Efficient Solid Acid Catalyst Containing Lewis and Brønsted Acid Sites for the Production of Furfurals

Mazzotta, Michael G.; Gupta, Dinesh; Saha, Basudeb; Patra, Astam K.; Bhaumik, Asim; Abu-Omar, Mahdi M.

doi:10.1002/cssc.201402007

Efficient Solid Acid Catalyst Containing Lewis and Brønsted Acid Sites for the Production of Furfurals

Journal Article · Wed May 07 04:00:00 EDT 2014 · ChemSusChem

DOI:https://doi.org/10.1002/cssc.201402007· OSTI ID:1384975

Mazzotta, Michael G.; Gupta, Dinesh; Saha, Basudeb; Patra, Astam K.; Bhaumik, Asim; Abu-Omar, Mahdi M.

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Direct Catalytic Conversion of Biomass to Biofuels (C3Bio)

Sponsoring Organization:: USDOE SC Office of Basic Energy Sciences (SC-22)

OSTI ID:: 1384975

Journal Information:: ChemSusChem, Journal Name: ChemSusChem Journal Issue: 8 Vol. 7; ISSN 1864-5631

Publisher:: ChemPubSoc Europe

Country of Publication:: United States

Language:: English

References (42)

Versatile mesoporous carbonaceous materials for acid catalysis Budarin, Vitaly L.; Clark, James H.; Luque, Rafael Chem. Commun., Issue 6 https://doi.org/10.1039/B614537J	journal	January 2007
Efficient process for conversion of fructose to 5-hydroxymethylfurfural with ionic liquids Qi, Xinhua; Watanabe, Masaru; Aida, Taku M. Green Chemistry, Vol. 11, Issue 9 https://doi.org/10.1039/b905975j	journal	January 2009
Production of 5-Hydroxymethylfurfural from Glucose Using a Combination of Lewis and Brønsted Acid Catalysts in Water in a Biphasic Reactor with an Alkylphenol Solvent Pagán-Torres, Yomaira J.; Wang, Tianfu; Gallo, Jean Marcel R. ACS Catalysis, Vol. 2, Issue 6, p. 930-934 https://doi.org/10.1021/cs300192z	journal	April 2012
Synthesis, Characterization, and Biofuel Application of Mesoporous Zirconium Oxophosphates Das, Swapan K.; Bhunia, Manas K.; Sinha, Anil K. ACS Catalysis, Vol. 1, Issue 5 https://doi.org/10.1021/cs200005z	journal	April 2011
Synthesis of Furfural from Xylose, Xylan, and Biomass Using AlCl3⋅6 H2O in Biphasic Media via Xylose Isomerization to Xylulose Yang, Yu; Hu, Chang-Wei; Abu-Omar, Mahdi M. ChemSusChem, Vol. 5, Issue 2 https://doi.org/10.1002/cssc.201100688	journal	February 2012
A Study of the Acid-Catalyzed Hydrolysis of Cellulose Dissolved in Ionic Liquids and the Factors Influencing the Dehydration of Glucose and the Formation of Humins Dee, Sean J.; Bell, Alexis T. ChemSusChem, Vol. 4, Issue 8 https://doi.org/10.1002/cssc.201000426	journal	August 2011
Direct conversion of cellulose and lignocellulosic biomass into chemicals and biofuel with metal chloride catalysts Dutta, Saikat; De, Sudipta; Alam, Md. Imteyaz Journal of Catalysis, Vol. 288, p. 8-15 https://doi.org/10.1016/j.jcat.2011.12.017	journal	April 2012
Simple Chemical Transformation of Lignocellulosic Biomass into Furans for Fuels and Chemicals Binder, Joseph B.; Raines, Ronald T. Journal of the American Chemical Society, Vol. 131, Issue 5, p. 1979-1985 https://doi.org/10.1021/ja808537j	journal	February 2009
Synthesis of Furfural from Xylose and Xylan Binder, Joseph B.; Blank, Jacqueline J.; Cefali, Anthony V. ChemSusChem, Vol. 3, Issue 11 https://doi.org/10.1002/cssc.201000181	journal	September 2010
Selective Conversion of Fructose to 5-Hydroxymethylfurfural Catalyzed by Tungsten Salts at Low Temperatures Chan, Jin Young Gerentt; Zhang, Yugen ChemSusChem, Vol. 2, Issue 8 https://doi.org/10.1002/cssc.200900117	journal	August 2009
High selective production of 5-hydroymethylfurfural from fructose by a solid heteropolyacid catalyst Zhao, Qian; Wang, Lei; Zhao, Shun Fuel, Vol. 90, Issue 6 https://doi.org/10.1016/j.fuel.2011.02.022	journal	June 2011
Solid-acid and ionic-liquid catalyzed one-pot transformation of biorenewable substrates into a platform chemical and a promising biofuel Imteyaz Alam, Md.; De, Sudipta; Dutta, Saikat RSC Advances, Vol. 2, Issue 17 https://doi.org/10.1039/c2ra20574b	journal	January 2012
Green chemistry: Biodiesel made with sugar catalyst Toda, Masakazu; Takagaki, Atsushi; Okamura, Mai Nature, Vol. 438, Issue 7065, p. 178-178 https://doi.org/10.1038/438178a	journal	November 2005
One pot production of 5-hydroxymethylfurfural with high yield from cellulose by a Brønsted–Lewis–surfactant-combined heteropolyacid catalyst Zhao, Shun; Cheng, Mingxing; Li, Junzi Chemical Communications, Vol. 47, Issue 7 https://doi.org/10.1039/c0cc04444j	journal	January 2011
Conversion of mono/di/polysaccharides into furan compounds using 1-alkyl-3-methylimidazolium ionic liquids Lima, Sérgio; Neves, Patrícia; Antunes, Maria M. Applied Catalysis A: General, Vol. 363, Issue 1-2 https://doi.org/10.1016/j.apcata.2009.04.049	journal	July 2009
Catalytic Conversion of Carbohydrates into 5-Hydroxymethylfurfural by Germanium(IV) Chloride in Ionic Liquids Zhang, Zehui; Wang, Qian; Xie, Haibo ChemSusChem, Vol. 4, Issue 1 https://doi.org/10.1002/cssc.201000279	journal	December 2010
Catalytic glucose and fructose conversions with TiO2 and ZrO2 in water at 473K: Relationship between reactivity and acid–base property determined by TPD measurement Watanabe, Masaru; Aizawa, Yuichi; Iida, Toru Applied Catalysis A: General, Vol. 295, Issue 2 https://doi.org/10.1016/j.apcata.2005.08.007	journal	November 2005
Synthesis of 5-Hydroxymethylfurural from Carbohydrates using Large-Pore Mesoporous Tin Phosphate Dutta, Arghya; Gupta, Dinesh; Patra, Astam K. ChemSusChem, Vol. 7, Issue 3 https://doi.org/10.1002/cssc.201300766	journal	January 2014
Self-Assembled Mesoporous Zirconia and Sulfated Zirconia Nanoparticles Synthesized by Triblock Copolymer as Template Das, Swapan K.; Bhunia, Manas K.; Sinha, Anil K. The Journal of Physical Chemistry C, Vol. 113, Issue 20, p. 8918-8923 https://doi.org/10.1021/jp9014096	journal	May 2009
Iron-Catalyzed Furfural Production in Biobased Biphasic Systems: From Pure Sugars to Direct Use of Crude Xylose Effluents as Feedstock vom Stein, Thorsten; Grande, Philipp M.; Leitner, Walter ChemSusChem, Vol. 4, Issue 11 https://doi.org/10.1002/cssc.201100259	journal	October 2011
In situ infrared study of pyridine adsorption/desorption dynamics over sulfated zirconia and Pt-promoted sulfated zirconia Stevens, R. Applied Catalysis A: General, Vol. 252, Issue 1 https://doi.org/10.1016/S0926-860X(03)00375-2	journal	October 2003
Conversion of carbohydrates and lignocellulosic biomass into 5-hydroxymethylfurfural using AlCl₃·6H₂O catalyst in a biphasic solvent system Yang, Yu; Hu, Chang-wei; Abu-Omar, Mahdi M. Green Chem., Vol. 14, Issue 2, p. 509-513 https://doi.org/10.1039/C1GC15972K	journal	January 2012
Hierarchically porous titanium phosphate nanoparticles: an efficient solid acid catalyst for microwave assisted conversion of biomass and carbohydrates into 5-hydroxymethylfurfural Dutta, Arghya; Patra, Astam K.; Dutta, Saikat Journal of Materials Chemistry, Vol. 22, Issue 28 https://doi.org/10.1039/c2jm30623a	journal	January 2012
Characterization of Porous Solids and Powders: Surface Area, Pore Size and Density Lowell, S.; Shields, Joan E.; Thomas, Martin A. Particle Technology Series https://doi.org/10.1007/978-1-4020-2303-3	book	September 2004
Efficient catalytic conversion of fructose into hydroxymethylfurfural by a novel carbon-based solid acid Wang, Jianjian; Xu, Wenjie; Ren, Jiawen Green Chemistry, Vol. 13, Issue 10 https://doi.org/10.1039/c1gc15306d	journal	January 2011
Self-assembled mesoporous TiO2 spherical nanoparticles by a new templating pathway and its enhanced photoconductivity in the presence of an organic dye Patra, Astam K.; Das, Swapan K.; Bhaumik, Asim Journal of Materials Chemistry, Vol. 21, Issue 11 https://doi.org/10.1039/c0jm02937h	journal	January 2011
Catalytical conversion of fructose and glucose into 5-hydroxymethylfurfural in hot compressed water by microwave heating Qi, Xinhua; Watanabe, Masaru; Aida, Taku M. Catalysis Communications, Vol. 9, Issue 13 https://doi.org/10.1016/j.catcom.2008.04.025	journal	July 2008
Xylose Isomerization to Xylulose and its Dehydration to Furfural in Aqueous Media Choudhary, Vinit; Pinar, Ana B.; Sandler, Stanley I. ACS Catalysis, Vol. 1, Issue 12 https://doi.org/10.1021/cs200461t	journal	October 2011
Biopolymer templated porous TiO2: An efficient catalyst for the conversion of unutilized sugars derived from hemicellulose De, Sudipta; Dutta, Saikat; Patra, Astam K. Applied Catalysis A: General, Vol. 435-436 https://doi.org/10.1016/j.apcata.2012.06.002	journal	September 2012
The Path Forward for Biofuels and Biomaterials Ragauskas, Arthur J.; Williams, Charlotte K.; Davison, Brian H. Science, Vol. 311, Issue 5760, p. 484-489 https://doi.org/10.1126/science.1114736	journal	January 2006
Novel sulfonated carbonaceous materials from p-toluenesulfonic acid/glucose as a high-performance solid-acid catalyst Zhang, Baohua; Ren, Jiawen; Liu, Xiaohui Catalysis Communications, Vol. 11, Issue 7 https://doi.org/10.1016/j.catcom.2010.01.010	journal	March 2010
Selective Conversion of Biomass Hemicellulose to Furfural Using Maleic Acid with Microwave Heating Kim, Eurick S.; Liu, Shuo; Abu-Omar, Mahdi M. Energy & Fuels, Vol. 26, Issue 2 https://doi.org/10.1021/ef2014106	journal	January 2012
Microwave assisted conversion of carbohydrates and biopolymers to 5-hydroxymethylfurfural with aluminium chloride catalyst in water De, Sudipta; Dutta, Saikat; Saha, Basudeb Green Chemistry, Vol. 13, Issue 10 https://doi.org/10.1039/c1gc15550d	journal	January 2011
Self-assembly of mesoporous TiO2 nanospheres via aspartic acid templating pathway and its catalytic application for 5-hydroxymethyl-furfural synthesis De, Sudipta; Dutta, Saikat; Patra, Astam K. Journal of Materials Chemistry, Vol. 21, Issue 43 https://doi.org/10.1039/c1jm13229f	journal	January 2011
Active solid acid catalysts prepared by sulfonation of carbonization-controlled mesoporous carbon materials Xing, Rong; Liu, Yueming; Wang, Yong Microporous and Mesoporous Materials, Vol. 105, Issue 1-2 https://doi.org/10.1016/j.micromeso.2007.06.043	journal	September 2007
Self-Assembled TiO ₂ Nanospheres By Using a Biopolymer as a Template and Its Optoelectronic Application Dutta, Saikat; Patra, Astam K.; De, Sudipta ACS Applied Materials & Interfaces, Vol. 4, Issue 3 https://doi.org/10.1021/am201759w	journal	February 2012
“One-Pot” Synthesis of 5-(Hydroxymethyl)furfural from Carbohydrates using Tin-Beta Zeolite Nikolla, Eranda; Román-Leshkov, Yuriy; Moliner, Manuel ACS Catalysis, Vol. 1, Issue 4, p. 408-410 https://doi.org/10.1021/cs2000544	journal	April 2011
Efficient conversion of glucose into 5-hydroxymethylfurfural catalyzed by a common Lewis acid SnCl4 in an ionic liquid Hu, Suqin; Zhang, Zhaofu; Song, Jinliang Green Chemistry, Vol. 11, Issue 11 https://doi.org/10.1039/b914601f	journal	January 2009
Microwave assisted rapid conversion of carbohydrates into 5-hydroxymethylfurfural catalyzed by mesoporous TiO2 nanoparticles Dutta, Saikat; De, Sudipta; Patra, Astam K. Applied Catalysis A: General, Vol. 409-410 https://doi.org/10.1016/j.apcata.2011.09.037	journal	December 2011
Advances in conversion of hemicellulosic biomass to furfural and upgrading to biofuels Dutta, Saikat; De, Sudipta; Saha, Basudeb Catalysis Science & Technology, Vol. 2, Issue 10 https://doi.org/10.1039/c2cy20235b	journal	January 2012
Metal Chlorides in Ionic Liquid Solvents Convert Sugars to 5-Hydroxymethylfurfural Zhao, H.; Holladay, J. E.; Brown, H. Science, Vol. 316, Issue 5831, p. 1597-1600 https://doi.org/10.1126/science.1141199	journal	June 2007
Carbocatalytic dehydration of xylose to furfural in water Lam, Edmond; Chong, Jonathan H.; Majid, Ehsan Carbon, Vol. 50, Issue 3 https://doi.org/10.1016/j.carbon.2011.10.007	journal	March 2012

Similar Records

Efficient solid acid catalyst containing Lewis and Brønsted acid sites for the production of furfurals

Journal Article · Wed May 07 00:00:00 EDT 2014 · ChemSusChem · OSTI ID:1167955

Conversion of Xylose to Furfural Using Lewis and Brønsted Acid Catalysts in Aqueous Media

Journal Article · Mon Aug 27 00:00:00 EDT 2012 · ACS Catalysis · OSTI ID:1381571

Insights into the Interplay of Lewis and Brønsted Acid Catalysts in Glucose and Fructose Conversion to 5-(Hydroxymethyl)furfural and Levulinic Acid in Aqueous Media

Journal Article · Wed Mar 13 00:00:00 EDT 2013 · J. Am. Chem. Soc. · OSTI ID:1105648

Related Subjects

catalysis (homogeneous)
catalysis (heterogeneous)
biofuels (including algae and biomass)
bio-inspired
materials and chemistry by design
synthesis (self-assembly)
synthesis (scalable processing)

Efficient Solid Acid Catalyst Containing Lewis and Brønsted Acid Sites for the Production of Furfurals

Citation Formats

References (42)

Similar Records

Related Subjects