skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Polaron-ion correlations in Li x FePO 4 studied by x-ray nuclear resonant forward scattering at elevated pressure and temperature

Journal Article · · Physical Review. B, Condensed Matter and Materials Physics

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Energy Frontier Research in Extreme Environments (EFree)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
DOE Contract Number:
SC0001057
OSTI ID:
1385856
Journal Information:
Physical Review. B, Condensed Matter and Materials Physics, Vol. 90, Issue 9; Related Information: EFree partners with Carnegie Institution of Washington (lead); California Institute of Technology; Colorado School of Mines; Cornell University; Lehigh University; Pennsylvania State University; ISSN 1098-0121
Publisher:
American Physical Society (APS)
Country of Publication:
United States
Language:
English

References (52)

Anisotropy of Electronic and Ionic Transport in LiFePO[sub 4] Single Crystals journal January 2007
Reaction behavior of LiFePO4 as a cathode material for rechargeable lithium batteries journal June 2002
Toward Understanding of Electrical Limitations (Electronic, Ionic) in LiMPO[sub 4] (M=Fe, Mn) Electrode Materials journal January 2005
Ab initio study of the migration of small polarons in olivine Li x FePO 4 and their association with lithium ions and vacancies journal March 2006
A multipurpose miniature diamond anvil cell journal March 1990
Dependence on pressure of conduction by hopping of small polarons in minerals of the Earth's lower mantle journal December 1999
High-temperature storage and cycling of C-LiFePO4/graphite Li-ion cells journal July 2005
Electronically conductive phospho-olivines as lithium storage electrodes journal September 2002
Studies of polaron motion journal November 1959
Phase Diagram of Li[sub x]FePO[sub 4] journal January 2006
Electronic, Optical, and Magnetic Properties of LiFePO 4 :  Small Magnetic Polaron Effects journal July 2007
Experimental visualization of lithium diffusion in LixFePO4 journal August 2008
Simultaneous enhancement of electronic and Li + ion conductivity in LiFePO 4 journal July 2012
Conduction in glasses containing transition metal ions journal December 1968
VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data journal October 2011
A Critical Review of the Li Insertion Mechanisms in LiFePO 4 Electrodes journal January 2013
Mössbauer Spectrometry Study of Thermally-Activated Electronic Processes in Li x FePO 4 journal January 2009
Mössbauer Spectra in a Fluctuating Environment journal January 1968
Evaluation of time-differential measurements of nuclear-resonance scattering of x rays journal April 1994
Ferric iron dependence of the electrical conductivity of the Earth´s lower mantle material
  • Poirier, J. P.; Goddat, A.; Peyronneau, J.
  • Philosophical Transactions of the Royal Society of London. Series A: Mathematical, Physical and Engineering Sciences, Vol. 354, Issue 1711, p. 1361-1369 https://doi.org/10.1098/rsta.1996.0052
journal June 1996
Coupled Ion/Electron Hopping in Li x NiO 2 :  A 7 Li NMR Study journal February 2006
Electronic Conductivity and Defect Chemistry of Heterosite FePO4 journal April 2011
Valence Fluctuations of 57 Fe in Disordered Li 0.6 FePO 4 journal February 2007
Studies of polaron motion journal November 1959
A review of conduction phenomena in Li-ion batteries journal December 2010
The electrical conductivity of the lower mantle phase magnesiowüstite at high temperatures and pressures journal January 2000
Phospho-olivines as Positive-Electrode Materials for Rechargeable Lithium Batteries journal April 1997
Nonstoichiometric LiFePO 4 : Defects and Related Properties journal April 2009
Theory of one-dimensional hopping conductivity and diffusion journal August 1977
Origin of valence and core excitations in LiFePO 4 and FePO 4 journal June 2010
Mössbauer Spectra in a Fluctuating Environment II. Randomly Varying Electric Field Gradients journal January 1968
Raman and FTIR Spectroscopic Study of Li[sub x]FePO[sub 4] (0≤x≤1) journal January 2004
The existence of a temperature-driven solid solution in LixFePO4 for 0 ≤ x ≤ 1 journal February 2005
Elastic properties of olivine Li x FePO 4 from first principles journal May 2006
Li Conductivity in Li[sub x]MPO[sub 4] (M = Mn, Fe, Co, Ni) Olivine Materials journal January 2004
Low hole polaron migration barrier in lithium peroxide journal February 2012
The effect of mixed Mn valences on Li migration in LiMn2O4 spinel: A molecular dynamics study journal January 2004
Ionic and electronic transport in single crystalline LiFePO4 grown by optical floating zone technique journal September 2008
Diamond anvil cell and high-pressure physical investigations journal January 1983
The electronic structure and band gap of LiFePO4 and LiMnPO4 journal October 2004
Diffusive behavior in Li M PO 4 with M = Fe , Co, Ni probed by muon-spin relaxation journal February 2012
Lithium extraction/insertion in LiFePO4: an X-ray diffraction and Mössbauer spectroscopy study journal May 2000
CONUSS and PHOENIX: Evaluation of nuclear resonant scattering data journal March 2000
Polarons in crystalline and non-crystalline materials journal January 1969
Small Polaron Hopping in Li x FePO 4 Solid Solutions:  Coupled Lithium-Ion and Electron Mobility journal September 2006
Enhancement of electronic conductivity of LiFePO 4 by Cr doping and its identification by first-principles calculations journal November 2003
A Mathematical Model for the Narrowing of Spectral Lines by Exchange or Motion journal May 1954
Phonon-assisted transition rates I. Optical-phonon-assisted hopping in solids journal May 1975
Determination of the chemical diffusion coefficient of lithium in LiFePO4 journal May 2002
Phonons and Thermodynamics of Unmixed and Disordered Li 0.6 FePO 4 journal November 2006
Electronic Structure and Electrical Conductivity of Undoped LiFePO[sub 4] journal January 2004
Electrical conductivity of the Earth's lower mantle journal December 1993