Cation-Dependent Intrinsic Electrical Conductivity in Isostructural Tetrathiafulvalene-Based Microporous Metal–Organic Frameworks

Park, Sarah S.; Hontz, Eric R.; Sun, Lei; Hendon, Christopher H.; Walsh, Aron; Van Voorhis, Troy; Dincă, Mircea

doi:10.1021/ja512437u

Cation-Dependent Intrinsic Electrical Conductivity in Isostructural Tetrathiafulvalene-Based Microporous Metal–Organic Frameworks

Journal Article · Thu Jan 29 00:00:00 EST 2015 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/ja512437u· OSTI ID:1170238

Park, Sarah S. ^[1]; Hontz, Eric R. ^[1]; Sun, Lei ^[1]; Hendon, Christopher H. ^[2]; Walsh, Aron ^[2]; Van Voorhis, Troy ^[1]; Dincă, Mircea ^[1]

Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States
Department of Chemistry, University of Bath, Claverton Down, Bath BA2 7AY, United Kingdom

Not Available

View Journal Article

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Excitonics (CE)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0001088; SC0006937

OSTI ID:: 1170238

Alternate ID(s):: OSTI ID: 1210696
OSTI ID: 1385577

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 5 Vol. 137; ISSN 0002-7863

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (50)

25th Anniversary Article: Key Points for High-Mobility Organic Field-Effect Transistors Dong, Huanli; Fu, Xiaolong; Liu, Jie Advanced Materials, Vol. 25, Issue 43 https://doi.org/10.1002/adma.201302514	journal	September 2013
How Chemistry and Physics Meet in the Solid State Hoffmann, Roald Angewandte Chemie International Edition in English, Vol. 26, Issue 9 https://doi.org/10.1002/anie.198708461	journal	September 1987
Electron Transfer Reactions in Chemistry: Theory and Experiment (Nobel Lecture) Marcus, Rudolph A. Angewandte Chemie International Edition in English, Vol. 32, Issue 8 https://doi.org/10.1002/anie.199311113	journal	August 1993
Dramatically Different Conductivity Properties of Metal-Organic Framework Polymorphs of Tl(TCNQ): An Unexpected Room-Temperature Crystal-to-Crystal Phase Transition Avendano, Carolina; Zhang, Zhongyue; Ota, Akira Angewandte Chemie International Edition, Vol. 50, Issue 29 https://doi.org/10.1002/anie.201100372	journal	June 2011
Mehrstufige reversible Redoxsysteme, LIV. Leitfähige CT-Komplexe des Tetrathiafulvalens (TTF) mit Tetracyanchinodimethan (TCNQ) undN,N′-Dicyanbenzochinondiimin (DCNQI) - ein Vergleich Aumüller, Alexander; Erk, Peter; Hünig, Siegfried Chemische Berichte, Vol. 124, Issue 6 https://doi.org/10.1002/cber.19911240620	journal	June 1991
A Roadmap to Implementing Metal-Organic Frameworks in Electronic Devices: Challenges and Critical Directions Allendorf, Mark D.; Schwartzberg, Adam; Stavila, Vitalie Chemistry - A European Journal, Vol. 17, Issue 41, p. 11372-11388 https://doi.org/10.1002/chem.201101595	journal	September 2011
Porous, Conductive Metal-Triazolates and Their Structural Elucidation by the Charge-Flipping Method Gándara, Felipe; Uribe-Romo, Fernando J.; Britt, David K. Chemistry - A European Journal, Vol. 18, Issue 34, p. 10595-10601 https://doi.org/10.1002/chem.201103433	journal	June 2012
Ionic Conductivity in the Metal-Organic Framework UiO-66 by Dehydration and Insertion of Lithium tert -Butoxide Ameloot, Rob; Aubrey, Michael; Wiers, Brian M. Chemistry - A European Journal, Vol. 19, Issue 18 https://doi.org/10.1002/chem.201300326	journal	March 2013
On the crystallography of the TTF-TCNQ salt at reduced temperatures Blessing, R. H.; Coppens, P. Solid State Communications, Vol. 15, Issue 2 https://doi.org/10.1016/0038-1098(74)90744-3	journal	July 1974
Dithiolene radicals: Sulfur K-edge X-ray absorption spectroscopy and Harry's intuition Sproules, Stephen; Wieghardt, Karl Coordination Chemistry Reviews, Vol. 255, Issue 7-8 https://doi.org/10.1016/j.ccr.2010.12.006	journal	April 2011
Comprehensive Approach to Intrinsic Charge Carrier Mobility in Conjugated Organic Molecules, Macromolecules, and Supramolecular Architectures Saeki, Akinori; Koizumi, Yoshiko; Aida, Takuzo Accounts of Chemical Research, Vol. 45, Issue 8 https://doi.org/10.1021/ar200283b	journal	May 2012
An Orbital Rule for Electron Transport in Molecules Yoshizawa, Kazunari Accounts of Chemical Research, Vol. 45, Issue 9 https://doi.org/10.1021/ar300075f	journal	June 2012
Interaction of orbitals through space and through bonds Hoffmann, Roald Accounts of Chemical Research, Vol. 4, Issue 1 https://doi.org/10.1021/ar50037a001	journal	January 1971
Band Gap Engineering of Paradigm MOF-5 Yang, Li-Ming; Fang, Guo-Yong; Ma, Jing Crystal Growth & Design, Vol. 14, Issue 5 https://doi.org/10.1021/cg500243s	journal	April 2014
Conductivity, Doping, and Redox Chemistry of a Microporous Dithiolene-Based Metal−Organic Framework Kobayashi, Yoji; Jacobs, Benjamin; Allendorf, Mark D. Chemistry of Materials, Vol. 22, Issue 14 https://doi.org/10.1021/cm101238m	journal	July 2010
New Porous Crystals of Extended Metal-Catecholates Hmadeh, Mohamad; Lu, Zheng; Liu, Zheng Chemistry of Materials, Vol. 24, Issue 18, p. 3511-3513 https://doi.org/10.1021/cm301194a	journal	August 2012
Metal–Organic Frameworks for Separations Li, Jian-Rong; Sculley, Julian; Zhou, Hong-Cai Chemical Reviews, Vol. 112, Issue 2, p. 869-932 https://doi.org/10.1021/cr200190s	journal	September 2011
Commensurate Adsorption of Hydrocarbons and Alcohols in Microporous Metal Organic Frameworks Wu, Haohan; Gong, Qihan; Olson, David H. Chemical Reviews, Vol. 112, Issue 2 https://doi.org/10.1021/cr200216x	journal	September 2011
Hydrogen Storage in Metal–Organic Frameworks Suh, Myunghyun Paik; Park, Hye Jeong; Prasad, Thazhe Kootteri Chemical Reviews, Vol. 112, Issue 2, p. 782-835 https://doi.org/10.1021/cr200274s	journal	September 2011
Metal–Organic Framework Materials as Chemical Sensors Kreno, Lauren E.; Leong, Kirsty; Farha, Omar K. Chemical Reviews, Vol. 112, Issue 2, p. 1105-1125 https://doi.org/10.1021/cr200324t	journal	September 2011
Carbon Dioxide Capture in Metal–Organic Frameworks Sumida, Kenji; Rogow, David L.; Mason, Jarad A. Chemical Reviews, Vol. 112, Issue 2, p. 724-781 https://doi.org/10.1021/cr2003272	journal	September 2011
Noninnocence in Metal Complexes: A Dithiolene Dawn Eisenberg, Richard; Gray, Harry B. Inorganic Chemistry, Vol. 50, Issue 20 https://doi.org/10.1021/ic2011748	journal	October 2011
Electroconductive Porous Coordination Polymer Cu[Cu(pdt) ₂ ] Composed of Donor and Acceptor Building Units Takaishi, Shinya; Hosoda, Miyuki; Kajiwara, Takashi Inorganic Chemistry, Vol. 48, Issue 19 https://doi.org/10.1021/ic802117q	journal	October 2009
A Solid Lithium Electrolyte via Addition of Lithium Isopropoxide to a Metal–Organic Framework with Open Metal Sites Wiers, Brian M.; Foo, Maw-Lin; Balsara, Nitash P. Journal of the American Chemical Society, Vol. 133, Issue 37 https://doi.org/10.1021/ja205827z	journal	September 2011
High Charge Mobility in a Tetrathiafulvalene-Based Microporous Metal–Organic Framework Narayan, Tarun C.; Miyakai, Tomoyo; Seki, Shu Journal of the American Chemical Society, Vol. 134, Issue 31 https://doi.org/10.1021/ja3059827	journal	July 2012
Energy Transfer from Quantum Dots to Metal–Organic Frameworks for Enhanced Light Harvesting Jin, Shengye; Son, Ho-Jin; Farha, Omar K. Journal of the American Chemical Society, Vol. 135, Issue 3 https://doi.org/10.1021/ja3097114	journal	January 2013
π-Conjugated Nickel Bis(dithiolene) Complex Nanosheet Kambe, Tetsuya; Sakamoto, Ryota; Hoshiko, Ken Journal of the American Chemical Society, Vol. 135, Issue 7 https://doi.org/10.1021/ja312380b	journal	February 2013
Mn ₂ (2,5-disulfhydrylbenzene-1,4-dicarboxylate): A Microporous Metal–Organic Framework with Infinite (−Mn–S−) _∞ Chains and High Intrinsic Charge Mobility Sun, Lei; Miyakai, Tomoyo; Seki, Shu Journal of the American Chemical Society, Vol. 135, Issue 22 https://doi.org/10.1021/ja4037516	journal	May 2013
Chirality Driven Metallic versus Semiconducting Behavior in a Complete Series of Radical Cation Salts Based on Dimethyl-Ethylenedithio-Tetrathiafulvalene (DM-EDT-TTF) Pop, Flavia; Auban-Senzier, Pascale; Frąckowiak, Arkadiusz Journal of the American Chemical Society, Vol. 135, Issue 45 https://doi.org/10.1021/ja408350r	journal	October 2013
Electronic Chemical Potentials of Porous Metal–Organic Frameworks Butler, Keith T.; Hendon, Christopher H.; Walsh, Aron Journal of the American Chemical Society, Vol. 136, Issue 7 https://doi.org/10.1021/ja4110073	journal	February 2014
Long-Range Electron Tunneling Winkler, Jay R.; Gray, Harry B. Journal of the American Chemical Society, Vol. 136, Issue 8 https://doi.org/10.1021/ja500215j	journal	February 2014
High Electrical Conductivity in Ni ₃ (2,3,6,7,10,11-hexaiminotriphenylene) ₂ , a Semiconducting Metal–Organic Graphene Analogue Sheberla, Dennis; Sun, Lei; Blood-Forsythe, Martin A. Journal of the American Chemical Society, Vol. 136, Issue 25 https://doi.org/10.1021/ja502765n	journal	April 2014
Engineering of Band Gap in Metal–Organic Frameworks by Functionalizing Organic Linker: A Systematic Density Functional Theory Investigation Pham, Hung Q.; Mai, Toan; Pham-Tran, Nguyen-Nguyen The Journal of Physical Chemistry C, Vol. 118, Issue 9 https://doi.org/10.1021/jp405997r	journal	February 2014
Two-dimensional charge transport in self-organized, high-mobility conjugated polymers Sirringhaus, H.; Brown, P. J.; Friend, R. H. Nature, Vol. 401, Issue 6754, p. 685-688 https://doi.org/10.1038/44359	journal	October 1999
Synthetic design of crystalline inorganic chalcogenides exhibiting fast-ion conductivity Zheng, Nanfeng; Bu, Xianhui; Feng, Pingyun Nature, Vol. 426, Issue 6965 https://doi.org/10.1038/nature02159	journal	November 2003
Spongy chalcogels of non-platinum metals act as effective hydrodesulfurization catalysts Bag, Santanu; Gaudette, Amy F.; Bussell, Mark E. Nature Chemistry, Vol. 1, Issue 3 https://doi.org/10.1038/nchem.208	journal	May 2009
Quantifying through-space charge transfer dynamics in π-coupled molecular systems Batra, Arunabh; Kladnik, Gregor; Vázquez, Héctor Nature Communications, Vol. 3, Issue 1 https://doi.org/10.1038/ncomms2083	journal	January 2012
Electrical conductive coordination polymers Givaja, Gonzalo; Amo-Ochoa, Pilar; Gómez-García, Carlos J. Chem. Soc. Rev., Vol. 41, Issue 1 https://doi.org/10.1039/C1CS15092H	journal	January 2012
Dynamic magnetic MOFs Coronado, Eugenio; Mínguez Espallargas, Guillermo Chem. Soc. Rev., Vol. 42, Issue 4 https://doi.org/10.1039/C2CS35278H	journal	January 2013
An electroactive porous network from covalent metal–dithiolene links Cui, Jieshun; Xu, Zhengtao Chem. Commun., Vol. 50, Issue 30 https://doi.org/10.1039/C4CC00408F	journal	January 2014
Band gap modulation of functionalized metal–organic frameworks Musho, Terence; Li, Jiangtan; Wu, Nianqiang Phys. Chem. Chem. Phys., Vol. 16, Issue 43 https://doi.org/10.1039/C4CP03110E	journal	January 2014
Methane storage in metal–organic frameworks He, Yabing; Zhou, Wei; Qian, Guodong Chem. Soc. Rev., Vol. 43, Issue 16 https://doi.org/10.1039/C4CS00032C	journal	January 2014
MOF-based electronic and opto-electronic devices Stavila, V.; Talin, A. A.; Allendorf, M. D. Chem. Soc. Rev., Vol. 43, Issue 16 https://doi.org/10.1039/C4CS00096J	journal	January 2014
Hydrogen storage in metal–organic frameworks Murray, Leslie J.; Dincă, Mircea; Long, Jeffrey R. Chemical Society Reviews, Vol. 38, Issue 5, p. 1294-1314 https://doi.org/10.1039/b802256a	journal	January 2009
Microporous magnets Dechambenoit, Pierre; Long, Jeffrey R. Chemical Society Reviews, Vol. 40, Issue 6 https://doi.org/10.1039/c0cs00167h	journal	January 2011
Structure of two polymorphs of the TTF-TCNE charge-transfer complex and the degree of ionicity Clemente, Dore Augusto; Marzotto, Armando Journal of Materials Chemistry, Vol. 6, Issue 6 https://doi.org/10.1039/jm9960600941	journal	January 1996
Structural phase transition and disorder in tetrathiafulvalenium chloride [(TTF)Cl _x ] Williams, R.; Lowe Ma, C.; Samson, S. The Journal of Chemical Physics, Vol. 72, Issue 6 https://doi.org/10.1063/1.439592	journal	March 1980
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Shannon, R. D. Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767 https://doi.org/10.1107/S0567739476001551	journal	September 1976
The Chemistry and Applications of Metal-Organic Frameworks Furukawa, H.; Cordova, K. E.; O'Keeffe, M. Science, Vol. 341, Issue 6149, p. 1230444-1230444 https://doi.org/10.1126/science.1230444	journal	August 2013
Tunable Electrical Conductivity in Metal-Organic Framework Thin-Film Devices Talin, A. Alec; Centrone, Andrea; Ford, Alexandra C. Science, Vol. 343, Issue 6166, p. 66-69 https://doi.org/10.1126/science.1246738	journal	December 2013

Similar Records

Cation-Dependent Intrinsic Electrical Conductivity in Isostructural Tetrathiafulvalene-Based Microporous Metal–Organic Frameworks

Journal Article · Tue Feb 10 23:00:00 EST 2015 · J. Am. Chem. Soc. · OSTI ID:1210696

Electrically Conductive Metal–Organic Frameworks

Journal Article · Thu Apr 09 20:00:00 EDT 2020 · Chemical Reviews · OSTI ID:1615048

Related Subjects

14 SOLAR ENERGY
36 MATERIALS SCIENCE
solar (photovoltaic)
solid state lighting
photosynthesis (natural and artificial)
charge transport
optics
synthesis (novel materials)
synthesis (self-assembly)
synthesis (scalable processing)

Cation-Dependent Intrinsic Electrical Conductivity in Isostructural Tetrathiafulvalene-Based Microporous Metal–Organic Frameworks

Citation Formats

References (50)

Similar Records

Related Subjects