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Title: Fluoride-free synthesis of a Sn-BEA catalyst by dry gel conversion

Abstract

A Sn-BEA catalyst was synthesized in a fluoride-free medium for the first timeviaa dry gel conversion method. The use of alkali ions, zeolite BEA seed crystals and ion-exchange before the removal of the organic template has been shown to be indispensable to obtain the desired material.

Authors:
 [1];  [1];  [1];  [1];  [1]
  1. Department of Chemical Engineering; University of Massachusetts Amherst; Amherst; USA
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Catalysis Center for Energy Innovation (CCEI)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1385933
DOE Contract Number:  
SC0001004
Resource Type:
Journal Article
Journal Name:
Green Chemistry
Additional Journal Information:
Journal Volume: 17; Journal Issue: 5; Related Information: CCEI partners with the University of Delaware (lead); Brookhaven National Laboratory; California Institute of Technology; Columbia University; University of Delaware; Lehigh University; University of Massachusetts, Amherst; Massachusetts Institute of Technology; University of Minnesota; Pacific Northwest National Laboratory; University of Pennsylvania; Princeton University; Rutgers University; Journal ID: ISSN 1463-9262
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
catalysis (homogeneous), catalysis (heterogeneous), biofuels (including algae and biomass), bio-inspired, hydrogen and fuel cells, materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly), synthesis (scalable processing)

Citation Formats

Chang, Chun-Chih, Cho, Hong Je, Wang, Zhuopeng, Wang, Xuanting, and Fan, Wei. Fluoride-free synthesis of a Sn-BEA catalyst by dry gel conversion. United States: N. p., 2015. Web. doi:10.1039/c4gc02457e.
Chang, Chun-Chih, Cho, Hong Je, Wang, Zhuopeng, Wang, Xuanting, & Fan, Wei. Fluoride-free synthesis of a Sn-BEA catalyst by dry gel conversion. United States. doi:10.1039/c4gc02457e.
Chang, Chun-Chih, Cho, Hong Je, Wang, Zhuopeng, Wang, Xuanting, and Fan, Wei. Thu . "Fluoride-free synthesis of a Sn-BEA catalyst by dry gel conversion". United States. doi:10.1039/c4gc02457e.
@article{osti_1385933,
title = {Fluoride-free synthesis of a Sn-BEA catalyst by dry gel conversion},
author = {Chang, Chun-Chih and Cho, Hong Je and Wang, Zhuopeng and Wang, Xuanting and Fan, Wei},
abstractNote = {A Sn-BEA catalyst was synthesized in a fluoride-free medium for the first timeviaa dry gel conversion method. The use of alkali ions, zeolite BEA seed crystals and ion-exchange before the removal of the organic template has been shown to be indispensable to obtain the desired material.},
doi = {10.1039/c4gc02457e},
journal = {Green Chemistry},
issn = {1463-9262},
number = 5,
volume = 17,
place = {United States},
year = {2015},
month = {1}
}

Works referenced in this record:

Al-Free Sn-Beta Zeolite as a Catalyst for the Selective Reduction of Carbonyl Compounds (Meerwein−Ponndorf−Verley Reaction)
journal, April 2002

  • Corma, Avelino; Domine, Marcelo E.; Nemeth, Laszlo
  • Journal of the American Chemical Society, Vol. 124, Issue 13, p. 3194-3195
  • DOI: 10.1021/ja012297m

Biofuels and Biomass-To-Liquid Fuels in the Biorefinery: Catalytic Conversion of Lignocellulosic Biomass using Porous Materials
journal, October 2008


“One-Pot” Synthesis of 5-(Hydroxymethyl)furfural from Carbohydrates using Tin-Beta Zeolite
journal, April 2011

  • Nikolla, Eranda; Román-Leshkov, Yuriy; Moliner, Manuel
  • ACS Catalysis, Vol. 1, Issue 4, p. 408-410
  • DOI: 10.1021/cs2000544

Catalytic consequences of borate complexation and pH on the epimerization of l-arabinose to l-ribose in water catalyzed by Sn-Beta zeolite with borate salts
journal, November 2013

  • Gunther, William R.; Duong, Quynh; Román-Leshkov, Yuriy
  • Journal of Molecular Catalysis A: Chemical, Vol. 379
  • DOI: 10.1016/j.molcata.2013.08.021

Liquid-Phase Catalytic Processing of Biomass-Derived Oxygenated Hydrocarbons to Fuels and Chemicals
journal, September 2007

  • Chheda, Juben N.; Huber, George W.; Dumesic, James A.
  • Angewandte Chemie International Edition, Vol. 46, Issue 38, p. 7164-7183
  • DOI: 10.1002/anie.200604274

Crystallization of high silica BEA by dry gel conversion
journal, January 1998


Unseeded synthesis of Al-free Ti-β zeolite in fluoride medium: a hydrophobic selective oxidation catalyst
journal, January 1996

  • Blasco, Teresa; Camblor, Miguel A.; Corma, Avelino
  • Chem. Commun., Issue 20
  • DOI: 10.1039/CC9960002367

Structure, Stability, and Lewis Acidity of Mono and Double Ti, Zr, and Sn Framework Substitutions in BEA Zeolites: A Periodic Density Functional Theory Study
journal, February 2013

  • Yang, Gang; Pidko, Evgeny A.; Hensen, Emiel J. M.
  • The Journal of Physical Chemistry C, Vol. 117, Issue 8
  • DOI: 10.1021/jp310433r

Zeolite-Catalyzed Isomerization of Triose Sugars
journal, July 2009

  • Taarning, Esben; Saravanamurugan, Shunmugavel; Spangsberg Holm, Martin
  • ChemSusChem, Vol. 2, Issue 7, p. 625-627
  • DOI: 10.1002/cssc.200900099

A roadmap for conversion of lignocellulosic biomass to chemicals and fuels
journal, August 2012

  • Wettstein, Stephanie G.; Alonso, David Martin; Gürbüz, Elif I.
  • Current Opinion in Chemical Engineering, Vol. 1, Issue 3
  • DOI: 10.1016/j.coche.2012.04.002

Beyond shape selective catalysis with zeolites: Hydrophobic void spaces in zeolites enable catalysis in liquid water
journal, January 2013

  • Gounder, Rajamani; Davis, Mark E.
  • AIChE Journal, Vol. 59, Issue 9, p. 3349-3358
  • DOI: 10.1002/aic.14016

Hierarchical Nanomanufacturing: From Shaped Zeolite Nanoparticles to High-Performance Separation Membranes
journal, October 2007

  • Snyder, Mark A.; Tsapatsis, Michael
  • Angewandte Chemie International Edition, Vol. 46, Issue 40, p. 7560-7573
  • DOI: 10.1002/anie.200604910

Chemical Routes for the Transformation of Biomass into Chemicals
journal, June 2007

  • Corma, Avelino; Iborra, Sara; Velty, Alexandra
  • Chemical Reviews, Vol. 107, Issue 6, p. 2411-2502
  • DOI: 10.1021/cr050989d

Peculiarities of Sn-Beta and potential industrial applications
journal, March 2007


Metal-containing zeolites as efficient catalysts for the transformation of highly valuable chiral biomass-derived products
journal, January 2013

  • Paris, Cecilia; Moliner, Manuel; Corma, Avelino
  • Green Chemistry, Vol. 15, Issue 8
  • DOI: 10.1039/c3gc40267c

Rapid synthesis of Sn-Beta for the isomerization of cellulosic sugars
journal, January 2012

  • Chang, Chun-Chih; Wang, Zhuopeng; Dornath, Paul
  • RSC Advances, Vol. 2, Issue 28
  • DOI: 10.1039/c2ra21381h

Aluminum-rich zeolite beta
journal, October 1997


Postsynthesis and Selective Oxidation Properties of Nanosized Sn-Beta Zeolite
journal, February 2011

  • Li, Pei; Liu, Guanqi; Wu, Haihong
  • The Journal of Physical Chemistry C, Vol. 115, Issue 9
  • DOI: 10.1021/jp1076966

Crystallization behavior of zeolite beta during steam-assisted crystallization of dry gel
journal, October 2002


Zeolite-based materials for novel catalytic applications: Opportunities, perspectives and open problems
journal, January 2012


Tin-containing silicates: structure-activity relations
journal, February 2012

  • Osmundsen, C. M.; Holm, M. S.; Dahl, S.
  • Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 468, Issue 2143, p. 2000-2016
  • DOI: 10.1098/rspa.2012.0047

Synthesis and Catalytic Activity of Sn-MFI Nanosheets for the Baeyer–Villiger Oxidation of Cyclic Ketones
journal, November 2012

  • Luo, Helen Y.; Bui, Linh; Gunther, William R.
  • ACS Catalysis, Vol. 2, Issue 12
  • DOI: 10.1021/cs300543z

Al-free Zr-zeolite beta as a regioselective catalyst in the Meerwein–Ponndorf–Verley reaction
journal, January 2003

  • Zhu, Yongzhong; Chuah, Gaikhuan; Jaenicke, Stephan
  • Chem. Commun., Issue 21
  • DOI: 10.1039/B309191K

Framework and Extraframework Tin Sites in Zeolite Beta React Glucose Differently
journal, November 2012

  • Bermejo-Deval, Ricardo; Gounder, Rajamani; Davis, Mark E.
  • ACS Catalysis, Vol. 2, Issue 12
  • DOI: 10.1021/cs300474x

Probing Lewis Acid Sites in Sn-Beta Zeolite
journal, February 2013

  • Roy, Sounak; Bakhmutsky, Kevin; Mahmoud, Eyas
  • ACS Catalysis, Vol. 3, Issue 4
  • DOI: 10.1021/cs300599z

Specific adsorption of saccharides by dealuminated Y-zeolites
journal, November 1993

  • Buttersack, Christoph; Wach, Wolfgang; Buchholz, Klaus
  • The Journal of Physical Chemistry, Vol. 97, Issue 46
  • DOI: 10.1021/j100148a003

Direct Synthesis and Characterization of Hydrophobic Aluminum-Free Ti−Beta Zeolite
journal, January 1998

  • Blasco, T.; Camblor, M. A.; Corma, A.
  • The Journal of Physical Chemistry B, Vol. 102, Issue 1
  • DOI: 10.1021/jp973288w

Effect of NH+4 Exchange on Hydrophobicity and Catalytic Properties of Al-Free Ti–Si–beta Zeolite
journal, April 2001

  • Ogura, Masaru; Nakata, Shin-ichi; Kikuchi, Eiichi
  • Journal of Catalysis, Vol. 199, Issue 1
  • DOI: 10.1006/jcat.2000.3156

Monosaccharide and disaccharide isomerization over Lewis acid sites in hydrophobic and hydrophilic molecular sieves
journal, December 2013


Conversion of Sugars to Lactic Acid Derivatives Using Heterogeneous Zeotype Catalysts
journal, April 2010

  • Holm, Martin Spangsberg; Saravanamurugan, Shunmugavel; Taarning, Esben
  • Science, Vol. 328, Issue 5978, p. 602-605
  • DOI: 10.1126/science.1183990

A novel method for the preparation of zeolite ZSM-5
journal, January 1990

  • Xu, Wenyang; Dong, Jinxiang; Li, Jinping
  • Journal of the Chemical Society, Chemical Communications, Issue 10
  • DOI: 10.1039/c39900000755

Sn-zeolite beta as a heterogeneous chemoselective catalyst for Baeyer–Villiger oxidations
journal, July 2001

  • Corma, Avelino; Nemeth, Laszlo T.; Renz, Michael
  • Nature, Vol. 412, Issue 6845
  • DOI: 10.1038/35086546

Xylose Isomerization to Xylulose and its Dehydration to Furfural in Aqueous Media
journal, October 2011

  • Choudhary, Vinit; Pinar, Ana B.; Sandler, Stanley I.
  • ACS Catalysis, Vol. 1, Issue 12
  • DOI: 10.1021/cs200461t

Synthesis of mesoporous TS-1 by hydrothermal and steam-assisted dry gel conversion techniques with the aid of triethanolamine
journal, November 2007


Productive sugar isomerization with highly active Sn in dealuminated β zeolites
journal, January 2013

  • Dijkmans, Jan; Gabriëls, Dries; Dusselier, Michiel
  • Green Chemistry, Vol. 15, Issue 10
  • DOI: 10.1039/c3gc41239c

The promotional effect of Sn-beta zeolites on platinum for the selective hydrogenation of α,β-unsaturated aldehydes
journal, January 2013

  • Concepción, Patricia; Pérez, Yolanda; Hernández-Garrido, J. C.
  • Physical Chemistry Chemical Physics, Vol. 15, Issue 29
  • DOI: 10.1039/c3cp50519g

Tin-containing zeolites are highly active catalysts for the isomerization of glucose in water
journal, March 2010

  • Moliner, M.; Roman-Leshkov, Y.; Davis, M. E.
  • Proceedings of the National Academy of Sciences, Vol. 107, Issue 14, p. 6164-6168
  • DOI: 10.1073/pnas.1002358107

One-Pot Synthesis of 5-(Ethoxymethyl)furfural from Glucose Using Sn-BEA and Amberlyst Catalysts
journal, March 2012

  • Lew, Christopher M.; Rajabbeigi, Nafiseh; Tsapatsis, Michael
  • Industrial & Engineering Chemistry Research, Vol. 51, Issue 14
  • DOI: 10.1021/ie2025536

Computer simulation of the interactions of tetraalkylammonium cations with ZSM-5 and ZSM-11
journal, October 1996


A rapid synthesis route for Sn-Beta zeolites by steam-assisted conversion and their catalytic performance in Baeyer–Villiger oxidation
journal, February 2013


Simple and Scalable Preparation of Highly Active Lewis Acidic Sn-β
journal, October 2012

  • Hammond, Ceri; Conrad, Sabrina; Hermans, Ive
  • Angewandte Chemie International Edition, Vol. 51, Issue 47
  • DOI: 10.1002/anie.201206193

Integration of Chemical and Biological Catalysis: Production of Furylglycolic Acid from Glucose via Cortalcerone
journal, October 2013

  • Schwartz, Thomas J.; Goodman, Samuel M.; Osmundsen, Christian M.
  • ACS Catalysis, Vol. 3, Issue 12
  • DOI: 10.1021/cs400593p

Mechanism of Glucose Isomerization Using a Solid Lewis Acid Catalyst in Water
journal, October 2010

  • Román-Leshkov, Yuriy; Moliner, Manuel; Labinger, Jay A.
  • Angewandte Chemie International Edition, Vol. 49, Issue 47, p. 8954-8957
  • DOI: 10.1002/anie.201004689