S0021889891010804	journal	April 1992
Separation of Hexane Isomers in a Metal-Organic Framework with Triangular Channels Herm, Z. R.; Wiers, B. M.; Mason, J. A. Science, Vol. 340, Issue 6135, p. 960-964 https://doi.org/10.1126/science.1234071	journal	May 2013
Synthesis and characterization of the mixed valence Cu(l)/Cu(ll) 3,5-bis(trifluoromethyl)-pyrazolate complex, [Cu(ll) ₂ Cu(l)(F ₆ dmpz) ₅ ] Ehlert, Martin K.; Storr, Alan; Summers, David A. Canadian Journal of Chemistry, Vol. 75, Issue 5 https://doi.org/10.1139/v97-057	journal	May 1997
Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984) Sing, K. S. W. Pure and Applied Chemistry, Vol. 57, Issue 4, p. 603-619 https://doi.org/10.1351/pac198557040603	journal	January 1985
Nanoscale Metal–Organic Frameworks for Biomedical Imaging and Drug Delivery Wenbin, Lin,; Joseph, Della Rocca,; Demin, Liu, The University of North Carolina at Chapel Hill University Libraries https://doi.org/10.17615/q7c0-kf53	text	January 2011

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